Contrasting fluid evolution of granulite-facies marbles: implications for a high-T intermediate-P terrain in the Famatinian Range, San-Juan, Argentina

High-temperature, intermediate-pressure calc-silicate marbles occur in the granulite-facies terrain of the La Huerta Range in the Province of San Juan, NW-Argentina, in three bulk-compositional varieties: Type (1) dolomite-absent scapolite-wollastonite-grandite-clinopyroxene-quartz—calcite marbles; Type (2) diopside-forsterite-spinel-corundum—calcite marbles with dolomite exolution lamellae in calcite; Type (3) serpentinized forsterite-spinel-dolomite marbles. An isobaric cooling path from peak-metamorphic conditions of 860°C to 750°C at 6.5 kbar is inferred from scapolite-wollastonite-grandite reaction textures in Type (1) and is consistent with cooling after an advective heat input from related gabbroic and tonalitic intrusive bodies. Stable carbon and oxygen isotope geochemistry was used to decipher the fluid/rock evolution of the three marble types. An interpreted four-stage temperature-time-fluid flow path comprises: (1) infiltration of pre-peak-metamorphic fluids, depleted in δ¹⁸O, that caused a shift of primary sedimentary δ¹⁸O ratios to lower values (19.6–20.0); (2) syn-metamorphic fluid liberation from Type (1) marbles with evidence for processes close to batch devolatilization that caused a weak coupled ¹³C and ¹⁸O depletion during prograde metamorphism. A different devolatilization behaviour, close to Rayleigh fractionation, texturally associated with fold settings indicates that granulite-facies fluid flow was focused rather than pervasive; (3) H₂O-absent conditions were dominant when coronal grandite formed during incipient high-temperature isobaric cooling at the expense of scapolite and wollastonite in the Type (1) marbles; (4) intense post-peak- hydration of Type (2) and Type (3) marbles is the last recognizable metasomatic event. In combination, the three marble types record fluid infiltration both before and after the metamorphic peak.     

Textural, chemical, and isotopic effects of late-magmatic carbonatitic fluids in the carbonatite–syenite Tamazeght complex, High Atlas Mountains, Morocco

Carbonatites of the Eocene Tamazeght complex, High Atlas Mountains, Morocco, consist of calciocarbonatites (alvikite and sövite dykes) and magnesiocarbonatites (diatreme breccias and dykes rocks). These are associated with ultramafic, shonkinitic, gabbroic to monzonitic and various foid syenitic silicate units. Stable and radiogenic isotope compositions for carbonatites and silicate rocks indicate that they share a common source in the mantle, although for some carbonatitic samples contamination with sedimentary rocks seems important. The observed isotopic heterogeneity is mainly attributed to source characteristics, fractional crystallization (accompanied by various degrees of assimilation), and late- to post-magmatic fluid–rock interaction. During the late fluid–rock interaction, Sr, Mn, and possibly also Fe were mobilized and redistributed to form secondary carbonate minerals in carbonatites. These fluids also penetrated into the adjacent syenitic rocks, causing enrichment in the same elements.     

Isotopic evidence (Sr/Sr, δLi) for alteration of the oceanic crust at deep-rooted mud volcanoes in the Gulf of Cadiz, NE Atlantic Ocean

The chemical and isotopic composition of pore fluids is presented for five deep-rooted mud volcanoes aligned on a transect across the Gulf of Cadiz continental margin at water depths between 350 and 3860 m. Generally decreasing interstitial Li concentrations and ⁸⁷Sr/⁸⁶Sr ratios with increasing distance from shore are attributed to systematically changing fluid sources across the continental margin. Although highest Li concentrations at the near-shore mud volcanoes coincide with high salinities derived from dissolution of halite and late-stage evaporites, clayey, terrigenous sediments are identified as the ultimate Li source to all pore fluids investigated. Light δ⁷Li values, partly close to those of hydrothermal vent fluids (δ⁷Li: +11.9‰), indicate that Li has been mobilized during high-temperature fluid/sediment or fluid/rock interactions in the deep sub-surface. Intense leaching of terrigenous clay has led to radiogenic ⁸⁷Sr/⁸⁶Sr ratios (∼0.7106) in pore fluids of the near-shore mud volcanoes. In contrast, non-radiogenic ⁸⁷Sr/⁸⁶Sr ratios (∼0.7075) at the distal locations are attributed to admixing of a basement-derived fluid component, carrying an isotopic signature from interaction with the basaltic crust. This inference is substantiated by temperature constraints from Li isotope equilibrium calculations suggesting exchange processes at particularly high temperatures (>200 °C) for the least radiogenic pore fluids of the most distal location.Advective pore fluids in the off-shore reaches of the Gulf of Cadiz are influenced by successive exchange processes with both oceanic crust and terrigenous, fine-grained sediments, resulting in a chemical and isotopic signature similar to that of fluids in near-shore ridge flank hydrothermal systems. This suggests that deep-rooted mud volcanoes in the Gulf of Cadiz represent a fluid pathway intermediate between mid-ocean ridge hydrothermal vent and shallow, marginal cold seep. Due to the thicker sediment coverage and slower fluid advection rates, the overall geochemical signature is shifted towards the sediment-diagenetic signal compared to ridge flank hydrothermal environments.     

Spatial Analysis of the Soil Carbon Sequestration Potential of Crop-residue Return in China Based on Model Simulation

Crop-residue return is a recommended practice for soil and nutrient management and is important in soil organic carbon (SOC) sequestration and CO₂ mitigation. We applied a process-based Environmental Policy Integrated Climate (EPIC) model to simulate the spatial pattern of topsoil organic carbon changes from 2001 to 2010 under 4 crop-residue return scenarios in China. The carbon loss (28.89 Tg yr^-1) with all crop-residue removal (CR0%) was partly reduced by 22.38 Tg C yr^-1 under the status quo CR30% (30% of crop-residue return). The topsoil in cropland of China would become a net carbon sink if the crop-residue return rate was increased from 30% to 50%, or even 75%. The national SOC sequestration potential of cropland was estimated to be 25.53 Tg C yr^-1 in CR50% and 52.85 Tg C yr^-1 in CR75%, but with high spatial variability across regions. The highest rate of SOC sequestration potential in density occurred in Northwest and North China while the lowest was in East China. Croplands in North China tended to have stronger regional SOC sequestration potential in storage. During the decade, the reduced CO₂ emissions from enhanced topsoil carbon in CR50% and CR75% were equivalent to 1.4% and 2.9% of the total CO₂ emissions from fossil fuels and cement production in China, respectively. In conclusion, we recommend encouraging farmers to return crop-residue instead of burning in order to improve soil properties and alleviate atmospheric CO₂ rises, especially in North China.     

The Compton and pair creation telescope MEGA

MEGA, short for Medium Energy Gamma-ray Astronomy, is the development of a new technology telescope in the energy band 0.4--50\ MeV. The wide energy range of MEGA, which spans nuclear γ-ray lines and energetic continuum spectra, the large field of view, and the capacity for polarimetry enables unique investigations into cosmic nucleosynthesis, particle accelerators around compact objects, and explosive high-energy events. We describe the development and tests of a prototype detector. Results from laboratory tests using radioactive sources and from a beam test calibration are presented and an outlook of a potential space mission is sketched.     

Influence of macroinvertebrates on physico‐chemical and microbial processes in hyporheic sediments

The objective of this study was to measure the effects of invertebrates on the physical characteristics and microbial processes in hyporheic sediments. We investigated the impacts of an assemblage of three taxa (asellids, chironomid larvae, and tubificid worms) on sediment distribution, water fluxes, sediment organic carbon, biofilm (attached bacteria) characteristics, and O₂, dissolved organic carbon NO₃^?, NO₂^?, and NH₄⁺ concentrations in slow filtration sand–gravel columns. The results showed that invertebrates clearly modified the distribution of particles in the sediment column, probably because of the structures (tubes, macropores, and faecal pellets) produced by the three taxa in the sediment. Our assessment of water fluxes indicated that invertebrate activities led to an increase in the porosity of the sediment columns. In addition, aerobic (O₂ consumption) and anaerobic (denitrification and fermentative decomposition of organic matter) microbial processes occurring in the sediment were stimulated in the presence of invertebrates. Finally, the present study demonstrates that invertebrates can act as ecosystem engineers in heterogeneous sediments that are under the influence of an advective flux of water. The solute residence time increased in columns containing the faunal assemblage. Micro‐organisms used more dissolved organic matter and nutrients in the presence of invertebrates because invertebrate activities increased the contact between the biofilm and water. We conclude that engineering by invertebrates in natural conditions modifies characteristics of the hyporheic zone and thereby enhances both the porosity of the sediment and the solute transport across the benthic interface. Copyright © 2002 John Wiley & Sons, Ltd.     

A study on iterative methods for solving Richards’ equation

This work concerns linearization methods for efficiently solving the Richards equation, a degenerate elliptic-parabolic equation which models flow in saturated/unsaturated porous media. The discretization of Richards’ equation is based on backward Euler in time and Galerkin finite elements in space. The most valuable linearization schemes for Richards’ equation, i.e. the Newton method, the Picard method, the Picard/Newton method and the L-scheme are presented and their performance is comparatively studied. The convergence, the computational time and the condition numbers for the underlying linear systems are recorded. The convergence of the L-scheme is theoretically proved and the convergence of the other methods is discussed. A new scheme is proposed, the L-scheme/Newton method which is more robust and quadratically convergent. The linearization methods are tested on illustrative numerical examples.     

Modelling innovation and the macroeconomics of low-carbon transitions: theory,perspectives and practical use

Energy and climate policies may have significant economy-wide impacts, which are regularly assessed based on quantitative energy-environment-economy models. These tend to vary in their conclusions on the scale and direction of the likely macroeconomic impacts of a low-carbon transition. This paper traces the characteristic discrepancies in models’ outcomes to their origins in different macro-economic theories, most importantly their treatment of technological innovation and finance. We comprehensively analyse the relevant branches of macro-innovation theory and group them into two classes: ‘Equilibrium’ and ‘Non-equilibrium’. While both approaches are rigorous and self-consistent, they frequently yield opposite conclusions for the economic impacts of low-carbon policies. We show that model outcomes are mainly determined by their representations of monetary and finance dimensions, and their interactions with investment, innovation and technological change. Improving these in all modelling approaches is crucial for strengthening the evidence base for policy making and gaining a more consistent picture of the macroeconomic impacts of achieving emissions reductions objectives. The paper contributes towards the ongoing effort of enhancing the transparency and understanding of sophisticated model mechanisms applied to energy and climate policy analysis. It helps tackle the overall ‘black box’ critique, much-cited in policy circles and elsewhere.

Key policy insights

• Quantitative models commissioned by policy-makers to assess the macroeconomic impacts of climate policy generate contradictory outcomes and interpretations.

• The source of the differences in model outcomes originates primarily from assumptions on the workings of the financial sector and the nature of money, and of how these interact with processes of low-carbon energy innovation and technological change.

• Representations of innovation and technological change are incomplete in energy-economy-environment models, leading to limitations in the assessment of the impacts of climate-related policies.

• All modelling studies should state clearly their underpinning theoretical school and their treatment of finance and innovation.

• A strong recommendation is given for modellers of energy-economy systems to improve their representations of money and finance.