Pressure-Dependence of Rare Earth Element Distribution in Amphibolite- and Granulite- Grade Garnets. A LA-ICP-MS Study

Using an excimer (KrF) laser ablation ICP-MS system, we studied the distribution of REE in garnets from metapelites and metabasites from Ivrea-Verbano (Western Alps, Italy) and from the Peña Negra Anatectic Complex (Central Iberia), finding systematic variations that correlate well with the metamorphic grade. Chondrite-normalized REE patterns of garnets from amphibolite-grade metapelites have lower-than-chondrite levels from La to Sm, a very small or no Eu anomaly, and a steep rise in the abundance of heavy REE as the atomic number increases. Metapelitic garnets from the amphibolite-granulite transition have a marked Eu negative anomaly and are enriched in MREE such that Sm is 10-15 times chondrite and the pattern is almost flat from Dy to Yb-Lu. In garnets from granulite-grade metapelites, the intensity of the Eu anomaly and the relative concentration of Nd, Sm, Gd and Tb increase, with almost flat chondrite-normalized patterns from Sm to Lu. Garnets from mafic granulites are remarkably similar to those of metapelitic garnets equilibrated at the same pressure, except for the Eu anomaly. The apparent paradox of enhanced uptake of larger REE ions with increasing pressure is attributed to the 3M²⁺ 2REE³⁺+ vacancy substitution, which produces a net decrease in the dimensions of the unit-cell of garnet. Variations in REE patterns depend essentially on the pressure and have little dependence on either temperature, bulk-composition of garnet, or REE whole-rock composition, so they could represent a new approach for geobarometric studies. The best numerical parameter to express pressure-related variations of REE distribution in garnets is the Gd/Dy ratio which does not seem perceptibly affected by disequilibrium partitioning. The regression equation between GASP pressure and the average Gd/Dy^garnet is P = 3.6 + 5.6 Gd/Dy. This equation seems to be reliable for garnets: (1)equilibrated within a pressure range of 4-9 kbar, (2) coexisting with modal monazite; and (3) with unit-cell dimensions under 11.46 Å.     

Flow time estimation with spatially variable hillslope velocity in ungauged basins

The automated spatial estimation of the hillslope runoff dynamics is used as a valuable tool for the estimation of the travel time distribution (flow time), a major factor for the hydrologic prediction in ungauged basins. In fact, while the flow time function is usually obtained by rescaling the flow paths with constant channel and hillslope velocities, in this work a spatially distributed kinematic component, as a function of terrain features and in particular slope and land use, is implemented and its influence on the hydrologic response is tested by means of the Width Function Instantaneous Unit Hydrograph (WFIUH) framework. Hillslope surface flow velocities are evaluated by applying different uniform flow formulas within an automated DEM-based (terrain analysis) algorithm. A comparison test of the performances of the Manning, Darcy, Maidment and Soil Conservation Service uniform flow equations is performed for several case studies in Italy pertaining to different climatic and geomorphic conditions. Results provide new insights for a better understanding of the flow time function also introducing a more parsimonious and physically-based calibration scheme of the WFIUH.     

Extreme events and disasters: a window of opportunity for change? Analysis of organizational,institutional and political changes,formal and informal responses after mega-disasters

Disaster associated with natural hazards can lead to important changes—positive or negative—in socio-ecological systems. When disasters occur, much attention is given to the direct disaster impacts as well as relief and recovery operations. Although this focus is important, it is noteworthy that there has been little research on the characteristics and progress of change induced by disasters. Change, as distinct from impacts, encompasses formal and informal responses to disaster events and their direct and indirect impacts. While smaller disasters do not often lead to significant changes in societies and organizational structures, major disasters have the potential to change dominant ways of thinking and acting. Against this background, the article presents an analytical framework for distinguishing change from disaster impacts. Drawing from research in Sri Lanka and Indonesia, formal and informal changes after the Indian Ocean Tsunami of 2004 are examined and discussed against the background of the conceptual framework. The changes examined range from the commencement of the peace process in Aceh, Indonesia, to organizational and legal reforms in Sri Lanka. The article concludes that change-making processes after disasters need to be understood more in depth in order to derive important strategic policy and methodological lessons learned for the future, particularly in view of the increasing complexity and uncertainty in decision making due to climate change.     

Tides and mixing in the northwestern East China Sea Part I: Rotating and reversing tidal flows

Bottom-mounted ADV and ADCP instruments in combination with CTD profiling measurements taken along the Chinese coast of the East China Sea were used to study the vertical structure of temperature, salinity, and velocity in reversing tidal currents on a shallow inner shelf and in rotating tidal flows over a deeper sloping bottom of the outer shelf. These two regimes of barotropic tide affect small-scale dynamics in the lower part of the water column differently. The reversing flow was superimposed by seiches of ∼2.3 h period generated in semienclosed Jiaozhou Bay located nearby. As the tidal vector rotates over the sloping bottom, the height of the near-bottom logarithmic layer is subjected to tidal-induced variations. A maximum of horizontal velocity U_max appears at the upper boundary of the log layer during the first half of the current vector rotation from the minor to the major axis of tidal ellipse. In rotating tidal flow, vertical shear generated at the seafloor, propagated slowly to the water interior up to the height of U_max, with a phase speed of ∼5 m/h. The time-shifted shear inside the water column, relative to the shear at the bottom, was associated with periodically changing increases and decreases of the tidal velocity above the log layer toward the sea surface. In reversing flows, the shear generated near the bottom and the shear at the upper levels were almost in phase.     

Dicroerisma (Actiniscales, Dinophyceae) in the open Pacific Ocean, a gymnodinioid dinoflagellate with an endoskeleton

This study is the first to describe and illustrate the dinoflagellate genus Dicroerisma in the open Pacific Sea and in the southern hemisphere.Eleven individuals ascribed to Dicroerisma psilonereiella were encountered in subsurface waters(>70 m depth) from 34°N to 33°S.Another specimen that differs from the type is also illustrated.These findings reveal that Dicroerisma is a widespread genus and that there is tentative existence of another species within the genus.     

U–Pb evidence for a polyorogenic evolution of the HP–HT units of the NW Iberian Massif

. A isotope dilution thermal ionisation mass spectrometry U-Pb geochronological study was carried out on the high-pressure and high-temperature units (HP-HT units) overlying the oceanic suture in the Allochthonous Complexes of the NW Iberian Variscan Belt. The rocks investigated are seven granulite- to eclogite-facies paragneisses and one leucosome within mafic high-pressure granulites in the Ordenes and Cabo Ortegal Complexes of NW Spain. U-Pb dating of zircon, monazite, titanite and rutile reveal the presence of a pervasive Early Ordovician metamorphic event at ca. 500-480 Ma and a later Early Devonian event at ca. 400-380 Ma. The U-Pb ages, in conjunction with petrological and structural data, indicate that the high-pressure event recorded by these rocks is Early Ordovician in age. Monazite ages in the paragneisses suggest that peak metamorphic conditions were reached at ca. 500-485 Ma. Subsequently, the rock ensemble underwent exhumation accompanied by partial melting and zircon growth at ca. 485-470 Ma. Melting of mafic granulites was coeval with this latter episode as indicated by zircon crystallisation age in the leucosomes dated at ca. 486 Ma. Based on these data and on the general features of magmatism and metamorphic evolution, it is proposed that this process took place at a convergent plate boundary within a peri-Gondwanan oceanic domain. Monazite, titanite and rutile data in some of the samples studied show evidence of a second metamorphic episode that took place between ca. 400 and 380 Ma (with a peak at ca. 390-385 Ma). This Early Devonian event, at variance with the previous one, was not pervasive, but, rather, was localised in areas of intense Variscan tectonothermal reworking. It is claimed that this later metamorphic event was recorded by the U-Pb system in areas where monazite and titanite growth was enhanced by fluid circulation in highly strained rocks (Variscan shear zones). According to previous structural studies and Ar-Ar dating of fabrics, this Early Devonian episode took place as the HP-HT units were deformed and thrusted upon the ophiolitic units in the early stages of the Variscan collision.     

Assessment of uncertainties in the response of the African monsoon precipitation to land use change simulated by a regional model

Land use and land cover (LULC) over Africa have changed substantially over the last 60 years and this change has been proposed to affect monsoon circulation and precipitation. This study examines the uncertainties of model simulated response in the African monsoon system and Sahel precipitation due to LULC change using a set of regional model simulations with different combinations of land surface and cumulus parameterization schemes. Although the magnitude of the response covers a broad range of values, most of the simulations show a decline in Sahel precipitation due to the expansion of pasture and croplands at the expense of trees and shrubs and an increase in surface air temperature. The relationship between the model responses to LULC change and the climatologists of the control simulations is also examined. Simulations that are climatologically too dry or too wet compared to observations and reanalyses have weak response to land use change because they are in moisture or energy limited regimes respectively. The ones that lie in between have stronger response to the LULC changes, showing a more significant role in land–atmosphere interactions. Much of the change in precipitation is related to changes in circulation, particularly to the response of the intensity and latitudinal position of the African Easterly Jet, which varies with the changes in meridional surface temperature gradients. The study highlights the need for measurements of the surface fluxes across the meridional cross-section of the Sahel to evaluate models and thereby allowing human impacts such as land use change on the monsoon to be projected more realistically.