Exploring the impact of diagenesis on (isotope) geochemical and microstructural alteration features in biogenic aragonite

For the Quaternary and Neogene, aragonitic biogenic and abiogenic carbonates are frequently exploited as archives of their environment. Conversely, pre‐Neogene aragonite is often diagenetically altered and calcite archives are studied instead. Nevertheless, the exact sequence of diagenetic processes and products is difficult to disclose from naturally altered material. Here, experiments were performed to understand biogenic aragonite alteration processes and products. Shell subsamples of the bivalve Arctica islandica were exposed to hydrothermal alteration. Thermal boundary conditions were set at 100°C, 175°C and 200°C. These comparably high temperatures were chosen to shorten experimental durations. Subsamples were exposed to different ¹⁸O‐depleted fluids for durations between two and twenty weeks. Alteration was documented using X‐ray diffraction, cathodoluminescence, fluorescence and scanning electron microscopy, as well as conventional and clumped isotope analyses. Experiments performed at 100°C show redistribution and darkening of organic matter, but lack evidence for diagenetic alteration, except in Δ₄₇ which show the effects of annealing processes. At 175°C, valves undergo significant aragonite to calcite transformation and neomorphism. The δ¹⁸O signature supports transformation via dissolution and reprecipitation, but isotopic exchange is limited by fluid migration through the subsamples. Individual growth increments in these subsamples exhibit bright orange luminescence. At 200°C, valves are fully transformed to calcite and exhibit purple‐blue luminescence with orange bands. The δ¹⁸O and Δ₄₇ signatures reveal exchange with the aqueous fluid, whereas δ¹³C remains unaltered in all experiments, indicating a carbonate‐buffered system. Clumped isotope temperatures in high‐temperature experiments show compositions in broad agreement with the measured temperature. Experimentally induced alteration patterns are comparable with individual features present in Pleistocene shells. This study represents a significant step towards sequential analysis of diagenetic features in biogenic aragonites and sheds light on reaction times and threshold limits. The limitations of a study restricted to a single test organism are acknowledged and call for refined follow‐up experiments.     

Annual Cycle of Zooplankton Biomass, Abundance and Species Composition in the Neritic Area of the Balearic Sea, Western Mediterranean

Abstract. Seasonal changes in zooplankton biomass, abundance and species composition were studied at a neritic station in the Balearic Sea between April 1993 and May 1994. Sampling was carried out every 10 days in a zone influenced by the main current circulating through the Mallorca channel. Three main peaks of zooplankton biomass and abundance were observed: (1) at the beginning of summer when the thermocline developed, (2) in autumn when the thermocline broke down, and (3) in early spring. The smaller zooplankton fraction (100–250 μm) comprised on average 32 % of the total biomass and 73 % of total abundance. Copepods were the predominant group (64 % of the total abundance) with Clausocalanus, Oithona and Paracalanus being the most abundant genera. Paracalanus parvus, Clausocalanus furcatus, Acartia clausi, Oithona plumifera, Temora stylifera, Centropages typicus and Oncaea mediterranea were found to be the most important species in the area. Other abundant groups were cladocerans (15 %) and meroplankton larvae (12 %), both of which were particularly numerous during the stratified period. The copepod community was characterized by the above‐cited perennial species, which were abundant during the cycle studied. However, the influence of the hydrological conditions of the Balearic Sea, such as the Atlantic water influx and the physical structure of the water column (stratification and mixing), promoted the observed variability in zooplankton as well as the appearance of characteristic species during the annual cycle.     

Coastal erosion vs riverine sediment discharge in the Arctic Shelf seas

This article presents a comparison of sediment input by rivers and by coastal erosion into both the Laptev Sea and the Canadian Beaufort Sea (CBS). New data on coastal erosion in the Laptev Sea, which are based on field measurements and remote sensing information, and existing data on coastal erosion in the CBS as well as riverine sediment discharge into both the Laptev Sea and the CBS are included. Strong regional differences in the percentages of coastal erosion and riverine sediment supply are observed. The CBS is dominated by the riverine sediment discharge (64.45᎒⁶ t a^-1) mainly of the Mackenzie River, which is the largest single source of sediments in the Arctic. Riverine sediment discharge into the Laptev Sea amounts to 24.10᎒⁶ t a^-1, more than 70% of which are related to the Lena River. In comparison with the CBS, the Laptev Sea coast on average delivers approximately twice as much sediment mass per kilometer, a result of higher erosion rates due to higher cliffs and seasonal ice melting. In the Laptev Sea sediment input by coastal erosion (58.4᎒⁶ t a^-1) is therefore more important than in the CBS and the ratio between riverine and coastal sediment input amounts to 0.4. Coastal erosion supplying 5.6᎒⁶ t a^-1 is less significant for the sediment budget of the CBS where riverine sediment discharge exceeds coastal sediment input by a factor of ca. 10.     

Combined effects of pumped-storage operation and climate change on thermal structure and water quality

Climatic Change - The assessment of ecological impacts of pumped-storage (PS) hydropower plants on the two connected water bodies is usually based on present climatic conditions. However,...     

Spectral density regression for bivariate extremes

We introduce a density regression model for the spectral density of a bivariate extreme value distribution, that allows us to assess how extremal dependence can change over a covariate. Inference is performed through a double kernel estimator, which can be seen as an extension of the Nadaraya–Watson estimator where the usual scalar responses are replaced by mean constrained densities on the unit interval. Numerical experiments with the methods illustrate their resilience in a variety of contexts of practical interest. An extreme temperature dataset is used to illustrate our methods.     

The postglacial environmental development of Raffles Sø, East Greenland: inferences from a 10,000 year diatom record

A 341 cm long sediment sequence was recovered from the unofficially named Raffles Sø on Raffles Ø, outer Scoresby Sund region, East Greenland. The sediment sequence consists in the upper part (0–230 cm) of a stratified gyttja enriched in organic carbon and biogenic silica whereas the lower core part (235–341 cm) is composed of terrigenous, consolidated glacio-limnic sediments. ¹⁴C-AMS measurements indicate that the sediment sequence represents the entire Holocene lake history from 10,030 calibrated radiocarbon years.The geochemical parameters (opal, total organic carbon (TOC), total nitrogen (TN)) and the total diatom concentration show similar developments during the Holocene, and reflect changes in biological production and nutrient input into the lake. These records clearly reveal a broad Holocene TOC-opal-maximum interval between 5200 and 1800 cal. yrs BP.The diatom flora consisted of 66 taxa representing 20 genera but only seven taxa were abundant and, sometimes, these were monospecifically dominant during the Holocene. In the sediment core from Raffles Sø four successive stratigraphical zones can be distinguished. Accumulation of diatom valves began at 9900 cal. yrs BP with a Stephanodiscus minutulus (Kütz.) Cleve and Möller dominated assemblage (stratigraphic zone 1) followed by a diatom flora dominated by Cyclotella pseudostelligera Hustedt and, less frequently, by Diatoma tenuis Agardh (9400 until 5900 cal. yrs BP, zone 2). Cyclotella sp. A, a taxon which belongs to the Cyclotella rossii-comensis-tripartita-complex, was the dominant floral element between 5200 and 1800 cal. yrs BP (zone 3). From 1800 cal. yrs BP, the periphytic taxa Fragilaria capucina var. gracilis (Østr.) Hustedt and F. capucina var. rumpens (Kütz.) Lange-Bertalot attained highest relative abundances, also almost monospecifically (zone 4).The distribution and composition of the diatom assemblages in the sediment record from Raffles Sø probably reflect past variations in the extent of the lake-ice cover during the growing season. More or less ice-free conditions during summer may have prevailed during the early Holocene until ca. 1800 cal. yrs BP, which allowed growth of planktonic diatoms (Cyclotella taxa) in the pelagic lake region. From 1800 cal. yrs BP, colder conditions lead to a perennial lake-ice cover with a small ice-free moat in summer which favored the growth of periphytic, littoral species (Fragilaria capucina varieties).     

Distinguishing volcanic debris avalanche deposits from their reworked products: the Perrier sequence (French Massif Central)

Debris avalanches associated with volcanic sector collapse are usually high-volume high-mobility phenomena. Debris avalanche deposit remobilisation by cohesive debris flows and landslides is common, so they can share textural characteristics such as hummocks and jigsaw cracks. Distinguishing original deposits from reworked products is critical for geological understanding and hazard assessment because of their different origin, frequency and environmental impact. We present a methodology based on field evidence to differentiate such epiclastic breccias. Basal contact mapping constrained by accurate altitude and location data allows the reconstruction of deposit stratigraphy and geometry. Lithological analysis helps to distinguish the different units. Incorporation structures, kinematic indicators and component mingling textures are used to characterise erosion and transport mechanisms. We apply this method to the enigmatic sequence at Perrier (French Massif Central), where four units (U1–U4) have been interpreted either as debris flow or debris avalanche deposits. The sequence results from activity on the Monts Dore Volcano about 2 Ma ago. The epiclastic units are matrix supported with an almost flat top. U2 and U3 have clear debris flow deposit affinities such as rounded clasts and intact blocks (no jigsaw cracks). U1 and U4 have jigsaw cracked blocks with matrix injection and stretched sediment blocks. U1 lacks large blocks (>10 m wide) and has a homogenous matrix with an upward increase of trapped air vesicle content and size. This unit is interpreted as a cohesive debris flow deposit spawned from a debris avalanche upstream. In contrast, U4 has large mega-blocks (up to 40 m wide), sharp contacts between mixed facies zones with different colours and numerous jigsaw fit blocks (open jigsaw cracks filled by monogenic intra-clast matrix). Mega-blocks are concentrated near the deposit base and are spatially associated with major substratum erosion. This deposit has a debris avalanche distal facies with local debris flow affinities due to partial water saturation. We also identify two landslide deposits (L1 and L2) resulting from recent reworking that has produced a similar facies to U1 and U4. These are distinguishable from the original deposits, as they contain blocks of mixed U1/U4 facies, a distinctly less consolidated and more porous matrix and a fresh hummocky topography. This work shows how to differentiate epiclastic deposits with similar characteristics, but different origins. In doing so, we improve understanding of present and past instability of the Monts Dore and identify present landslide hazards at Perrier.     

Soil Organic Carbon mapping of partially vegetated agricultural fields with imaging spectroscopy

Soil Organic Carbon (SOC) is one of the key soil properties, but the large spatial variation makes continuous mapping a complex task. Imaging spectroscopy has proven to be an useful technique for mapping of soil properties, but the applicability decreases rapidly when fields are partially covered with vegetation. In this paper we show that with only a few percent fractional maize cover the accuracy of a Partial Least Square Regression (PLSR) based SOC prediction model drops dramatically. However, this problem can be solved with the use of spectral unmixing techniques. First, the fractional maize cover is determined with linear spectral unmixing, taking the illumination and observation angles into account. In a next step the influence of maize is filtered out from the spectral signal by a new procedure termed Residual Spectral Unmixing (RSU). The residual soil spectra resulting from this procedure are used for mapping of SOC using PLSR, which could be done with accuracies comparable to studies performed on bare soil surfaces (Root Mean Standard Error of Calibration = 1.34 g/kg and Root Mean Standard Error of Prediction = 1.65 g/kg). With the presented RSU approach it is possible to filter out the influence of maize from the mixed spectra, and the residual soil spectra contain enough information for mapping of the SOC distribution within agricultural fields. This can improve the applicability of airborne imaging spectroscopy for soil studies in temperate climates, since the use of the RSU approach can extend the flight-window which is often constrained by the presence of vegetation.     

The two-step shape and timing of the last deglaciation in Antarctica

The two-step character of the last deglaciation is well recognized in Western Europe, in Greenland and in the North Atlantic. For example, in Greenland, a gradual temperature decrease started at the Bölling (B) around 14.5 ky BP, spanned through the Alleröd (A) and was followed by the cold Younger Dryas (YD) event which terminated abruptly around 11.5 ky BP. Recent results suggest that this BA/YD sequence may have extended throughout all the Northern Hemisphere but the evidence of a late transition cooling is still poor for the Southern Hemisphere. Here we present a detailed isotopic record analyzed in a new ice core drilled at Dome B in East Antarctica that fully demonstrates the existence of an Antarctic cold reversal (ACR). These results suggest that the two-step shape of the last deglaciation has a worldwide character but they also point to noticeable interhemispheric differences. Thus, the coldest part of the ACR, which shows a temperature drop about three times weaker than that recorded during the YD in Greenland, may have preceded the YD. Antarctica did not experienced abrupt changes and the two warming periods started there before they started in Greenland. The links between Southern and Northern Hemisphere climates throughout this period are discussed in the light of additional information derived from the Antarctic dust record.     

Coupling hydrogeological with surface runoff model in a Poltva case study in Western Ukraine

This paper presents the hydrological coupling of the software framework OpenGeoSys (OGS) with the EPA Storm Water Management Model (SWMM). Conceptual models include the Saint Venant equation for river flow, the 2D Darcy equations for confined and unconfined groundwater flow, a two-way hydrological coupling flux in a compartment coupling approach (conductance concept), and Lagrangian particles for solute transport in the river course. A SWMM river–OGS aquifer inter-compartment coupling flux is examined for discharging groundwater in a systematic parameter sensitivity analysis. The parameter study involves a small perturbation (first-order) sensitivity analysis and is performed for a synthetic test example base-by-base through a comprehensive range of aquifer parametrizations. Through parametrization, the test cases enables to determine the leakance parameter for simulating streambed clogging and non-ocillatory river-aquifer water exchange rates with the sequential (partitioned) coupling scheme. The implementation is further tested with a hypothetical but realistic 1D river–2D aquifer model of the Poltva catchment, where discharging groundwater in the upland area affects the river–aquifer coupling fluxes downstream in the river course (propagating feedbacks). Groundwater contribution in the moving river water is numerically determined with Lagrangian particles. A numerical experiment demonstrates that the integrated river–aquifer model is a serviceable and realistic constituent in a complete compartment model of the Poltva catchment.