Soluble organic compounds in fog and cloud droplets: what have we learned over the past few years?

We have recently set up a new procedure for characterising the water soluble organic compounds (WSOC) in fog water, for which information is still rather limited. Fog samples collected during the 1998–1999 fall–winter season in the Po Valley (Italy) were analysed following this procedure, which allows a quantitative determination of three main classes of organic compounds (neutral species, mono- and di-carboxylic acids, polycarboxylic acids), together accounting for ca. 85% of the total WSOC. This procedure also provides information on the main chemical characteristics of these three classes of compounds (functional groups, aliphatic vs. aromatic character, etc.). The enhanced chemical knowledge on fog/cloud chemical composition opens new scenarios as far as chemical and microphysical processes in clouds and fogs are concerned.     

Analysis of a regional change in the sign of the SAM�Ctemperature relationship in Antarctica

This study examines regional atmospheric circulation changes associated with a reversal in the sign of the relationship between the Southern Annular Mode (SAM) and near-surface temperatures at Halley station, East Antarctica, during the 1980s. We show that the key factor affecting the regional SAM?Ctemperature relationship (STR) is the relative magnitude of two climatological low pressure centres to the west and east of the area, which determines the source region of air masses advected into the locality. The principal difference affecting the STR is shown to be a trend towards a significantly weaker climatological low (higher pressure) at ~20°E during a positive phase of the SAM. Specifically, it is variations in the phase and magnitude of the wave number three patterns of atmospheric circulation, the non-annular component of the SAM, which are the principal factors governing the regional STR. A similar reversal is observed in the sign of the correlation between the SAM and oxygen-isotope values from an ice core located some 1,200?km east of Halley. This relationship is examined throughout the 20th Century, by comparing the isotope data to SAM reconstructions, and demonstrates marked decadal variability. Thus, these data suggest that switches in the STR are more likely to reflect natural variability in the long-wave patterns over the Southern Ocean rather than the influence of an anthropogenic forcing. This finding is important when considering the potential utility of Antarctic isotope data as a proxy for the SAM.     

On the use of the autocorrelation function: the constraint of using frequency band-limited signals for monitoring relative velocity changes

Correlations of seismic noise are commonly used to monitor temporal variations of relative seismic velocity in period ranges from 1 s up to 100 s. Of particular interest is the detection of small changes in the order of 0.01–0.1 % in propagation speeds. Measuring such small differences can, however, be significantly biased by temporal variations in the properties of the noise sources within the corresponding frequency band. Using synthetic data, we show that apparent relative velocity variations might appear only due to changes in the amplitude and frequency content caused by source variations. Removing such unwanted effects by applying narrow bandpass filters in the preprocessing restricts the high-resolution analysis of any signal due to Gabor’s uncertainty limit, i.e., the correlation function suffers a limited resolution to time delay estimates for small correlation times, low-frequency ranges, and in narrow frequency bands. Better understanding of spatiotemporal noise source properties and the theoretical limitations of time–frequency analysis is critical for accurate and reliable passive monitoring.     

The effect of Congo River freshwater discharge on Eastern Equatorial Atlantic climate variability

The surface ocean explains a considerable part of the inter-annual Tropical Atlantic variability. The present work makes use of observational datasets to investigate the effect of freshwater flow on sea surface salinity (SSS) and temperature (SST) in the Gulf of Guinea. In particular, the Congo River discharges a huge amount of freshwater into the ocean, affecting SSS in the Eastern Equatorial Atlantic (EEA) and stratifying the surface layers. The hypothesis is that an excess of river runoff emphasize stratification, influencing the ocean temperature. In fact, our findings show that SSTs in the Gulf of Guinea are warmer in summers following an anomalously high Congo spring discharge. Vice versa, when the river discharges low freshwater, a cold anomaly appears in the Gulf. The response of SST is not linear: temperature anomalies are considerable and long-lasting in the event of large freshwater flow, while in dry years they are less remarkable, although still significant. An excess of freshwater seems able to form a barrier layer, which inhibits vertical mixing and the entrainment of the cold thermocline water into the surface. Other processes may contribute to SST variability, among which the net input of atmospheric freshwater falling over EEA. Likewise the case of continental runoff from Congo River, warm anomalies occur after anomalously rainy seasons and low temperatures follow dry seasons, confirming the effect of freshwater on SST. However, the two sources of freshwater anomaly are not in phase, so that it is possible to split between atypical SST following continental freshwater anomalies and rainfall anomalies. Also, variations in air-sea fluxes can produce heating and cooling of the Gulf of Guinea. Nevertheless, atypical SSTs cannot be ascribed to fluxes, since the temperature variation induced by them is not sufficient to explain the SST anomalies appearing in the Gulf after anomalous peak discharges. The interaction processes between river runoff, sea surface salinity and temperature play an effective role in the interannual variability in the EEA region. Our results add a new source of variability in the area, which was often neglected by previous studies.     

All-sky Data Assimilation of MWTS-2 and MWHS-2 in the Met Office Global NWP System.

Microwave radiances from passive polar-orbiting radiometers have been, until recently, assimilated in the Met Office global numerical weather prediction system after the scenes significantly affected by atmospheric scattering are discarded.Recent system upgrades have seen the introduction of a scattering-permitting observation operator and the development of a variable observation error using both liquid and ice water paths as proxies of scattering-induced bias. Applied to the Fengyun 3 Microwave Temperature Sounder 2(MWTS-2) and the Microwave Humidity Sounder 2(MWHS-2), this methodology increases the data usage by up to 8% at 183 GHz. It also allows for the investigation into the assimilation of MWHS-2 118 GHz channels, sensitive to temperature and lower tropospheric humidity, but whose large sensitivity to ice cloud have prevented their use thus far. While the impact on the forecast is mostly neutral with small but significant shortrange improvements, 0.3% in terms of root mean square error, for southern winds and low-level temperature, balanced by 0.2% degradations of short-range northern and tropical low-level temperature, benefits are observed in the background fit of independent instruments used in the system. The lower tropospheric temperature sounding Infrared Atmospheric Sounding Interferometer(IASI) channels see a reduction of the standard deviation in the background departure of up to 1.2%. The Advanced Microwave Sounding Unit A(AMSU-A) stratospheric sounding channels improve by up to 0.5% and the Microwave Humidity Sounder(MHS) humidity sounding channels improve by up to 0.4%.     

Deformation patterns of upper Quaternary strata and their relation to active tectonics,Po Basin,Italy

Despite increased application of subsurface datasets below the limits of seismic resolution, reconstructing near‐surface deformation of shallow key stratigraphic markers beneath modern alluvial and coastal plains through sediment core analysis has received little attention. Highly resolved stratigraphy of Upper Pleistocene to Holocene (Marine Isotope Stage 5e to Marine Isotope Stage 1) alluvial, deltaic and coastal depositional systems across the southern Po Plain, down to 150 m depth, provides an unambiguous documentation on the deformation of previously flat‐lying strata that goes back in time beyond the limits of morphological, historical and palaeoseismic records. Five prominent key horizons, accurately selected on the basis of their sedimentological characteristics and typified for their fossil content, were used as highly effective stratigraphic markers (M1 to M5) that can be tracked for tens of kilometres across the basin. A facies‐controlled approach tied to a robust chronology (102 radiocarbon dates) reveals considerable deformation of laterally extensive nearshore (M1), continental (M2 and M3) and lagoon (M4 and M5) marker beds originally deposited in a horizontal position (M1, M4 and M5). The areas where antiformal geometries are best observed are remarkably coincident with the axes of buried ramp anticlines, across which new seismic images reveal substantially warped stratal geometries of Lower Pleistocene strata. The striking spatial coincidence of fold crests with the epicentres of historic and instrumental seismicity suggests that deformation of marker beds M1 to M5 might reflect, in part at least, syntectonically generated relief and, thus, active tectonism. Precise identification and lateral tracing of chronologically constrained stratigraphic markers in the ¹⁴C time window through combined sedimentological and palaeoecological data may delineate late Quaternary subsurface stratigraphic architecture at an unprecedented level of detail, outlining cryptic stratal geometries at the sub‐seismic scale. This approach is highly reproducible in tectonically active Quaternary depositional systems and can help to assess patterns of active deformation in the subsurface of modern alluvial and coastal plains worldwide.     

The June 4th 1999 severe weather episode in San Quirino, Italy: a tornado event?

On the morning of June 4th 1999, a severe weather event took place in San Quirino, a small village of Friuli-Venezia Giulia in the northeast of Italy. This village is located near the piedmont of the Alps, 40 km west from Udine and 60 km north from Venice.Around 0900 UTC (1100 local time), a thunderstorm with an intense hail fall affected the area of San Quirino. A few minutes later (around 0920 UTC, source: a farmer), a funnel cloud from a cumulonimbus touched the ground, producing damages to houses, trees and sheds. The damaged area was quite narrow (about 300 m) and short (less than 10 km). No injuries to people were reported.In spite of the smallness of the area interested by the phenomenon, this storm is studied here starting from the synoptic scale, moving to the mesoscale and finishing with the storm scale, trying to underline its characteristics. These analyses, especially those coming from the Doppler radar images, bring us to the conclusion that the San Quirino episode was produced by a supercell storm.     

Development and validation of a metallic haunch seismic retrofit solution for existing under‐designed RC frame buildings

The feasibility and efficiency of a seismic retrofit solution for existing reinforced concrete frame systems, designed before the introduction of modern seismic‐oriented design codes in the mid 1970s, is conceptually presented and experimentally investigated. A diagonal metallic haunch system is introduced at the beam–column connections to protect the joint panel zone from extensive damage and brittle shear mechanisms, while inverting the hierarchy of strength within the beam–column subassemblies and forming a plastic hinge in the beam. A complete step‐by‐step design procedure is suggested for the proposed retrofit strategy to achieve the desired reversal of strength hierarchy. Analytical formulations of the internal force flow at the beam–column‐joint level are derived for the retrofitted joints. The study is particularly focused on exterior beam–column joints, since it is recognized that they are the most vulnerable, due to their lack of a reliable joint shear transfer mechanism. Results from an experimental program carried out to validate the concept and the design procedure are also presented. The program consisted of quasi‐static cyclic tests on four exterior, ? scaled, beam–column joint subassemblies, typical of pre‐1970 construction practice using plain round bars with end‐hooks, with limited joint transverse reinforcement and detailed without capacity design considerations. The first (control specimen) emulated the as‐built connection while the three others incorporated the proposed retrofitted configurations. The experimental results demonstrated the effectiveness of the proposed solution for upgrading non‐seismically designed RC frames and also confirmed the applicability of the proposed design procedure and of the analytical derivations. Copyright © 2006 John Wiley & Sons, Ltd.     

On estimating frequency-magnitude relations from heterogeneous catalogs

The paper studies the effect of magnitude errors on heterogeneous catalogs, by applying the apparent magnitude theory (seeTinti andMulargia, 1985a), which proves to be the most natural and rigorous approach to the problem. Heterogeneities in seismic catalogs are due to a number of various sources and affect both instrumental as well as noninstrumental earthquake compilations.The most frequent basis of heterogeneity is certainly that the recent instrumental records are to be combined with the historic and prehistoric event listings to secure a time coverage, considerably longer than the recurrence time of the major earthquakes. Therefore the case which attracts the greatest attention in the present analysis is that of a catalog consisting of a subset of higher quality data, generallyS ₁, spanning the interval T ₁ (the instrumental catalog), and of a second subset of more uncertain magnitude determination, generallyS ₂, covering a vastly longer interval T ₂ (the historic and/or the geologic catalog). The magnitude threshold of the subcatalogS ₁ is supposedly smaller than that ofS ₂, which, as we will see, is one of the major causes of discrepancy between the apparent magnitude and the true magnitude distributions. We will further suppose that true magnitude occurrences conform to theGutenberg-Richter (GR) law, because the assumption simplified the analysis without reducing the relevancy of our findings.The main results are: 1) the apparent occurrence rate exceeds the true occurrence rate from a certain magnitude onward, saym _GR; 2) the apparent occurrence rate shows two distinct GR regimes separated by an intermediate transition region. The offset between the two regimes is the essential outcome ofS ₁ being heterogeneous with respect toS ₂. The most important consequences of this study are that: 1) it provides a basis to infer the parameters of the true magnitude distribution, by correcting the bias deriving from heterogeneous magnitude errors; 2) it demonstrates that the double GR decay, that several authors have taken as the incontestable proof of the failure of the GR law and of the experimental evidence of the characteristic earthquake theory, is instead perfectly consistent with a GR-type seismicity.     

Potential merits for substorm research from imaging of charge-exchange neutral atoms

The in situ observations of the Earth magnetosphere performed over the past decades of space research have provided a rather good understanding of many partial localized processes of the magnetospheric substorm. The continuing lack of global observations inhibits the construction of a coherent picture of the substorm as a whole, which is actually determined by the coupling of the partial processes. In this context the importance of global observations for the advancement of magnetospheric substorm studies is critical. This paper presents briefly a promising technique of global observations, namely the imaging of charge exchange neutral atoms, or neutral atom imaging (NAI) of the magnetosphere. Model and theoretical estimates of charge-exchange neutral atom fluxes, as well as appropriate spacecraft orbit and instrumentation requirements are presented and discussed for specific regions of interest and vantage points. The potential merits of NAI for substorm research are presented along with possible combinations with other types of observational methods. Substorm issues that would benefit from NAI should include among others the assessment of the ionospheric contribution to the hot magnetospheric plasma, the relative importance of various ionospheric ion source regions, the resolution of spatial and temporal characteristics of substorm ion injections. NAI observations can be precious complements to local observations and lead to the understanding of how local processes, many of which are resolved quite well today, combine to form the global process of the magnetospheric substorm.