Pressure-Dependence of Rare Earth Element Distribution in Amphibolite- and Granulite- Grade Garnets. A LA-ICP-MS Study

Using an excimer (KrF) laser ablation ICP-MS system, we studied the distribution of REE in garnets from metapelites and metabasites from Ivrea-Verbano (Western Alps, Italy) and from the Peña Negra Anatectic Complex (Central Iberia), finding systematic variations that correlate well with the metamorphic grade. Chondrite-normalized REE patterns of garnets from amphibolite-grade metapelites have lower-than-chondrite levels from La to Sm, a very small or no Eu anomaly, and a steep rise in the abundance of heavy REE as the atomic number increases. Metapelitic garnets from the amphibolite-granulite transition have a marked Eu negative anomaly and are enriched in MREE such that Sm is 10-15 times chondrite and the pattern is almost flat from Dy to Yb-Lu. In garnets from granulite-grade metapelites, the intensity of the Eu anomaly and the relative concentration of Nd, Sm, Gd and Tb increase, with almost flat chondrite-normalized patterns from Sm to Lu. Garnets from mafic granulites are remarkably similar to those of metapelitic garnets equilibrated at the same pressure, except for the Eu anomaly. The apparent paradox of enhanced uptake of larger REE ions with increasing pressure is attributed to the 3M²⁺ 2REE³⁺+ vacancy substitution, which produces a net decrease in the dimensions of the unit-cell of garnet. Variations in REE patterns depend essentially on the pressure and have little dependence on either temperature, bulk-composition of garnet, or REE whole-rock composition, so they could represent a new approach for geobarometric studies. The best numerical parameter to express pressure-related variations of REE distribution in garnets is the Gd/Dy ratio which does not seem perceptibly affected by disequilibrium partitioning. The regression equation between GASP pressure and the average Gd/Dy^garnet is P = 3.6 + 5.6 Gd/Dy. This equation seems to be reliable for garnets: (1)equilibrated within a pressure range of 4-9 kbar, (2) coexisting with modal monazite; and (3) with unit-cell dimensions under 11.46 Å.     

The Bayesian detection of discontinuities in a polynomial regression and its application to the cycle-slip problem

This paper deals with the problem of detecting and correcting cycle-slips in Global Navigation Satellite System (GNSS) phase data by exploiting the Bayesian theory. The method is here applied to undifferenced observations, because repairing cycle-slips already at this stage could be a useful pre-processing tool, especially for a network of permanent GNSS stations. If a dual frequency receiver is available, the cycle-slips can be easily detected by combining two phase observations or phase and range observations from a single satellite to a single receiver. These combinations, expressed in a distance unit form, are completely free from the geometry and depend only on the ionospheric effect, on the electronic biases and on the initial integer ambiguities; since these terms are expected to be smooth in time, at least in a short period, a cycle-slip in one or both the two carriers can be modelled as a discontinuity in a polynomial regression. The proposed method consists in applying the Bayesian theory to compute the marginal posterior distribution of the discontinuity epoch and to detect it as a maximum a posteriori (MAP) in a very accurate way. Concerning the cycle-slip correction, a couple of simultaneous integer slips in the two carriers is chosen by maximazing the conditional posterior distribution of the discontinuity amplitude given the detected epoch. Numerical experiments on simulated and real data show that the discontinuities with an amplitude 2 or 3 times larger than the noise standard deviation are successfully identified. This means that the Bayesian approach is able to detect and correct cycle-slips using undifferenced GNSS observations even if the slip occurs by one cycle. A comparison with the scientific software BERNESE 5.0 confirms the good performance of the proposed method, especially when data sampled at high frequency (e.g. every 1 s or every 5 s) are available.     

Comparing access for all: disability-induced accessibility disparity in Lisbon

It is well known that individual impairments create disparities in the accessibility of individuals to opportunities, lengthening the distances or time needed to reach them or even completely impeding access. However, the accurate calculation and representation of these disparities remain a major challenge for urban and transportation planners. In this paper, we adopt the concept of accessibility disparity, originally applied to measure place accessibility by different modes of transport, to measure and represent the accessibility of individuals with physical disabilities compared to those without disabilities. We use spatial network analysis to calculate spatial connectivity and the accessibility of Lisbon’s city center, revealing what we define as ‘disability-induced accessibility disparity’. Our results reveal not only the locations responsible for reduced accessibility, i.e., barriers and/or deterrents to movement, but also how much any given disparity reduces the accessibility of an individual, allowing the use of this methodology by planners to identify critical areas and to design inclusive public spaces.     

Coda Q before and after the eruptions of 13 November 1985, and 1 September 1989, at Nevado del Ruiz Volcano, Colombia

 Coda Q^–1 was calculated at Nevado del Ruiz Volcano (NRV) before and after two phreatomagmatic eruptions (November 1985, September 1989) and for a period of stability (May 1987) using a functional form for coda derived from a single scattering model (Sato 1977). Substantial changes were found before and after the eruptions. The highest value of Q^–1 was found during the November 1985 eruption, an intermediate value for the September 1989 eruption, and the lowest value for May 1987. It seems that the changes in coda Q^–1 at NRV have a still-unknown relationship with the volume or magnitude of the eruption. A relatively strong frequency dependence was found for all periods. Also Q^–1 clearly changed with time, suggesting that the scattering was strong for the eruption of November 1985 and decreased for the eruption of September 1989, and that the intrinsic absorption probably increased. This suggests the possibility that crystallization is taking place in the NRV magma. The clear change of coda Q^–1 before and after the eruptions at NRV also suggests the possibility that coda Q^–1 is a premonitory tool of activity at this volcano. Received: 25 October 1996 / Accepted: 21 January 1998     

Burial and scour around short cylinder under progressive shoaling waves

The results of a laboratory experimental program aimed at better understanding the scour around and burial of heavy cylindrical objects under oscillating flow on a sandy bed are described. This study was motivated by its application to the dynamics of isolated cobbles/mines on a sandy floor under nonlinear progressive waves, such as that occur in shallow coastal waters beyond the wave-breaking region. In the experiments, nonlinear progressive waves were generated in a long wave tank of rectangular cross-section with a bottom slope. Model mines (short cylinders) were placed on the sandy bottom and the temporal evolution of the bed profile and the velocity field in the near field of the object were observed. Experiments were conducted at relatively high Reynolds numbers for a range of flow conditions, which can be characterized by the Keulegan–Carpenter number and Shields parameter. Depending on the values of these parameters, four different scour regimes around the cylinder including periodical burial of cylinder under migrating sand ripples were observed; they were classified as: (i) no scour/burial, (ii) initial scour, (iii) expanded scour, and (iv) periodic burial cases. A scour regime diagram was developed and the demarcation criteria between different regimes were deduced. Semi-empirical formulae that permit estimation of the scour depth with time, the equilibrium maximum scour depth and length, and conditions necessary for the burial of the cylinder as a function of main external parameters are also proposed.     

Tides and mixing in the northwestern East China Sea Part I: Rotating and reversing tidal flows

Bottom-mounted ADV and ADCP instruments in combination with CTD profiling measurements taken along the Chinese coast of the East China Sea were used to study the vertical structure of temperature, salinity, and velocity in reversing tidal currents on a shallow inner shelf and in rotating tidal flows over a deeper sloping bottom of the outer shelf. These two regimes of barotropic tide affect small-scale dynamics in the lower part of the water column differently. The reversing flow was superimposed by seiches of ∼2.3 h period generated in semienclosed Jiaozhou Bay located nearby. As the tidal vector rotates over the sloping bottom, the height of the near-bottom logarithmic layer is subjected to tidal-induced variations. A maximum of horizontal velocity U_max appears at the upper boundary of the log layer during the first half of the current vector rotation from the minor to the major axis of tidal ellipse. In rotating tidal flow, vertical shear generated at the seafloor, propagated slowly to the water interior up to the height of U_max, with a phase speed of ∼5 m/h. The time-shifted shear inside the water column, relative to the shear at the bottom, was associated with periodically changing increases and decreases of the tidal velocity above the log layer toward the sea surface. In reversing flows, the shear generated near the bottom and the shear at the upper levels were almost in phase.     

The impact of hurricanes on sedimenting particulate matter in the semi-arid Bahía de La Paz,Gulf of California

From 2002 through 2004, time-series sediment trap samples were collected from a depth of 410 m in Cuenca Alfonso, Bahía de La Paz, on the SW coast of the Gulf of California. The instrument recorded the impact of the local passage of hurricanes “Ignacio” (24–26 August) and “Marty” (21–23 September) in 2003. These two events accounted for 82% of the total rainfall measured in 2003, equivalent to the annual average precipitation in years without hurricanes. Mean total mass fluxes (TMFs) of 2.88 and 3.58 g m⁻² d⁻¹ were measured during the week of each hurricane as well as the following week. This may have been enough to produce a lamina in the underlying sediment with characteristics peculiar to such events. The terrigenous component was particularly abundant, with notably higher concentrations of Fe, Sc, Co and Cs and REEs. In contrast, TMFs throughout 2002–2004 (excluding the hurricane periods) averaged only 0.73 g m⁻² d⁻¹ and had a larger marine biogenic component. The extraordinary elemental fluxes during the 29 days of hurricane-influenced sedimentation represented a great proportion of the totals over an entire “normal” year: Co (67.8%) >Sc (62.6) >Fe (59.6) >Cs (53.4)>Lu (51.5)>La (51.3)>Yb (51.0)>Ce (49.5) >Tb (48.4) >Sm (44.7)>Cr (36.5) >Ca (31.0)>Eu (25.4%). The terrigenous fraction was calculated using (a) TMF minus the sum of CaCO₃, biogenic silica and organic matter and (b) the ratio of Sc in the trap samples to the average in the Earth's crust. The latter was consistently smaller, but the two methods offered similar results following hurricanes (78% vs. 63%, respectively). For normal sedimentation, however, the difference method yielded values twice as large as the Sc method (58% vs. 30%) This suggests that the mineralogy of the terrigenous fraction may also vary, with unsorted dessert soil being carried to sea by the powerful flash floods associated with hurricanes. Eolian supply of particles, particularly Sc-free quartz grains, possibly from beyond the limited fluvial drainage basin, apparently dominates normal sedimentation.     

Sources and behavior of arsenic and trace elements in groundwater and surface water in the Poopó Lake Basin,Bolivian Altiplano

Water management in semiarid and arid catchments such as the Poopó Lake Basin requires improved understanding of the complex behavior of the various contaminants, which affect the drinking water quality and considered as crucial for sustainable development of the region. Mechanisms of arsenic (As) release in the surface and groundwater were studied. Hydrochemical data for surface water (4 samples) and groundwater (28 samples) were collected in a small watershed in the Poopó catchment at the highland of the Bolivian Andes (Altiplano). All of them show high electrical conductivity values and moderately oxidizing conditions. The surface water contains high concentration of sulfate and the trace elements As, Zn and Pb in the zone affected by acid mine drainage. There is a large variability of the concentration of As and of the trace elements in the groundwater in the five different regions within the Poopó catchment. The metal concentrations sensitive to changes of redox state and results of speciation modeling suggest that As (V) is a predominant aqueous species, which conforms to the prevailing oxidizing conditions in the shallow groundwater environment. Two generalized trends for As distribution were identified in groundwater: (a) high concentrations are found in the arid zone (100–250 μg/L) in the southern (region III) and in the northwestern (region V) regions, and (b) low concentrations (<50 μg/L) are found in the remaining part of the basin (region I, II and IV). However, the spatial distribution within these regions needs to be investigated further. A conclusion from the present study is that there are multiple sources of As as well as other trace elements (such as Cd, Mn and Zn) in the Poopó Lake Basin. Among the sources and the processes which led to the mobility of As and other trace metals in the region are: (a) weathering of sulfide minerals, (b) oxidation of pyrite and/or arsenopyrite in mineralized areas and (c) desorption from hydrous ferric oxide (HFO) surfaces. In non-mining areas, volcanic ash is suggested to be a significant source of As.     

Resting Stages of Plankton in Recent North Adriatic Sediments

Abstract. Plankton-derived resting stages were found in 26 sediment cores collected in the North Adriatic Sea; 46 morphotypes were identified, 38 were attributed to taxa according to their morphology and, in some hatching cases, also according to the morphology of the derived active forms. Six species of Dinophyta were recorded for the first time from the North Adriatic Sea. Each morphotype was described in detail. Twenty-nine resting stages were Dinophyta; one was a Chrysophyta; two were Tintinnina; and six were metazoans. At every site Dinophyta cysts were more abundant than Metazoa cysts. Cyst bank densities were variable, with empty forms generally more abundant than full ones; cyst concentrations were highest at the mouth of the Po River delta.