Potential nitrate leaching to groundwater from house building

Nitrate pollution has been identified as a major water quality issue in the UK. This study aimed to determine the potential additional loading of nitrate that could arise from the disturbance caused by house construction. The study is centred around the towns of Nottingham and Mansfield, UK, which are situated on a Triassic Sandstone aquifer. Soil samples up to a depth of 2·70 m were taken from seven sites under construction and other land uses. The average nitrogen load was 59 kg ha^?1, which is slightly higher than the nitrate leaching observed when temporary grassland is ploughed in temperate climates. The most important factors involved in nitrogen loss from house building are expected to be previous land use, quantity of total nitrogen after topsoil stripping, and seasonal timing of construction. Copyright © 2006 John Wiley & Sons, Ltd.     

Mesoarchean sanukitoid rocks of the Rio Maria Granite-Greenstone Terrane,Amazonian craton,Brazil

The Archean sanukitoid Rio Maria Granodiorite yielded zircon ages of ～2.87 Ga and is exposed in large domains of the Rio Maria Granite-Greenstone Terrane, southeastern Amazonian craton. It is intrusive in the greenstone belts of the Andorinhas Supergroup, in the Arco Verde Tonalite and Caracol Tonalitic Complex (older TTGs). Archean potassic leucogranites, younger TTGs and the Paleoproterozoic granites of Jamon Suite are intrusive in the Rio Maria Granodiorite.The more abundant rocks of the Rio Maria Granodiorite have granodioritic composition and display medium to coarse even-grained textures. These rocks show generally a gray color with greenish shades due to strongly saussuritized plagioclase, and weak WNW-ESE striking foliation. The significant geochemical contrasts between the occurrences of Rio Maria Granodiorite in different areas suggest that this unit corresponds in fact to a granodioritic suite of rocks derived from similar but distinct magmas. Mingling processes involving the Rio Maria Granodiorite and similar mafic to intermediate magmas are able to explain the constant occurrence of mafic enclaves in the granodiorite.The associated intermediate rocks occur mainly near Bannach, where mostly quartz diorite and quartz monzodiorite are exposed. The dominant rocks are mesocratic, dark-green rocks, with fine to coarse even-grained texture. The Rio Maria Granodiorite and associated intermediate rocks show similar textural and mineralogical aspects. They follow the calc-alkaline series trend in some diagrams. However, they have high-Mg#, Cr, and Ni conjugate with high contents of large ion lithophile elements (LILEs), typical of sanukitoids series. The patterns of rare earth elements of different rocks are similar, with pronounced enrichment in light rare earth elements (LREEs) and strong to moderate fractionation of heavy rare earth elements (HREEs).Field aspects and petrographic and geochemical characteristics denote that the granodiorites and intermediate rocks have sanukitoid affinity. However, geochemical data suggest that the intermediate rocks and the granodiorites are not related by a fractional crystallization process. It is concluded that the intermediate rocks derived from similar sources to the granodiorites, but probably result from a higher degree of melting, being both cogenetic, but not comagmatic rocks.Mineralogical aspects associated with experimental evidence suggest that the Rio Maria Granodiorite magma was relatively water-enriched (>4 wt.%), explaining the presence of hornblende at the liquidus and the absence of clinopyroxene and orthopyroxene in the studied rocks. The occurrence of well-preserved magmatic epidote crystals, admitting that the Rio Maria Granodiorite was emplaced at shallow crustal levels, points to a rapid ascent of the Rio Maria Granodiorite magma.     

1.3–0.9 Ga Oaxaquia (Mexico): Remnant of an arc/backarc on the northern margin of Amazonia

Rocks with ages of ca. 1 Ga occur in central and southern Mexico as inliers surrounded by ubiquitous Mesozoic and Cenozoic rocks. They appear to share a common history consisting of: (i) ca. 1300–1200 Ma arc magmatism and deposition of sediments including evaporites; (ii) ca.1160–1100 Ma intrusion of syenite, granite and anorthosite, the later part of which is synchronous with migmatization; (iii) intrusion of a ca. 1035–1010 Ma anorthosite–gabbro–charnockite–granite (AMCG) suite; (iv) a 1000–980 Ma granulite facies tectonothermal event with a stretching axis parallel to the long axis of Oaxaquia; (v) gradual exhumation at 750 and/or 545 Ma; and (vi) 517 Ma intrusion of an isolated calcalkaline granitoid pluton. The common Precambrian geological record of these outcrops suggests that they belonged to a single terrane (Oaxaquia) and formed a juvenile arc/backarc bordering a continent that underwent collision with, and overthrusting of, the Avalonian arc at 1000–980 Ma. This buried Oaxaquia to 25–30 km and was followed by further supra-subduction zone magmatism at ca. 917 Ma. These Precambrian rocks are unconformably overlain by uppermost Cambrian and Silurian platform rocks containing Gondwanan fauna and ca. 1 detrital zircons of Oaxacan provenance. The neighbouring Mixteca terrane includes lower Paleozoic, rift-passive margin sedimentary rocks that also contain 900–750 Ma detrital zircons probably derived from the Goiás arc in eastern Amazonia. The arc-backarc tectonic setting inferred for the 1300–900 Ma rocks also suggests that Oaxaquia lay on an active periphery of Amazonia until ca. 900 Ma, well after the amalgamation of Rodinia. This precludes a location for Oaxaquia off southern and western Amazonia that are inferred to have been juxtaposed against eastern Laurentia; contiguity with eastern Amazonia is also unlikely given the absence of the 900–750 Ma convergent tectonics in the Goiás arc. This leaves northern Amazonia as the most likely position, a location that requires the least relative displacement between Oaxaquia and Amazonia. The inferred 750 and 545 Ma exhumation episodes of Oaxaquia correspond to two proposed breakup stages of Rodinia.     

Slab melt as metasomatic agent in island arc magma mantle sources, Negros and Batan (Philippines)

Abstract Two new cases of association of adakites with ‘normal’ island arc lavas and transitional adakites are recognized in the islands of Batan and Negros in northern and central Philippines, respectively. The Batan lavas are related to the subduction of the middle Miocene portion of the South China Sea basin along the Manila trench; those of Negros come from the almost aseismic subduction of the middle Miocene Sulu Sea crust along the Negros trench. The occurrence of the Batan adakites is consistent with previous findings showing adakitic glass inclusions within minerals of mantle xenoliths associated with Batan arc lavas. The similarity of adakite ages (1.09 Ma) and that of the metasomatized xenoliths (1 Ma) suggests that both are linked to the same slab‐melting and metasomatic event. Earlier Sr, Pb and Nd‐isotopic studies, however, also reveal the presence of an important sediment contribution to the Batan lava geochemistry. Thus, the role played by slab melts, assumed to have mid‐ocean ridge basalts‐like (MORB) isotopic characteristics, in enriching the Batan subarc mantle is largely masked by the sediment input. The Negros adakites are present only in Mount Cuernos, the volcanic center nearest to the Negros trench. Batch partial melting calculations show that the Negros adakites could be derived from a garnet amphibolitic source with normal‐MORB (N‐MORB) geochemistry. This is supported by the MORB‐like isotopic characteristics of the Mount Cuernos lavas. The volcanic rocks from the other volcanoes consist of normal arc and transitional adakitic lavas that have slightly higher Sr‐ and Pb‐isotopic ratios, probably due to slight sediment input. Mixing of adakites and normal arc lavas to produce transitional adakites is only partly supported by trace element geochemistry and not by field evidence. The transitional adakites can be modeled as partial melts of an adakite‐enriched mantle. Trace element enrichment of non‐adakitic lavas could reflect the interaction of their mantle source with uprising slab melts, as metasomatic mantle minerals scavenge certain trace elements from the adakitic fluids. Therefore, in arcs beneath which thick (up to 2 km) continent‐derived detrital sediments are involved in subduction, like in Batan, the sediment signature can overwhelm the slab melt input. In arcs like Negros where slow subduction could cause a more efficient scraping of thinner (approximately 1 km) detrital sediments, the contribution of slab melts is easier to detect.     

Behavior of Niobium, Tantalum and other high field strength elements in adakites and related lavas from The Philippines

Abstract Pliocene–Quaternary adakites and spatially and temporally associated niobium-enriched basalts (the latter thought to be derived by melting of slab melt-metasomatized mantle) from the Philippine island arcs have been selected for analysis of high field strength elements (HFSE). All these samples have nearly constant and chondritic Zr/Hf ratio (36.5) and slightly infrachondritic Nb/Ta ratio (14.7). We interpret adakitic magmas to be derived from the partial melting at approximately 900°C of subducted mid-ocean ridge basalts (MORB) crust, with rutile and/or ilmenite as residual minerals. Melting calculations show that, under these conditions, slab melts should have suprachondritic Nb/Ta ratios. The obvious discrepancy with our data is attributed to insufficient knowledge of rutile-melt partition coefficients for HFSE. Consequently, abnormal Nb/Ta or Zr/Hf ratios cannot be considered as potential markers of slab melting processes in island arcs.     

Time calibration of a P–T path from a Variscan high-temperature low-pressure metamorphic complex (Bayerische Wald, Germany), and the detection of inherited monazite

A temperature–time path was constructed for high-temperature low-pressure (HT–LP) migmatites of the Bayerische Wald, internal zone of the Variscan belt, Germany. The migmatites are characterised by prograde biotite dehydration melting, peak metamorphic conditions of approximately 850 °C and 0.5–0.7 GPa and retrograde melt crystallisation at 800 °C. The time-calibration of the pressure–temperature path is based on U–Pb dating of single zircon and monazite grains and titanite separates, on ⁴⁰Ar/³⁹Ar ages obtained by incremental heating experiments on hornblende separates, single grains of biotite and K-feldspar, and on ⁴⁰Ar/³⁹Ar spot fusion ages of biotite determined in situ from sample sections. Additionally, crude estimates of the duration of peak metamorphism were derived from garnet zoning patterns, suggesting that peak temperatures of 850 °C cannot have prevailed much longer than 2.5 Ma. The temperature–time paths obtained for two areas approximately 30 km apart do not differ from each other considerably. U–Pb zircon ages reflect crystallisation from melt at 850–800 °C at 323 Ma (southeastern area) and 326 Ma (northwestern area). The U–Pb ages of monazite mainly coincide with those from zircon but are complicated by variable degrees of inheritance. The preservation of inherited monazite and the presence of excess ²⁰⁶Pb resulting from the incorporation of excess ²³⁰Th in monazite formed during HT–LP metamorphism suggest that monazite ages in the migmatites of the Bayerische Wald reflect crystallisation from melt at 850–800 °C and persistence of older grains at these temperatures during a comparatively short thermal peak. The U–Pb ages of titanite (321 Ma) and ⁴⁰Ar/³⁹Ar ages of hornblende (322–316 Ma) and biotite (313–309 Ma) reflect cooling through the respective closure temperatures of approximately 700, 570–500 and 345–310 °C published in the literature. Most of the feldspars' ages (305–296 Ma) probably record cooling below 150–300 °C, while two grains most likely have higher closure temperatures. The temperature–time paths are characterised by a short thermal peak, by moderate average cooling rates and by a decrease in cooling rates from 100 °C/my at temperatures between 850–800 and 700 °C to 11–16 °C/my at temperatures down to 345–310 °C. Further cooling to feldspar closure for Ar was probably even slower. The lack of decompressional features, the moderate average cooling rates and the decline of cooling rates with time are not easily reconciled with a model of asthenospheric heating, rapid uplift and extension due to lithospheric delamination as proposed elsewhere. Instead, the high peak temperatures at comparatively shallow crustal levels along with the short thermal peak require external advective heating by hot mafic or ultramafic material. Received: 7 July 1999 / Accepted: 28 October 1999     

Extraction of Pb with artificially too-old ages during stepwise dissolution experiments on Archean zircon

Stepwise HF-dissolution experiments on five Archean zircon populations reveal very systematic patterns of Pb discrimination, releasing at one point Pb with artificially too-old ²⁰⁷Pb/²⁰⁶Pb ages. The experiments involved a first HF dissolution step for 1 h at room temperature and evaporation on a hot-plate that produces Pb with young ²⁰⁷Pb/²⁰⁶Pb ages, followed by a 4 1/2 h HF dissolution step in an oven at 190°C that liberates the excessively old Pb. The final residue yields in most cases U–Pb data that are consistent with the results obtained by the normal selection, abrasion, and total dissolution procedure. In these examples, the too-old ages cannot be easily explained by the presence of an inherited core component but are more likely to indicate segregation of Pb in zircon sub-domains during thermal annealing episodes early in its history, as has been proposed by other workers. Aside from shedding light on these particular aspects of zircon U–Pb systematics, the combined results also provide geologically relevant information concerning the regional evolution of the western Superior Province in Ontario. An age of 2718±3 Ma for a gabbroic unit from the Quetico Subprovince shows that this was coeval to 2722–2718 Ma ultramafic to felsic igneous rocks in the adjacent Shebandowan greenstone belt, including a gabbro body dated in this study at 2725+17/−11 Ma. These age relationships suggest that volcanic units of the Shebandowan greenstone belt were tectonically imbricated in younger sedimentary rocks of the Quetico basin during late Archean convergence. The other three samples represent felsic intrusive units from Geraldton in the Wabigoon subprovince. An age of 2699±1 Ma for an Au-mineralized feldspar porphyry dyke and identical ages of 2690±1 Ma for two phases of the syn-tectonic Croll Lake stock put constraints on the timing of major deformation and hydrothermal activity in the belt.     

Comparison of the Performance of Fourteen Statistical Tests for Detection of Outlying Values in Geochemical Reference Material Databases

This work presents a comparison of relative efficiency of fourteen statistical tests to detect outliers in normally distributed samples. These tests include deviation/spread, Grubbs-type, Dixon-type, and high-order moment statistics. Performance for the statistical tests is evaluated using Geochemical Reference Material databases from the United States Geological Survey. Test efficiency is compared for the first application of statistics in version k = 1 and k = 2, as well as for tests in version k = 1 applied consecutively against block procedures in which k = 2, 3, or 4 values are evaluated at the same time. In both evaluations, the sensitivity of the statistical tests shows a general strong dependence on sample size. The best performance is observed for the block procedures compared to consecutive statistical tests affected by masking effects.     

Lateral variation and frequency dependence of coda-Q in the southern part of Iberia

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A method based on the coda attenuation law: Q = Q ₀( f/f ₀)^v leads to the determination of the lateral variation of coda- Q in the southern part of the Iberian Peninsula using seismograms belonging to the seismological network of the Cartuja Observatory, located in Granada. The lateral variation of Q ₀ ( Q value corresponding to a reference frequency f ₀ of 1 Hz) and its frequency dependence for the 1 to 5 Hz frequency range are, in general, in agreement with coda- Q values for frequencies less than about 1 Hz, previously determined in the region under study.
To determine the coda- Q values analytical functions have been used to fit the magnification curves of the vertical component short-period seismographs belonging to the Cartuja network. The problem is solved by using least-squares techniques and non-linear inversion. The determined coda- Q ₀ values and its frequency dependence correlate well with several known geophysical parameters in the southern part of the Iberian Peninsula.