Extinction versus backscatter relationships for lidar applications at 351 nm: maritime and desert aerosol simulations and comparison with observations

Functional relationships linking at λ₀=351 nm aerosol extinction α_λ0^aer and backscatter coefficient β_λ0^aer of maritime and desert type aerosols are determined to allow for inversion of the single-wavelength lidar signals. Such relationships are derived as mean behavior of 20,000 extinction versus backscatter computations, performed for aerosol size distributions and compositions whose describing parameters are randomly chosen within the naturally observed variability. For desert-type aerosols, the effect of the particle non-sphericity is considered and it is shown that the extinction to backscatter ratio of non-spherical dust particles can be up to 60% larger than the values obtained for spherical particles. Aerosol extinction and backscatter coefficient profiles obtained inverting the single-wavelength lidar signal with the modeled relationships are then compared to the same profiles measured by a combined elastic-Raman lidar operating at 351 nm. Analytical back trajectories and satellite images are used to characterize advection patterns during lidar measurements and to properly choose the modeled functional relationship. A good accordance between the two techniques is found for advection patterns over the lidar site typical of maritime and dust conditions. Maximum differences between the model-based α_λ0^aer and β_λ0^aer vertical profiles and the corresponding ones measured by the combined elastic-Raman lidar technique are of 30% and 40% in maritime and desert dust conditions, respectively. The comparison of elastic-Raman lidar measurements and model-based results also reveals that particle non-sphericity must be taken into account when mineral dust-type aerosols are directly advected over the measurement site.     

Numerical investigation of small- and medium-diameter drain wells to stabilise deep landslides

The stabilisation of deep landslides is still a challenge for geotechnical engineers, mainly due to the high cost of structural control works that generally lead engineers to opt for drain systems. Unfortunately there are operative difficulties affecting excavation of deep drain trenches in soils dislocated by landslides (especially as regards the provisional support of the excavation walls). Small- and medium-diameter wells are a valid alternative in deep landslides, being less expensive than large-diameter wells equipped with horizontal pipes and simpler to construct than deep trenches. However, no technical procedures for their proper design are reported in the literature: design criteria commonly used in practice are derived from pumping problems and are largely inadequate, being based on Dupuit’s hypothesis that presumes stream lines to be horizontal. This paper presents numerical solutions obtained from three-dimensional seepage and consolidation analyses of a slope drained by small- and medium-diameter wells, arranged according to various positions, showing that the efficiency of the well system decreases as the depth of the landslide slip surface increases. Comparison is also made between well systems and deep trenches occupying the same draining volume in the landslide body, showing that the former attains much greater efficiency than the latter. Non-dimensional abaci for the square grid of wells (which is the most effective arrangement) are reported herein to be used for practical purposes.

     

Short-range order in tourmaline: a vibrational spectroscopic approach to elbaite

Polarized Fourier-transform infrared and Raman spectra were acquired on an elbaite sample previously characterized by electron- and ion microprobe analysis, X-ray diffraction and structure refinement. Spectra from the two vibrational spectroscopy techniques reveal a close similarity in the OH-stretching region, with three main absorption bands strongly polarized in the c-axis direction. By means of bond-valence theory arguments, the observed OH bands are interpreted and assigned to specific local cation arrangements around the O1 (≡W) and O3 (≡V) anion sites. In combination with the relatively simple composition of the studied sample, bond-valence constraints are used to identify stable anion-cation arrangements, which permit the occurrence of short-range ordering to be assessed. Evidence for nearly complete short-range order at the O1 site, with the stable arrangements ^Y(LiAlAl)_0.6–^W(OH)_0.6 and ^Y(LiLiAl)_0.4–^W(F)_0.4, are presented. These two local arrangements can be further expanded to obtain the larger ordered clusters [^W(OH)–^Y(LiAl₂)–^V(OH)₃–^Z(Al)₆]_0.6 and [^W(F)–^Y(Li₂Al)–^V(OH)₃–^Z(Al)₆]_0.4.