Variations in some physico-chemical parameters in a hypersaline coastal lagoon of Baja California,Mexico

San Jose lagoon is a hypersaline body of water located in Mexico in the Baja California Peninsula. The lagoon belongs to a system that lies between the fault ridge known as San Jose Creek. Because of its marine origin, it can be considered as thalassohaline, but its isolation from the ocean has brought about changes in its salt composition. It has an area of 13,500 m², a mean depth of 80 cm and a total volume of 10,000 m³. It does not desiccate and can be considered as a permanent lagoon. Seasonal variations are small. TheArtemia population in San Jose produces cysts all year. To determine the physico-chemical conditions inducing permanent production of cysts, temperature, salinity, dissolved oxygen, and pH of the lagoon were monitored, as well as relative humidity and wind conditions in the region in different seasons of the year. From spring to summer, differences of 1 mg L^–1 of O₂, 1°C in water temperature, and 8 g L^–1 in salinity were observed, and from summer to winter differences of 3.3 mg L^–1, 6.5°C, and 14 g L^–1, respectively. Despite small seasonal variations, the lagoon exhibits strong spatial and daily changes that are important for cyst production.     

Age and kinematics of ductile deformation in the Cerro Durazno area, NW Argentina: Significance for orogenic processes operating at the western margin of Gondwana during Ordovician – Silurian times

The Cerro Durazno Pluton belongs to a suite of Paleozoic granitoid intrusions in NW-Argentina, that are central for understanding the tectonic setting of the western margin of Gondwana in Ordovician and Silurian times. The pluton and its host rocks were tectonically overprinted by metamorphic mineral shape fabrics formed under middle greenschist-facies metamorphic conditions and associated with the nearby Agua Rosada Shear Zone. Kinematic analysis of the shear zone based on the geometric relationship between individual segments of the shear plane and principal axes of mineral fabric ellipsoids indicates reverse-sense of shear with a minor component of left-lateral displacement. This is compatible with the kinematics of other ductile deformation zones in this area, collectively forming a network, which accomplished orogen-parallel extension in addition to vertical thickening. Using the Rb–Sr isotopic system, an undeformed pegmatite dike of the Cerro Durazno Pluton was dated at 455.8 ± 3.6 Ma and mineral fabrics of the Agua Rosada Shear Zone formed at middle greenschist-facies metamorphism gave deformation ages of 437.0 ± 3.8 Ma and 428.4 ± 4.5 Ma. Thus, tectonic overprint at low metamorphic grade occurred about 20–30 Ma after terminal magmatism in the Cerro Durazno area. Our data from the Cerro Durazno area and regional considerations suggest that the western margin of Gondwana was characterized by orogen-parallel extension in addition to crustal thickening as well as episodes of magmatism and ductile deformation that varied greatly in time and space.     

Victoria Carbonate-Base Metal Gold Deposit and Its Significance in the Mankayan Mineral District, Luzon, Philippines

Abstract. The Victoria gold deposit is a low-sulfidation style epithermal carbonate-base metal gold deposit discovered in 1995 in the Mankayan mineral district, northern Luzon, Philippines. It occurs just south of a high-sulfidation copper-gold orebody (Lepanto enargite deposit) and a porphyry copper-gold orebody (Far Southeast (FSE) deposit). Radiometric dating of the Victoria mineralization yields ages from 1.6 to 1.1 Ma, similar to ages of the Lepanto enargite deposit. Mineralogical, geochemical, fluid inclusion and sulfur isotope studies suggest that the Victoria deposit is not directly related to the late stage of hydrothermal activity that produced the FSE porphyry copper-gold and the Lepanto enargite deposits. The hydrothermal fluids from which Victoria was formed appear to have been derived from the south, and not from the FSE intrusive center to the northeast. This would suggest a regional south to north hydrothermal gradient, consistent with the similar flow within the FSE porphyry-Lepanto enargite system. On a district scale, structures similar to those of the Victoria deposit in trend and nature would be highly prospective, especially if they occur north of identified plutons and volcanic centers.     

U‐Pb Detrital Zircon Analysis – Results of an Inter‐laboratory Comparison

Inter‐laboratory comparison of laser ablation ICP‐MS and SIMS U‐Pb dating of synthetic detrital zircon samples provides an insight into the state‐of‐the art of sedimentary provenance studies. Here, we report results obtained from ten laboratories that routinely perform this type of work. The achieved level of bias was mostly within ± 2% relative to the ID‐TIMS U‐Pb ages of zircons in the detrital sample, and the variation is likely to be attributed to variable Pb/U elemental fractionation due to zircon matrix differences between the samples and the reference materials used for standardisation. It has been determined that ~ 5% age difference between adjacent age peaks is currently at the limit of what can be routinely resolved by the in situ dating of detrital zircon samples. Precision of individual zircon age determination mostly reflects the data reduction and procedures of measurement uncertainty propagation, and it is largely independent of the instrumentation, analytical technique and reference samples used for standardisation. All laboratories showed a bias towards selection of larger zircon grains for analysis. The experiment confirms the previously published estimates of the minimum number of grains that have to be analysed in order to detect minor zircon age populations in detrital samples.     

Two-Way Regionalized Classification of Multivariate Datasets and its Application to the Assessment of Hydrodynamic Dispersion

Zones of mixing between shallow groundwaters of different composition were unravelled by “two-way regionalized classification,” a technique based on correspondence analysis (CA), cluster analysis (ClA) and discriminant analysis (DA), aided by gridding, map-overlay and contouring tools. The shallow groundwaters are from a granitoid plutonite in the Fundão region (central Portugal). Correspondence analysis detected three natural clusters in the working dataset: 1, weathering; 2, domestic effluents; 3, fertilizers. Cluster analysis set an alternative distribution of the samples by the three clusters. Group memberships obtained by correspondence analysis and by cluster analysis were optimized by discriminant analysis, gridded over the entire Fundão region, and converted into “two-way regionalized classification” memberships as follows: codes 1, 2 or 3 were used when classification by correspondence analysis and cluster analysis produced the same results; code 0 when the grid node was first assigned to cluster 1 and then to cluster 2 or vice versa (mixing between weathering and effluents); code 4 in the other cases (mixing between agriculture and the other influences). Code-3 areas were systematically surrounded by code-4 areas, an observation attributed to hydrodynamic dispersion. Accordingly, the extent of code-4 areas in two orthogonal directions was assumed proportional to the longitudinal and transverse dispersivities of local soils. The results (0.7–16.8 and 0.4–4.3 m, respectively) are acceptable at the macroscopic scale. The ratios between longitudinal and transverse dispersivities (1.2–11.1) are also in agreement with results obtained by other studies.     

Ku– and Ka-band Altimeter Data in the Northwestern Mediterranean Sea: Impact on the Observation of the Coastal Ocean Variability

The strong increase in altimeter measurement errors near land surfaces is a limiting factor for coastal applications. We analyze the performance of the new Ka-band SARAL/AltiKa (SRL) mission in the northwestern Mediterranean Sea. SRL sea surface height (SSH) measurements are compared with those from the Jason-2 Ku-band satellite mission. The results show a significant increase in both quantity and quality of SSH data available near coastlines when using SRL data. Available edited data are 95.1% of SRL compared with 88.6% for Jason-2. Closer than 10 km to the coastline, available SRL data are still about 60% and only about 31% for Jason-2. Comparisons of the altimeter sea level variations are made with available coastal tide gauge data. The differences obtained between altimeter and tide gauge SLA time series are reduced for SRL (3.3 cm in average) compared with Jason-2 (4.2 cm in average), especially closer than 30 km to the land. It results in higher correlations (by 30%) obtained with SRL data. The coastal circulation derived from altimetry using SRL data shows an offshore meandering, which is more stable in time and with larger velocities close to the coast than that derived from Jason-2 observations.     

Quality assessment of digital surface models extracted from WorldView-2 and WorldView-3 stereo pairs over different land covers

Digital surface models (DSMs) extracted from very high resolution (VHR) satellite stereo images are becoming more and more important in a wide range of geoscience applications. The number of software packages available for generating DSMs has been increasing rapidly. The main goal of this work is to explore the capabilities of VHR satellite stereo pairs for DSMs generation over different land-cover objects such as agricultural plastic greenhouses, bare soil and urban areas by using two software packages: (i) OrthoEngine (PCI), based on a hierarchical subpixel mean normalized cross correlation matching method, and (ii) RPC Stereo Processor (RSP), with a modified hierarchical semi-global matching method. Two VHR satellite stereo pairs from WorldView-2 (WV2) and WorldView-3 (WV3) were used to extract the DSMs. A quality assessment on these DSMs on both vertical accuracy and completeness was carried out by considering the following factors: (i) type of sensor (i.e., WV2 or WV3), (ii) software package (i.e., PCI or RSP) and (iii) type of land-cover objects (plastic greenhouses, bare soil and urban areas). A highly accurate light detection and ranging (LiDAR) derived DSM was used as the ground truth for validation. By comparing both software packages, we concluded that regarding DSM completeness, RSP produced significantly (p < 0.05) better scores than PCI for all the sensors and type of land-cover objects. The percentage improvement in completeness by using RSP instead of PCI was approximately 2%, 18% and 26% for bare soil, greenhouses and urban areas respectively. Concerning the vertical accuracy in root mean square error (RMSE), the only factor clearly significant (p < 0.05) was the land cover. Overall, WV3 DSM showed slightly better (not significant) vertical accuracy values than WV2. Finally, both software packages achieved similar vertical accuracy for the different land-cover objects and tested sensors.