天然气运移的气体同位素地球化学示踪

本文通过鄂尔多斯等含油气盆地内岩石酸解烃、罐顶气和同源多产层天然气碳同位素组成的变化，从实例剖析出发，探讨了天然气运移时气体同位素组成的变化及其对天然气运移的示踪。天然气在通过沉积地层中孔隙系统和微裂隙运移时，天然气中的甲烷碳同位素会发生一定的分馏，而乙烷以上重烃碳同位素几乎不发生分馏；在天然气层所在深度，罐顶气甲烷碳同位素组成与天然气一致，在天然气层附近，罐顶气甲烷碳同位素则明显偏离了热演化趋势线；烃源岩酸解烃与其同源的天然气重烃碳同位素组成具有较好的一致性和可比性。由此，可利用气体组分碳同位素的上述变化特征，追索天然气的运移作用。     

Tin mineralization in the Dajing tin–polymetallic deposit, Inner Mongolia, China

Dajing is a large-scale tin–polymetallic deposit that hosts the largest tin mine in North China. It is a hydrothermal vein-type deposit containing Sn, Cu, Pb, Zn, Ag, and minor components Co and In. The deposit consists of more than 690 veins hosted within Upper Permian sedimentary rocks.Three mineralization stages and six ore types are recognized with cassiterite constituting the dominant tin mineral. The SnO₂ content of cassiterite increases in the sequence of mineralization stages shear-deformation→cassiterite–quartz→cassiterite–sulfide (or chalcopyrite–pyrite) stage, while the content of FeO, TiO₂, Nb₂O₅, Ta₂O₅, and In₂O₅ tends to decrease with increases in NiO and Ga₂O₅. It is considered that the negative correlation between SnO₂ and FeO, Nb₂O₅, Ta₂O₅, and In₂O₅ results from elemental substitutions. The early stage cassiterite is much richer in Ta and the later stage cassiterite is much poorer in Ti and Fe than is usual in hydrothermal vein type tin deposits. This is interpreted to indicate that the component of early stage cassiterite reflects a granitic magma source while the composition of later stage cassiterite has a more obvious strata source. The compositional variation of cassiterite corresponds to decreasing crystallization temperatures within each stage and between sequential stages with time. The characteristics of REE in cassiterite from two stages are in accord with that of subvolcanic rocks and the Linxi formation. It suggests that tin transported during the cassiterite–quartz stage may have originated from subvolcanic dikes (e.g., dacite porphyry), while in the cassiterite–sulfide stage, tin may have been derived from wallrock (e.g. siltstone) of the Upper Permian-age Linxi Formation.     

拉斯曼丘陵新生代剥露作用的裂变径迹证据

在西南极和横贯南极山脉地区,新生代裂谷和剥露作用非常普遍。但是,文献中很少记录东南极地区的新生代剥露作用。文中根据东南极普里兹湾拉斯曼丘陵地质样品的磷灰石裂变径迹年龄和热历史的模拟,认为在东南极海岸边缘存在新生代的隆升和伸展作用,其年龄为始于(49.8±12)Ma。该年龄略晚于西南极裂谷系的启动年龄(约60~50Ma)。由于差异隆升作用,在拉斯曼丘陵地区发育了更新的正断层作用——拉斯曼丘陵拆离断层的新活动,其年龄为约5.4Ma。东南极周缘新生代裂谷和伸展作用的普遍存在,是冈瓦纳裂解以来大陆分离和印度洋形成的结果。     

零价铁去除Cr（Ⅵ）的批实验研究

零价铁去除Cr(Ⅵ)的一系列批实验结果表明：水溶液中发生的氧化还原反应符合准一级反应；对于相同粒度的铁屑(比表面积2．89m^2／g)，固液比由05g／100mL增加到2．0g／100mL，Cr(Ⅵ)质量浓度达到排放标准所需反应时间从26．7min降为3．6min；在固液比相同、原水中Cr(Ⅵ)质量浓度不超过30mg／L时，原水质量浓度增大，达到饮用水标准的反应时间增加；其他条件相同，升高温度可提高零价铁与Cr(Ⅵ)的反应速率。     

西藏高原大地电磁深探测———亚东—巴木错沿线地区壳幔电性结构

摘 要　 展示了超宽频带大地电磁深探测所获得的西藏亚东—巴木错沿线地区电性结构图像; 阐述了西藏中、南部特殊的壳幔电性特征。     

Bearing Capacity of Two-Layered Artificial Ground with Firm Crust and Weak Subgrade Under Circular Pressure

Classical bearing capacity expressions can not afford variant engineering requests, since they were deducted under hypotheses of strip footing on homogeneous soil. An often met case was taken into account that circular footing on two-layered ground, which has firm crust and weak subgrade. Weighted method and layered method were used in capacity deduction, respectively. The former counts layered soils as single layer of weighted structure and material parameters. But it is restricted to conditions with close strength to each layer. The latter is preferred in engineering calculation, which regards the whole bearing capacity as subgrade’s capacity under the influence of the upper layer. Thus the issue is transformed to K. Terzaghi model plus stress reduction and dispersion effects. At last, the expressions gained from both methods and finite element analysis (FEA) were used in an example calculation, respectively. It approves layered calculating method and suggests the corresponding security coefficient based on elastoplastic FEA results.     

修正的镜质体反射率剥蚀厚度恢复方法

针对目前用的地层剥蚀厚度恢复镜质体反射率差值法所存在问题,在考察地层沉降、抬升、再沉降埋藏史过程的基础上,根据有机质演化累积性和不可逆性原则,利用经典的有机质成熟度时温关系模型（ＴＴＩ）,建立了修正的镜质体反射率剥蚀厚度恢复方法。该方法不仅考虑了剥蚀界面上下镜质体反射率的相对值,还考虑了各自绝对量,与以往仅考虑镜质体反射率差值相比,有较大改进。     

龙门山前山断裂大地震原地重复发生的地质地貌证据

龙门山前山断裂大地震是原地重复发生的吗？针对这一问题,对前山断裂的同震地表形变带进行了追踪,并选择5.12汶川地震区九龙、白鹿以及汉旺等3个地点开展了古地震探槽研究工作。调查结果是： 前山断裂5.12地震地表形变带基本沿1 ∶200000地质图上先存基岩断裂发育,但仅限于通济－安昌以南段; 白鹿－八角一带同震地表形变带继承先存断层陡坎或断层沟谷发育; 偏离先存断裂而被一些学者视为断裂全新世活动重要证据的永安附近T1阶地上线性陡坎实为废弃河岸; 白鹿、汉旺探槽剖面揭示这两个地点5.12汶川地震之前至少有过一次古地震事件。这些研究结果表明前山断裂大地震是沿晚第四纪活动断裂原地重复发生的,此次地震是沿先存活动断裂又一次发生的大地震事件,为大地震原地复发模型提供了一个新的震例支持。在沿该断裂周边进行规划建设时应当合理避让。     

西藏罗布莎铬铁矿区高海拔巨厚覆盖层钻探技术

西藏罗布莎铬铁矿区海拔高、覆盖层厚、地质条件复杂,岩层破碎、裂隙发育,局部岩层水溶、水蚀、水敏,存在地层漏失、缩径等钻探难题。本文总结了该区28个中深钻孔施工经验,包括：钻孔结构、钻进工艺、冲洗液、护壁堵漏技术、复杂情况采取的技术措施等,取得了较好的效果,各项指标满足设计要求,岩（矿）心采取率达到90%以上,台月效率555 m,各项质量指标均符合设计要求。     

有色示踪剂模拟槽实验图像分析法

图像分析法是处理有色示踪剂模拟槽实验结果的常用方法之一。本文以食用亮蓝为示踪剂,从污染物的检测精度和污染羽描绘的准确度两个方面将图像分析法与传统取样法进行对比,并利用Matlab编程对模拟槽内的污染物贮存质量进行定量计算。结果表明,与传统取样法结果相比：图像分析法的检测精度可提高1个数量级;污染羽的描绘准确度至少可提高3%左右,在实验所设置的非均质条件下可提高17%左右。利用自行编制的Matlab程序对本实验模拟槽内贮存亮蓝质量进行计算可得,当剖分格数为3 700²（1 369万）时,亮蓝贮存质量的计算值最接近实测值,最小误差仅为0.5%。综合来讲,图像分析法是一种准确度高、空间分辨率高的信息采集和处理手段,可实现对非均质地层中有色示踪剂运移过程更为精细的描述。