Generalized thermostatistics and wavelet analysis of solar wind and proton density variability

In this paper, we analyze the probability density function (PDF) of solar wind velocity and proton density, based on generalized thermostatistics (GT) approach, comparing theoretical results with observational data. The time-series analyzed were obtained from the SOHO satellite mission where measurements were sampled every hour. We present in the investigations data for two years of different solar activity: (a) moderate activity (MA) period (1997) and (b) high activity (HA) period (2000). For the MA period, the results show good agreement between experimental data and GT model. For the HA period, the agreement between experimental and theoretical PDFs was fairly good, but some distortions were observed, probably due to intermittent characteristics of turbulent processes. As a complementary analysis, the global wavelet spectrum (GWS) was obtained, allowing the characterization of the predominant temporal variability scales for both periods and the stochastic aspects of the nonlinear solar wind variability are discussed.     

Numerical and functional representations of regional heat flow in South America

A summary of heat flow data acquired over recent years in several areas in the eastern (Brazil and Paraguay) and western (Bolivia, Chile, Colombia and Ecuador) parts of South American continent are presented. The improvements in the database have allowed numerical representations of heat flow for southeastern and central segments of the Precambrian fold belts in Brazil, Central Andean cordilleras in Chile and Bolivia, Southern Volcanic arc in Peru, Neuquén Province in southwestern Argentina, Chaco basin in Paraguay, Oriente basin in Ecuador and the system of pericratonic basins in north central Colombia. The maps reveal considerable variability in heat flow, not only between the main tectonic units but also within them. The intra-regional variations seem to originate mainly from complexities in local geologic structures while the inter-regional ones seem to point to action of deep-seated tectonic processes. The cordilleran regions are, in general, characterized by relatively high heat flow (>70 mW/m²), compared with the coastal regions to the west and the Pre-cordilleran basins to the east. In the eastern part of the continent, heat flow is low to normal (<60 mW/m²), the exceptions being the Mesozoic rift basins, areas of Cenozoic alkaline intrusions and some isolated belts of overthrust tectonics in the central parts of Brazil. There are indications that heat flow is high in the Patagonian Platform relative to that found in the Brazilian Platform.In addition, polynomial methods were employed for examining large-scale variations of heat flow over the continent. Specifically, a general-purpose least square solution was used to determine the coefficients of up to fourth order in latitude and longitude. Some of the large-scale trends seen in low order polynomial representations seem to be indicative of the nature of deep-seated heat transfer processes. The systematic increase in regional heat flow in the north-south direction is an example. It is considered as the consequence of thermal blanketing effect of the continental segment of the South American lithosphere. Trends seen in higher order polynomials seem to be associated with regional tectonic patterns and subduction-related magmatism. Prominent among these are east-west trending belts of low heat flow in northern Peru and in central Chile, as well as the high heat flow belts in northern Chile, Altiplano of Bolivia and northwestern Argentina. Limitations arising from low data density and uneven geographic distribution warrant higher degree polynomial representations.     

Comparison of Linear Regression Models for Quantitative Geochemical Analysis: An Example Using X-Ray Fluorescence Spectrometry

This paper presents statistical aspects related to the calibration process and a comparison of different regression approaches of relevance to almost all analytical techniques. The models for ordinary least-squares (OLS), weighted least-squares (WLS), and maximum likelihood fitting (MLF) were evaluated and, as a case study, X-ray fluorescence (XRF) calibration curves for major elements in geochemical reference materials were used. The results showed that WLS and MLF models were statistically more consistent in comparison with the usually applied OLS approach. The use of uncertainty on independent and dependent variables during the calibration process and the calculation of final uncertainty on individual results using error propagation equations are the novel aspects of our work.     

Influence of a low-viscosity layer between rigid inclusion and viscous matrix on inclusion rotation and matrix flow: A numerical study

We have used 2-D finite element modelling to investigate the influence of a permanent low-viscosity layer between matrix and inclusion on matrix flow and inclusion rotation under viscous simple shear flow. Rigid inclusions of different shape (circle, square, ellipse, lozenge, rectangle and skewed rectangles) and aspect ratio (R) were used. The calculated matrix flow pattern is neither bow tie nor eye-shaped. It is a new flow pattern that we call cat eyes-shaped, which is characterized by: (i) straight streamlines that slightly bend inwards at the inclusion's crests; (ii) elongate eye-shaped streamlines on each side of the inclusion; (iii) stagnation points in the centre of the eyes; (iv) absence of closed streamlines surrounding the inclusion; (v) changes in flow configuration with inclusion orientation; the lines of flow reversal bend and tilt, closed streamline circuits may disappear, and streamlines may bend outwards at the inclusion's crests.Concerning inclusion rotation, the numerical results show that: (i) a low-viscosity layer (LVL) makes inclusions with R = 1 rotate synthetically, but the rotation rate depends upon shape (circle or square) and orientation. Therefore, shape matters in the slipping mode. (ii) All studied shapes with R > 1 rotate antithetically when starting with the greatest principal axis (e₁) parallel to the shear direction ( = 0°); (iii) rotation is limited because there is a stable equilibrium orientation (_se) for all studied shapes with R > 1. (iii) There is also an unstable equilibrium orientation (_ue), and both _se and _ue depend upon inclusion's R and shape.The present numerical results closely agree with previous results of analogue experiments with a permanent low viscosity interface. Only minor deviations related with small shape differences were detected.     

4: Transpressional tectonics, lower crust decoupling and intrusion of deep mafic sills: A model for the unusual metallogenesis of SW Iberia

SW Iberia is interpreted as an accretionary magmatic belt resulting from the collision between the South Portuguese Zone and the autochthonous Iberian terrane in Variscan times (350 to 330 Ma). In the South Portuguese Zone, pull-apart basins were filled with a thick sequence of siliciclastic sediments and bimodal volcanic rocks that host the giant massive sulphides of the Iberian Pyrite Belt. Massive sulphides precipitated in highly efficient geochemical traps where metal-rich but sulphur-depleted fluids of dominant basinal derivation mixed with sulphide-rich modified seawater. Massive sulphides formed either in porous/reactive volcanic rocks by sub-seafloor replacement, or in dark shale by replacement of mud or by exhalation within confined basins with high biogenic activity. Crustal thinning and magma intrusion were responsible for thermal maturation and dehydration of sedimentary rocks, while magmatic fluids probably had a minor influence on the observed geochemical signatures.The Ossa Morena Zone was a coeval calc-alkaline magmatic arc. It was the site for unusual mineralization, particularly magmatic Ni–(Cu) and hydrothermal Fe-oxide–Cu–Au ores (IOCG). Most magmatism and mineralization took place at local extensional zones along first-order strike-slip faults and thrusts. The source of magmas and IOCG and Ni–(Cu) deposits probably lay in a large mafic–ultramafic layered complex intruded along a detachment at the boundary between the upper and lower crust. Here, juvenile melts extensively interacted with low-grade metamorphic rocks, inducing widespread anatexis, magma contamination and further exsolution of hydrothermal fluids. Hypersaline fluids (δ¹⁸O_fluid > 5.4‰ to 12‰) were focused upward into thrusts and faults, leading to early magnetite mineralization associated with a high-temperature (> 500 °C) albite–actinolite–salite alteration and subsequent copper–gold-bearing vein mineralization at somewhat lower temperatures. Assimilation of sediments by magmas led in turn to the formation of immiscible sulphide and silicate melts that accumulated in the footwall of the layered igneous complex. Further injection of both basic and sulphide-rich magmas into the upper crust led to the formation of Ni–(Cu)-rich breccia pipes.Younger (330 to 280 Ma?) peraluminous granitoids probably reflect the slow ascent of relatively dry and viscous magmas formed by contact anatexis. These granitoids have W–(Sn)- and Pb–Zn-related mineralization that also shows geochemical evidence of major mantle–crust interaction. Late epithermal Hg–(Cu–Sb) and Pb–Zn–(Ag) mineralization was driven by convective hydrothermal cells resulting from the high geothermal gradients that were set up in the zone by intrusion of the layered igneous complex. In all cases, most of the sulphur seems to have been derived from leaching of the host sedimentary rocks (δ³⁴S = 7‰ to 20‰) with only limited mixing with sulphur of magmatic derivation.The metallogenic characteristics of the two terranes are quite different. In the Ossa Morena Zone, juvenile magmatism played a major role as the source of metals, and controlled the styles of mineralization. In the South Portuguese Zone, magmas only acted as heat sources but seem to have had no major influence as sources of metals and fluids, which are dominated by crustal signatures. Most of the magmatic and tectonic features related to the Variscan subduction and collision seem to be masked by those resulting from transpressional deformation and deep mafic intrusion, which led to the development of a metallogenic belt with little resemblance to other accretionary magmatic arcs.     

Characterisation of dispersed organic matter from lower Palaeozoic metasedimentary rocks by organic petrography, X-ray diffraction and micro-Raman spectroscopy analyses

Dispersed organic matter (DOM) concentrates of C-rich rocks from areas with different metamorphic characteristics were studied by organic petrography, X-ray diffraction (XRD) and micro-Raman spectroscopy analysis. The concentrates contain several types of DOM with different morphologies, reflectance, X-ray diffraction and micro-Raman characteristics.Four different morphological types were identified in the two studied areas. The different types have different distributions and their reflectance is quite variable in the four types, with a dominance of the highest reflectance values in the DOM from the area with the highest metamorphic grade.XRD analyses of samples from the areas reveal the presence of fine graphite together with non-graphitised carbons.The Raman spectral profiles show the usual bands G (1582 cm⁻¹) and D1 (1350 cm⁻¹), on the first-order Raman spectrum, and S1 (2700 cm⁻¹) on the second-order spectrum. Additional weaker bands, D2 (1620 cm⁻¹), and more rarely D3 (1500 cm⁻¹) and S2 (2900 cm⁻¹), are present. These are characteristic for disordered carbons in the different types of DOM and in both studied areas. However, the Raman parameters (D1/G intensity area ratio and the frequency and width of G band) indicate variable degrees of organisation in all DOM types.The existence of different types of DOM with different degrees of ordering in the same lithologies and metamorphic grade seems to be related to different organic precursors, as they are graphitised to different extents under the same metamorphic conditions. However, in the same lithologies and metamorphic grade, the existence of various stages of graphitisation within the same type of DOM can only be explained though the interaction of DOM with the metamorphic fluids present in the rocks. The ordering graphitisation process may be due to the existence of metamorphic fluid circulation events with a variety of compositions.     

History of sedimentary infilling and faulting in Subic Bay, Philippines revealed in high-resolution seismic reflection profiles

Subic Bay sediments and faults identified in seismic-reflection profiles were dated using sea-level curves. The oldest sedimentary packages are marine sediments subaerially exposed and eroded 20 ka. Fluvio-marine to wholly marine sediments were deposited during the ensuing transgression, and prograding units were deposited during stillstands or minor sea-level falls. Faults within the bay have three age ranges. The oldest set cuts through the pre-δ¹⁸O Stage 2 rock units, >18 ka; a second disrupts 10.2–11.3 ka sediments; and the youngest, which cut the uppermost sedimentary package, show that movements occurred about every 2 ky, most recently about 3 ka. Northwest–southeast faults that parallel onshore structures associated with Paleogene emplacement of the Zambales Ophiolite Complex to the west and north likely represent rejuvenated tectonism. The northern coastline and north–south-trending axial bay islands appear related to a lineament that dissects Mt Pinatubo farther northeast. A breach in the caldera of Mt Natib is the most likely source of a presumed pyroclastic deposit in the eastern bay that is associated with sediments about 11.3–18 ka, indicating that a Natib eruption occurred much more recently than previously documented for this volcano.     

The Aguablanca Ni–(Cu) sulfide deposit, SW Spain: geologic and geochemical controls and the relationship with a midcrustal layered mafic complex

The Aguablanca Ni–(Cu) sulfide deposit is hosted by a breccia pipe within a gabbro–diorite pluton. The deposit probably formed due to the disruption of a partially crystallized layered mafic complex at about 12–19 km depth and the subsequent emplacement of melts and breccias at shallow levels (<2 km). The ore-hosting breccias are interpreted as fragments of an ultramafic cumulate, which were transported to the near surface along with a molten sulfide melt. Phlogopite Ar–Ar ages are 341–332 Ma in the breccia pipe, and 338–334 Ma in the layered mafic complex, and are similar to recently reported U–Pb ages of the host Aguablanca Stock and other nearby calc-alkaline metaluminous intrusions (ca. 350–330 Ma). Ore deposition resulted from the combination of two critical factors, the emplacement of a layered mafic complex deep in the continental crust and the development of small dilational structures along transcrustal strike-slip faults that triggered the forceful intrusion of magmas to shallow levels. The emplacement of basaltic magmas in the lower middle crust was accompanied by major interaction with the host rocks, immiscibility of a sulfide melt, and the formation of a magma chamber with ultramafic cumulates and sulfide melt at the bottom and a vertically zoned mafic to intermediate magmas above. Dismembered bodies of mafic/ultramafic rocks thought to be parts of the complex crop out about 50 km southwest of the deposit in a tectonically uplifted block (Cortegana Igneous Complex, Aracena Massif). Reactivation of Variscan structures that merged at the depth of the mafic complex led to sequential extraction of melts, cumulates, and sulfide magma. Lithogeochemistry and Sr and Nd isotope data of the Aguablanca Stock reflect the mixing from two distinct reservoirs, i.e., an evolved siliciclastic middle-upper continental crust and a primitive tholeiitic melt. Crustal contamination in the deep magma chamber was so intense that orthopyroxene replaced olivine as the main mineral phase controlling the early fractional crystallization of the melt. Geochemical evidence includes enrichment in SiO₂ and incompatible elements, and Sr and Nd isotope compositions (⁸⁷Sr/⁸⁶Sr_i 0.708–0.710; ¹⁴³Nd/¹⁴⁴Nd_i 0.512–0.513). However, rocks of the Cortegana Igneous Complex have low initial ⁸⁷Sr/⁸⁶Sr and high initial ¹⁴³Nd/¹⁴⁴Nd values suggesting contamination by lower crustal rocks. Comparison of the geochemical and geological features of igneous rocks in the Aguablanca deposit and the Cortegana Igneous Complex indicates that, although probably part of the same magmatic system, they are rather different and the rocks of the Cortegana Igneous Complex were not the direct source of the Aguablanca deposit. Crust–magma interaction was a complex process, and the generation of orebodies was controlled by local but highly variable factors. The model for the formation of the Aguablanca deposit presented in this study implies that dense sulfide melts can effectively travel long distances through the continental crust and that dilational zones within compressional belts can effectively focus such melt transport into shallow environments.Electronic supplementary material Supplementary material is available in the online version of this article at and is accessible for authorized users.