An electrochemical study of pyrite oxidation in the presence of carbon coatings in cyanide medium

The anodic and cathodic behaviour of pyrite with clay and different carbon coatings of activated carbon, graphite and carbonaceous matter in cyanide medium was investigated using the potentiodynamic method. The presence of clay coating did not change the polarisation curve appearance for either the anodic oxidation of pyrite or the cathodic reduction of oxygen or the potential of the current plateau, but only decreased the plateau current especially at a higher coating thickness. The presence of the carbon coatings marginally shifted the rest potential for pyrite to a more anodic position and slightly changed the polarisation curve appearance for pyrite oxidation. The current density for pyrite oxidation largely increased in the presence of the carbon coatings, the potential at the plateau shifted to more cathodic positions, and the plateau width became smaller. These effects became more noticeable at a higher coating thickness. The activated carbon, graphite and carbonaceous matter coatings performed similarly in affecting pyrite oxidation at a similar thickness. The carbon coatings significantly increased the limiting current densities for oxygen reduction on pyrite, and the limiting current plateau became steeper at a higher coating thickness. The carbon coatings increased the limiting current density for oxygen reduction to a similar extent at a low coating thickness, but increased to varied extents at a higher coating thickness. The carbon coatings also greatly increased the cathodic current density for gold reduction on pyrite. The enhancement of pyrite oxidation and oxygen or gold reduction on pyrite by the carbon coatings was likely attributed to the electrochemical interaction between pyrite and the carbon materials with electron-rich surfaces and high conductivity. The presence of the carbon coatings significantly increased the oxidation of pyrite in aerated cyanide solutions and the preg-robbing of pyrite especially at a higher coating thickness.     

广州科学城保利林语山庄高边坡支护工程的实践

主要介绍了广州科学城保利林语山庄高边坡支护设计方案与施工方法。支护方案综合采用了锚索、锚杆、抗滑桩、钢管桩、格构梁及挡土墙等多种支护方法，有效地提高了边坡的稳定性。应用有限元方法来验证设计方案的合理性，模拟结果与工程实践基本吻合。     

基于国际经验的西部经济发展与生态建设互动途径研究

本文在分析巴西、印度等发展中国家和美国、德国等发达国家经济发展和生态环境建设经验的基础上,针对我国西部农村贫困和产业落后等影响经济、生态的制约因素,提出了西部经济发展与生态建设互动的一些有效途径,以期对最终实现西部经济发展与生态建设的双赢有所启示。     

Toxicities of p-nitrotoluenes and their effects on blood corpuscles and ovaries in Crusian carps (Carassius auratus)

p-nitrotoluene is an important organic intermediate widely used in pesticide, foamed plastics, dyestuff and medicine industries. In this paper, Crusian carps (Carassius auratus) were exposed to dilute p-nitrotoluene solutions with different concentrations of 0, 20, 40, 80, 120, 160, 240 and 320 μg/L; the subsequent physiological responses to the chemical were observed, and the variation characteristics of blood corpuscles, ovaries and oocytes were studied by bio-microscopy. Results showed that even very low concentrations of p-nitrotoluene would lead to toxicosis and even the death of Carassius auratus. The bio-microscopic structures revealed that, compared with the compartment of Carassius auratus growing in the p-nitrotoluene-free water (the control group), the lower concentrations of p-nitrotoluene (for example no more than 80 μg/L) would result in the faster disintegration of erythrocytes and the significant enlargement of oocytes, while the higher contents of p-nitrotoluene (no less than 240 μg/L in this case) would inhibit the division of cells and their further growth, even degenerate blood corpuscles and ovaries, suggesting stronger estrogenic activities. The study is financially supported by the Development Foundation of Science and Technology under Shandong Provincial Education Department (No. J05D51).     

政府办公自动化系统建设和应用浅谈

本文简要地介绍了办公自动化的发展过程,分析了其常用的功能、特点,以及内容分类,论述了目前办公自动化系统的技术支撑和实现,并指出政府办公自动化系统在开发和应用中存在的问题和解决思路。对系统的推广使用具有一定的参考意义。     

地学自由曲面径向基函数网络重建的详细算法

径向基函数(RadialBasisFunction,简称RBF)神经网络是一种理想的地学离散数据网格化工具,能够适应各种不同分布形式和边界条件的数据,收敛速度较快,可以逼近任何复杂曲面。这里详细介绍了RBF神经网络的算法。适当径向基函数的形式和偏差系数是使用RBF神经网络作地学曲面重建的关键。大量的实际数据验证结果表明,当选用Gauss型径向基函数时,一般可获得比较理想的网格化效果,同时具备"曲面平滑"和"拟合度高"的特点。     

迭代折射静校正技术在鄂北地震资料处理中的应用

在低速层速度(地表直达波)已知的条件下,利用生产炮初至信息,用加权最小平方法和共轭梯度法建立的折射静校正数学模型,迭代求取长波长、短波长静校正量,在解决鄂尔多斯盆地北部的虚假小幅度构造问题及改善剖面质量方面取得了明显的效果。     

HD-4002型综合测井仪

HD 4002型综合测井仪是核工业北京地质研究院于1998年开始研制的, 其目标是为铀矿地质系统提供适合砂岩型铀矿勘查的轻便型数字测井仪, 满足测井生产的需要。该仪器于2001 年3月通过部级鉴定, 2002至2003年投入海拉尔盆地铀矿勘查测井试生产。本文介绍了仪器的用途、功能及特点、性能指标, 简要说明了各部分的工作原理。     

冲绳海槽玄武岩中中酸性残余熔体研究及其岩石学意义

与洋壳有关的酸性岩由于对了解幔源岩浆的演化以及判别古老蛇绿岩套及其构造位置的重要意义而倍受岩石学家和构造地质学家的关注。本对发现于冲绳海槽玄武岩基质中的中酸性到酸性残余熔体进行了详细研究，它们提供了幔源玄武岩浆结晶分异形成酸性岩浆的直接证据。在细小的基质矿物间分布有一种玻璃质的残余熔体，其成分随距冷凝边距离(L)的增加而越来越酸性。在SiO2对Na2O K2O图解上，残余熔体的投影点从玄武岩到英安岩均有分布，反映了一个连续的演化系列。在AFM图解上，残余熔体表现出与Thingmuli火山岩系列类似的拉斑玄武岩系列的演化趋势。我们的研究表明：残余熔体的演化受结晶分异作用控制。在早期结晶阶段，辉石的结晶起主导作用，结果造成残余熔体中SiO2、Al2O3，Na2O的迅速增加，FeO、MgO、CaO迅速降低。在晚期结晶阶段，斜长石成为主导结晶相，导致残余熔体中Al2O3，Na2O的迅速消减。Al2O3、Na2O从增加到降低的转变出现在SiO2=62％左右。在L=27．5mm处，85～90％的基质岩浆已发生了结晶作用，导致残余熔体中SiO2含量达到69～70％，而且此处还新出现了一种富FeTi的氧化物。该玄武岩中残余熔体和基质矿物的成分及演化特征分别与Thingmuli火山岩系列中酸性端元的组成相似，在也佐证了Thingmuli火山岩系列是幔源岩浆结晶分异的产物.