Sorption-desorption kinetics and toxic cell concentration in marine phytoplankton microalgae exposed to Linear Alkylbenzene Sulfonate

Linear Alkylbenzene Sulfonates (LAS) are ubiquitous surfactants. Traces can be found in coastal environments. Sorption and toxicity of C₁₂-LAS congeners were studied in controlled conditions (2-3500 μg C₁₂LAS/L) in five marine phytoplanktonic species, using standardized methods. IC₅₀ values ranged from 0.5 to 2 mg LAS/L. Sorption of ¹⁴C₁₂-6 LAS isomer was measured at environmentally relevant trace levels (4 μg/L) using liquid scintillation counting. Steady-state sorption on algae was reached within 5 h in the order dinoflagellate > diatoms > green algae. The sorption data, fitted a L-type Freundlich isotherm, indicating saturation. Desorption was rapid but a low LAS fraction was still sorbed after 24 h. Toxic cell concentration was 0.38 ± 0.09 mg/g for the studied species. LAS toxicity results from sorption on biological membranes leading to non-specific disturbance of algal growth. Results indicate that LAS concentrations in coastal environments do not represent a risk for these organisms.     

A western boundary current east of New Caledonia: Observed characteristics

Waters from the South Equatorial Current (SEC), the northern branch of the South Pacific subtropical gyre, are a major supply of heat to the equatorial warm pool, and have an important contribution to climate variability and ENSO which motivated the Southwest Pacific Ocean and Climate Experiment (SPICE, CLIVAR/WCRP). Initially a broad westward current extending from the equator to 30°S, the SEC splits upon arriving at the major islands and archipelagoes of Fiji (18°S, 180°E), Vanuatu (16°S, 168°E), and New Caledonia (22°S, 165°E), resulting in a complex system of western boundary currents and zonal jets that feed the Coral and Solomon Seas. We focus here on the formation of one specific jet feeding the Coral Sea, the North Caledonian Jet (NCJ). Using a combination of recent oceanographic cruises, we describe the ocean circulation to the northeast of New Caledonia, where the SEC forms a western boundary current that ultimately becomes the NCJ. This current, which we document for the first time and propose to refer to as the East Caledonian Current (ECC), has its core located 10-100 km off the east coast of New Caledonia, and extends vertically to at least 1000 m depth. Water mass properties show continuous westward transports through the ECC, from the SEC to the NCJ in both the South Pacific Tropical Waters in the thermocline and Antarctic Intermediate Waters near 700 m depth. The ECC extends about 100 km horizontally; its average 0-1000 m transport was estimated at 14.5±3 Sv off the north tip of the New Caledonian reef, with a maximum of 20 Sv in May 2010. South of that the upstream branch of the ECC east of the Loyalty is close to 8 Sv suggesting an important additional contribution from central Pacific waters carried by the SEC at 16°S and diverted to our region through the western boundary current system east of Vanuatu.     

Electrical conductivity and crustal structure beneath the central Hellenides around the Gulf of Corinth (Greece) and their relationship with the seismotectonics

A deep magnetotelluric sounding (MTS) investigation in the western part of the Gulf of Corinth has revealed a complex electrical image of the crustal structure. The geotectonic structure of the Parnassos unit and the Transition zone in the central Hellenides, overthrusting the Pindos zone both towards the west and towards the south, has been clearly identified by its higher resistivity and its intrinsic anisotropy related to the N–S strike of the Hellenides range. Subsequent N–S extension of the Gulf introduced another heterogeneous anisotropy characteristic that corresponds to E–W-trending normal faults on both sides of the Gulf. The 2-D modelling of the MTS results reveals the existence of a relatively conductive layer about 4 km thick at a depth greater than 10 km in the middle crust. It corresponds to a ductile detachment zone suggested by microseismic and seismic studies ( King et al . 1985 ; Rigo et al . 1996 ; Bernard et al . 1997a ). It may be attributed to the phyllite series lying between the allochthonous Hellenic nappes and the autochthonous Plattenkalk basement. Towards the east, under the Pangalos peninsula, approaching the internal Hellenides, the detachment zone could root deeply into the lower crust.
Some strong local electrical anomalies are observed, reaching the conductive layer in the middle crust, such as that under the Mamousia fault and under the front of the overthrust of the Transition zone on the Pindos zone. Other anomalies affect only the shallower zones such as that beneath the Helike fault and in the Psaromita peninsula. These shallower anomalies provide complementary information to the study of spatial and temporal variations of the seismic anisotropy in relation to the short- and long-term tectonic activity of the Gulf ( Bouin et al . 1996 ; Gamar et al . 1999 ).     

Microbial nitrogen transformations in sediments and inorganic nitrogen fluxes across the sediment/water interface on the South Island West Coast,New Zealand

In January 1982, sediment microbial N transformations and inorganic N fluxes across the sediment/water interface were studied at nine sites off the South Island West Coast, New Zealand. The sediments showed a great variety in physical, chemical and biological properties. The sediment organic matter had a molar $\text{C}\text{N}$ ratio of 5.9–10.9, and the total $\text{N}\text{P}$ ratio was 1.2–4.0. The denitrification capacity in the top 7.5 cm of sediment was 0.1–77.2 mmol N m^?2 day^?1 and generally declined with increasing sediment depth. The in situ denitrification rate was 0.02–1.84 mmol N m^?2 day^?1 and highest activities were generally found in surface sediments and at 6–7.5 cm depth. Denitrification accounted for 82–100% of total nitrate reduction. Net N mineralization was indirectly estimated at 0.6–2.4 mmol N m^?2 day^?1, and the experimental determination of this N transformation gave 0.6–3.2 mmol N m^?2 day^?1. Denitrification accounted for 3–75% of net N mineralization. The diffusive flux of ammonium and nitrate across the sediment/water interface was 0.1–0.7 and 0.1–0.6 mmol N m^?2 day^?1, respectively.     

The 4-day rotation of the upper atmosphere of venus

Near u.v. photographs of Venus have been analysed. Evidence is presented that so-called Y- and ψ-shaped markings accelerate from local sunrise to some time during local afternoon; mean horizontal velocities are 83 msec^?1 (morning) and 122 msec^?1 (afternoon). Possibly these configurations are more stable than a normal cloud system. ‘Irregular’ features do not seem to share this acceleration; they circulate at higher altitudes, sometimes covering or distorting the stable configurations.     

Morphodynamics and cobbles behavior in and near the surf zone

The evolution of an initially flat sandy slope and the dynamics of large objects (cobbles/mines) emplaced on it are studied in a laboratory wave tank under simulated surf conditions. Upon initiation of wave forcing, the initially flat beach undergoes bedform changes before reaching a quasi-steady morphology characterized by a system of sand ripples along the slope and a large bar near the break point. Although the incoming wave characteristics are held fixed, the bottom morphology never reaches a strict steady state, but rather slowly changes due to the migration of ripples and bar transformation. When the wave characteristics are changed, the bedform adjusts to a new quasi-steady state after a suitable adjustment time. Studies conducted by placing model cobbles/mines on the evolving sandy bottom subjected to wave forcing show four distinct scenarios: (i) periodic cobble oscillations with zero mean displacement and small scour around the cobbles, (ii) mean onshore motion of relatively light cobbles, (iii) periodic burial of relatively heavy cobbles when their sizes are comparable to those of sand ripples, and (iv) the burial of relatively large cobbles under the bar, when the bar migrates due to changes of incoming waves. Quantitative data on the characteristics and dynamics of the bedform, including ripple-formation front propagating down the slope, ripple growth and drift, and flow around ripples, are presented. Physical explanations are provided for the observations.