A simplified resorcinol method for direct spectrophotometric determination of nitrate in seawater

A direct, spectrophotometric method has been adapted for quantitative determination of nitrate concentrations in seawater. The method is based on nitration of resorcinol in acidified seawater, resulting in a color product. The absorption spectrum obtained for the reaction product shows a maximum absorption at 505 nm, with a molar absorptivity of 1.7 × 10⁴ L mol^− 1 cm^− 1. This method has a detection limit of 0.5 μM and is linear up to 400 μM for nitrate. The advantage of this method is that all reagents are in aqueous solutions without involving cadmium granules as a heterogeneous reactant, as in conventional methods, and therefore is simple to implement. Application of the resorcinol to seawater analysis demonstrated that the results obtained are in good agreement with the conventional approach involving the reduction of nitrate by cadmium followed by diazotization.     

Reduktive Dehalogenierung von Chlorkohlenwasserstoffen während der anaeroben Stabilisierung von Hausmüll

Reductive Dehalogenation of Chlorinated Hydrocarbons during Anaerobic Stabilization of Municipal Wastes During sequential anaerobic digestion of municipal wastes, distinct biogeochemical phases exist which show different capabilities to transform halogenated hydrocarbons. Chlorophenols, tetrachloroethylene, and chloroanilines codisposed together with organic-rich waste substrates are reductively dehalogenated during methanogenic conditions. Lindane is degraded during acidogenesis as well as during methanogenesis. However, degradation in methanogenic leachates is faster by a factor of 10. The poor transformation potential during acidogenesis compared to subsequent transient methanogenic and stabile methanogenic phases cannot be explained by inadequate acclimation of prevailing microorganisms to the codisposed organochlorines. Thus, observed transformation capabilities are a pertinent feature of methanogenic leachates, probably due to prevailing low redox potential and/or presence of suitable microbial activities (not necessarily methanogenis). Dehalogenation of 2,3,4,6-tetrachlorophenol as a model compound is hampered in methanogenic leachate by addition of a surplus of sulfate and is completely suppressed by addition of molybdate which selectively inhibits sulfate reducing microorganisms. Competition for common electron donators (e.g. H₂) is discussed as an explanation of these results. The results point to sulfate reducing microorganisms being involved in reductive dehalogenation of chlorophenols.     

Influence of the topography of the surface of the Earth on vertical sounding of the temperature profile

Atmospheric temperature and humidity fields as well as information on other meteorological parameters are nowadays retrieved from radiance measurements recorded by operational meteorological satellites. Up to now, the inversion procedures used only take into account crude information on the topography of the Earth’s surface. However, the applied radiative transfer codes have to consider the Earth’s surface as the lower boundary of the atmospheric model and, therefore, need a more precise mean elevation and a classification of the roughness of the Earth’s surface. The influence of the topography of the Earth surface on retrieved temperature profiles is studied by using a physico-statistical inversion method. An objective analysis is made of the more precise mean elevation and derivation of roughness parameters using a new high-resolution digital elevation model (DEM) with a resolution of 500 m×500 m. By means of a geomorphological process and a newly developed topography rejection test, areas with a high surface roughness are localized and singled out. The influence of topography on the retrieved temperature profiles is illustrated by case studies. Changes are found predominantly in areas with a high variation of topography. Using the new high-resolution DEM and the topography rejection test, the geographical position of the calculated temperature profiles tends to be shifted towards areas with a small vertical variation of topography. The mean elevation determined by the new elevation model better characterizes the area observed. Hence, the temperature profiles can be calculated down to lower atmospheric levels. Furthermore, a guess profile better describing the atmospheric situation is selected by the more precise elevation. In addition, the temperature profiles obtained near the coast are improved considerably by the more precise determination of the surface property ‘sea’ and ‘land,’ respectively. Integration of an independent physical information such as topography leads, on average, to a slight improvement of the results of the physico-statistical inversion procedure. In some cases, however, significant improvements have been achieved regarding the desired accuracy of temperature profiles of the order of 1 K. In future, the spatial resolution of new high-resolution sounding instrumentation on the next generation of operational meteorological satellites will be increased. To exploit the resolving power of this new instrumentation, the different variation of the topography of the Earth surface, especially in regions with a high variation of topography, can be taken into account more precisely by using a high-resolution DEM.     

Coupling between auroral kilometric radiation and auroral radio noise based on wave-particle resonance interaction

Summary The existence of a coupling, due to wave-particle resonance interaction, between magnetospheric radio emissions, i.e. auroral kilometric radiation (AKR), and auroral radio noise(AN), separated in an inhomogeneous magnetospheric plasma by an opacity barrier, is studied. It is proved that the ballistic process can only take place on the electrons of the superthermal component of the plasma, i.e. on particles of auroral electron fluxes of the inverted V type, due to finite width of the AKR spectral lines, which amounts to 1 kHz. Analyses indicate that its effectiveness is sufficient to explain radio emission coupling and that it increases with the degree of auroral activity.

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On latitudinal variations of temporal characteristics of the VLF chorus in the upper ionosphere

Summary The elements of the VLF chorus, observed simultaneously at a ground station and satellite in polar orbit, can be used to determine the differences in the arrival times of waves and their dependence on latitude. Mostly does not change practically over a wide range of latitudes, however, in some cases it may increase appreciably at low value of L. Model computations of the propagation time, based on the assumption that the source of the chorus is located close to the equatorial plane, have indicated the possibility of explaining the increase in at low latitudes by the presence of a step in the electron density profile close to this plane.

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a¶rt;u m a u a um nmu nun um nm n¶rt;um amu u nu¶rt;a ma a u u um auum (L). um a a m ¶rt;uana um, m a a¶rt;am aum uu a a L-a. am anmau n¶rt;nuu amua umua naam m um uu a uu uma auu mnu an¶rt;uu m mauu amua nmu.

     

Einfluß des Komplexbildungsgrades auf die Migrationsgeschwindigkeit von Eisen(II,III)-Verbindungen

This paper describes relations between the degree of complexation calculated with a mathematical model (FISCHER and REISSIG, 1984) and the ion-exchange and migration behaviour of iron(II, III)-compounds in a simulated aquifer. In general, the bonding of the complexes to the soil matrix becomes stronger with increasing positive charge. Negatively charged or neutral complex compounds do not show any, or show only slight interactions with the soil matrix. By complexation it is possible to achieve great differences in the migration behaviour of a particular metal. In the course of migration in the deposit there was found a separation of the complex mixture in accordance with charge. The break-through curves are characterized by a stepped shape, for this case. If weak acids or weak bases act as complex-forming ligands, the pH-dependent dissociation of the complexing species has to be taken into account in the complex calculation; this is represented by the example of the iron(III)-citrate system in this paper. Moreover, experimental results concerning the migration behaviour of iron(II, III)-fulvic acid complexes are given     

ELF and VLF electric field measurements with the Interkosmos 10 satellite

Summary The ELF-VLF experiment onboard the Interkosmos 10 satellite consisted mainly of a broadband receiver covering the frequency range from 20 Hz to 22 kHz. The signal level in this broad band has also been measured, as well as the level in two narrow bands with centre frequencies of 720 Hz and 4 kHz. The electric component of the ELF-VLF fields has been measured by using an electric dipole antenna, 2.35 m in length. The purpose of this paper is to characterise the data obtained by the broadband RTT transmissions at the Panská Ves station during the seven-months active period of the satellite. The spectral analysis of all broad-band ELF-VLF recordings has been used. Examples of some typical phenomena, most frequently observed at different invariant latitudes are given.     

A sediment trap intercomparison study in the Santa Barbara Basin

Four sediment traps of radically different design were deployed in the Santa Barbara Basin for approximately 45 days. The measured fluxes ranged from 370 to 774 g m^?2 yr^?1 for the different designs. These values lie within flux measurements previously determined for the basin. Compared to the 25-year record (920 g m^?2 yr^?1), however, all fluxes determined in this experiment are somewhat low. Because this experiment was conducted during a general period of high storm activity and runoff, measurement of greater than average flux was expected. It is probable that the higher flux recorded by the sediments results from a significant input of detritus into the basin by near bottom transport.The chemical composition of trapped material was nearly identical in all four trap designs. The deep cone design, however, had a significantly lower Mn content. Since this trap was the only one in which reducing conditions were produced in the sample container, reduction and mobilization of manganese after collection is believed to have occurred.In spite of the very different designs tested, the factor of two agreement in flux determination and the compositional similarity of the material collected is encouraging for future attempts to directly measure the flux of particulates in the ocean.     

On the characteristics of vlf emissions in the upper ionosphere and on the ground

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