Pressure-Dependence of Rare Earth Element Distribution in Amphibolite- and Granulite- Grade Garnets. A LA-ICP-MS Study

Using an excimer (KrF) laser ablation ICP-MS system, we studied the distribution of REE in garnets from metapelites and metabasites from Ivrea-Verbano (Western Alps, Italy) and from the Peña Negra Anatectic Complex (Central Iberia), finding systematic variations that correlate well with the metamorphic grade. Chondrite-normalized REE patterns of garnets from amphibolite-grade metapelites have lower-than-chondrite levels from La to Sm, a very small or no Eu anomaly, and a steep rise in the abundance of heavy REE as the atomic number increases. Metapelitic garnets from the amphibolite-granulite transition have a marked Eu negative anomaly and are enriched in MREE such that Sm is 10-15 times chondrite and the pattern is almost flat from Dy to Yb-Lu. In garnets from granulite-grade metapelites, the intensity of the Eu anomaly and the relative concentration of Nd, Sm, Gd and Tb increase, with almost flat chondrite-normalized patterns from Sm to Lu. Garnets from mafic granulites are remarkably similar to those of metapelitic garnets equilibrated at the same pressure, except for the Eu anomaly. The apparent paradox of enhanced uptake of larger REE ions with increasing pressure is attributed to the 3M²⁺ 2REE³⁺+ vacancy substitution, which produces a net decrease in the dimensions of the unit-cell of garnet. Variations in REE patterns depend essentially on the pressure and have little dependence on either temperature, bulk-composition of garnet, or REE whole-rock composition, so they could represent a new approach for geobarometric studies. The best numerical parameter to express pressure-related variations of REE distribution in garnets is the Gd/Dy ratio which does not seem perceptibly affected by disequilibrium partitioning. The regression equation between GASP pressure and the average Gd/Dy^garnet is P = 3.6 + 5.6 Gd/Dy. This equation seems to be reliable for garnets: (1)equilibrated within a pressure range of 4-9 kbar, (2) coexisting with modal monazite; and (3) with unit-cell dimensions under 11.46 Å.     

Critical evaluation of the customisation process of the UNDRR disaster resilience scorecard for cities to earthquake-induced soil liquefaction disaster events

Bulletin of Earthquake Engineering - As cities become larger and more densely populated the impacts of major earthquake events on city communities become more severe. Improving community resilience...     

A New Method for the Estimation of Avalanche Distance Exceeded Probabilities

A crucial point in any methodology for avalanche hazard assessment is the evaluation of avalanche distance exceeded probability, i.e., the annual probability that any assigned location along a given path is reached or exceeded by an avalanche. Typically this problem is faced by estimating the snow volume in the starting zone that is likely to accumulate an average every T years by statistical analysis of snowfall record, and then using this volume as input to an appropriately calibrated avalanche dynamics model to determine the runout distancesfor this design event. This methodology identifies the areas that canbe affected by an avalanche for the considered value of the return period (i.e. the average interval of time for a certain event to repeat itself), ¯T. However, it does not allow us to evaluate the actual avalanche encounter probability for any given point in the runout zone. In the present work this probability is computed by numerical integration of the expression P(x) = ∫₀ ^∞ P^*(V)f(V) dV, where f is the probabilitydensity function (PDF) of the avalanche release volume V, and P^* is the probability of the point x being reached or passed by an avalanche if the release volume is V; this latter probability is calculated by avalanche dynamics simulations. The procedure is implemented using a one-dimensional hydraulic-continuum avalanche dynamic model, calibrated on data from different Italian Alpine ranges, and is applied to a real world hazard mapping problem.     

Coexisting tectonic settings: the example of the southern Tyrrhenian Sea

We performed geodetic strain rate analyses in southern Italy, using new GPS velocities. Two-dimensional strain and rotation rate fields were estimated and results show that most of the shortening is distributed in the northern Sicily offshore. Extension becomes more evident and comparable with shortening on the eastern side of the same margin, and greater in the eastern Sicily offshore. Principal shortening and extension rate axes are consistent with long-term geological features: seismic reflection profiles show both active compressive and extensional faults affecting Pleistocene strata. We show evidence for contemporaneous extension and transtension in the Cefalù Basin. Combining geodetic data and geological features point to the coexistence of independent geodynamic processes, i.e., the active E–W backarc spreading in the hangingwall of the Apennines subduction zone and shortening along the southern margin of the Tyrrhenian backarc basin operated by the NNW-motion of Africa relative to Eurasia.     

Physicochemical properties of fine aerosols at Plan d'Aups during ESCOMPTE

The physical and chemical properties of aerosol particles were investigated at Plan d'Aups, one of the ESCOMPTE sites located in the St. Baume mountain area (700 m a.s.l.), 50 km east of Marseilles (France). The site is ideally located for assessing the vertical and horizontal extent of the pollution plume from the Marseilles–Berre area.Our study showed that polluted air masses from the Marseilles–Berre area are advected to Plan d'Aups in the early afternoon. Average daily concentration of particles reaches up to 40 μg m⁻³ while 1-h average particle number concentration is greater than 30,000 cm⁻³. Most of the particle mass is composed of SO₄²⁻ and organic carbon (OC). The chemical properties of the particles revealed that an additional source, possibly from the industrial area of Gardanne, contributes to the aerosol mass. This last source is characterised by significant emissions of elements, such as Zn, V, Al and Si.In addition to transport, we found that gas-to-particle conversion takes place at the interface between the free troposphere and the boundary layer. We estimated that on average, 30% of the particle number is accounted for by direct nucleation. This is potentially a major aerosol source to the free troposphere.     

Assessing degradation capability of aerobic indigenous microflora in PAH-contaminated brackish sediments

A study was conducted to determine polycyclic aromatic hydrocarbons (PAHs) distribution and microbial population changes in brackish sediments from an Italian lagoon included in the Ramsar List of Wetlands of International Importance. The presence and level of PAH-degrading bacteria were estimated by the most probable number (MPN) enumeration technique, whereas degradation capability towards target compounds was checked against loss of spiked PAHs (Phenanthrene, Anthracene and Fluoranthene) in MPN tubes after incubation in optimal conditions. Chemical analyses and microbiological counts suggested a potential for PAHs biodegradation by natural occurring populations of sediment microorganisms, thus indicating an "optimal range" in sediment PAHs concentrations, outside of which the natural selection of the indigenous microflora did not occur. The MPN procedure here described, provided an effective and reliable way to simultaneously determine microbial population densities and subsequent confirmation of the biodegradation capability of sediment indigenous microflora when exposed to laboratory and environmental concentrations of PAHs.     

Fungal colonies in open fractures of subseafloor basalt

The deep subseafloor crust is one of the few great frontiers of unknown biology on Earth and, still today, the notion of the deep biosphere is commonly based on the fossil record. Interpretation of palaeobiological information is thus central in the exploration of this hidden biosphere and, for each new discovery, criteria used to establish biogenicity are challenged and need careful consideration. In this paper networks of fossilized filamentous structures are for the first time described in open fractures of subseafloor basalts collected at the Emperor Seamounts, Pacific Ocean. These structures have been investigated with optical microscopy, environmental scanning electron microscope, energy dispersive spectrometer, X-ray powder diffraction as well as synchrotron-radiation X-ray tomographic microscopy, and interpreted as fossilized fungal mycelia. Morphological features such as hyphae, yeast-like growth and sclerotia were observed. The fossilized fungi are mineralized by montmorillonite, a process that probably began while the fungi were alive. It seems plausible that the fungi produced mucilaginous polysaccharides and/or extracellular polymeric substances that attracted minerals or clay particles, resulting in complete fossilization by montmorillonite. The findings are in agreement with previous observations of fossilized fungi in subseafloor basalts and establish fungi as regular inhabitants of such settings. They further show that fossilized microorganisms are not restricted to pore spaces filled by secondary mineralizations but can be found in open pore spaces as well. This challenges standard protocols for establishing biogenicity and calls for extra care in data interpretation.     

Food Diaries to Measure Food Access: A Case Study from Rural Cuba

This article aims to make a contribution to current debates in the literature on food access by describing a mixed-methods approach to study the access to food in one rural community in Cuba. Each of the forty households in our study was asked to complete a detailed food diary in which they indicated what they ate and where they acquired each of the ingredients that they used for a full week. Although in Cuba the state plays a central role in organizing the distribution of food items, this method revealed a much more complex web of rural food access. By addressing alternative networks of food access and informal social relations, we aim to show how the use of food diaries, in combination with qualitative data from interviews and participant observation, can provide detailed insights in the complex processes and networks of food access.