The information system of the French Peatland Observation Service: Service National d'Observation Tourbières – A valuable tool to assess the impact of global changes on the hydrology and biogeochemistry of temperate peatlands through long term monitoring

Mitigating and adapting to global changes requires a better understanding of the response of the Biosphere to these environmental variations. Human disturbances and their effects act in the long term (decades to centuries) and consequently, a similar time frame is needed to fully understand the hydrological and biogeochemical functioning of a natural system. To this end, the ‘Centre National de la Recherche Scientifique’ (CNRS) promotes and certifies long-term monitoring tools called national observation services or ‘Service National d'Observation’ (SNO) in a large range of hydrological and biogeochemical systems (e.g., cryosphere, catchments, aquifers). The SNO investigating peatlands, the SNO ‘Tourbières’, was certified in 2011 ( https://www.sno-tourbieres.cnrs.fr/ ). Peatlands are mostly found in the high latitudes of the northern hemisphere and French peatlands are located in the southern part of this area. Thus, they are located in environmental conditions that will occur in northern peatlands in coming decades or centuries and can be considered as sentinels. The SNO Tourbières is composed of four peatlands: La Guette (lowland central France), Landemarais (lowland oceanic western France), Frasne (upland continental eastern France) and Bernadouze (upland southern France). Thirty target variables are monitored to study the hydrological and biogeochemical functioning of the sites. They are grouped into four datasets: hydrology, fluvial export of organic matter, greenhouse gas fluxes and meteorology/soil physics. The data from all sites follow a common processing chain from the sensors to the public repository. The raw data are stored on an FTP server. After operator or automatic processing, data are stored in a database, from which a web application extracts the data to make them available ( https://data-snot.cnrs.fr/data-access/ ). Each year at least, an archive of each dataset is stored in Zenodo, with a digital object identifier (DOI) attribution ( https://zenodo.org/communities/sno_tourbieres_data/ ).     

Depositional environment of a Kimmeridgian carbonate 'black band' (Akkuyu Formation, south-western Turkey)

The Upper Jurassic Akkuyu Formation of south-western Turkey consists of pale-coloured carbonate facies, but includes a peculiar ‘black band’ at its base. In order to characterize the depositional environment of this level, a sedimentological, organic and inorganic geochemical study was performed on 30 samples. Three units are distinguished. Unit 1 consists of black marlstones, very rich in organic carbon (22–30%) with HI (hydrogen index) values around 600. The organic matter is an amorphous homogeneous material even at nanoscopic scale. This unit is also characterized by a very high concentration of V ( >1000 p.p.m.) and a δ¹³C_org value around ?26·5‰. Unit 2 shows thin-bedded black limestones with chert layers. Its organic content varies from 2% to 6%. As in unit 1, the HI values are uniformly high (600), and gas chromatography shows a high quantity of hopanes. The V concentration is also high (≈400 p.p.m.). The unit has a high Sr/Ca ratio, an organic carbon isotopic ratio close to ?28·7‰ and diffuse, nanoscopically amorphous organic material that is closely associated with pyrite. Unit 3 corresponds to the white limestones overlying the ‘black band’. This calcitic facies is almost devoid of organic carbon (<0·1%). The δ¹³C_org values are similar to those of unit 1 (?25·5‰ to ?26‰). Deposition occurred in a basinal environment surrounded by a carbonate platform. Primary productivity was high but not exceptional; terrestrial organic inputs were scarce. Bottom waters were probably euxinic during the deposition of unit 1. The presence of both hopane-rich and sulphur-rich nanoscopically amorphous organic matter may be the result of strong sulphate-reducing bacterial activity. Coupled with low amounts of iron, this led to intense vulcanization of the organic matter and thus good preservation. With the onset of unit 2 deposition, environmental conditions became less extreme, perhaps because of cooler water temperatures. Finally, the depositional conditions became oxic, leading to the accumulation of pale-coloured organic-poor limestones of unit 3.     

Water temperature modelling: comparison between the generalized additive model,logistic, residuals regression and linear regression models

Water temperature has a significant influence on aquatic organisms, including stenotherm fish such as salmonids. It is thus of prime importance to build reliable tools to forecast water temperature. This study evaluated a statistical scheme to model average water temperature based on daily average air temperature and average discharge at the Sainte-Marguerite River, Northern Canada. The aim was to test a non-parametric water temperature generalized additive model (GAM) and to compare its performance to three previously developed approaches: the logistic, residuals regression and linear regression models. Due to its flexibility, the GAM was able to capture some of the nonlinear response between water temperature and the two explanatory variables (air temperature and flow). The shape of these effects was determined by the trends shown in the collected data. The four models were evaluated annually using a cross-validation technique. Three comparison criteria were calculated: the root mean square error (RMSE), the bias error and the Nash-Sutcliffe coefficient of efficiency (NSC). The goodness of fit of the four models was also compared graphically. The GAM was the best among the four models (RMSE = 1.44°C, bias = ?0.04 and NSC = 0.94).     

Magnetic anisotropy of hematite natural crystals: high field experiments

Hematite is one of the most important carriers of remanent magnetization in natural samples. Its strong magnetocrystalline anisotropy makes it difficult to determine one single value for the magnetic anisotropy constant and other magnetic properties. In particular, the anisotropy of hematite within its basal plane is controversial because an assumed triaxial anisotropy compatible with the crystallographic structure has not always been detected. This study presents a comparative analysis of rock magnetic properties, compositional analysis and determination of the magnetic anisotropy constant. Different models with anisotropy constant within the basal plane ranging from 0 to 13 (J m⁻³) are considered in the evaluation of the factors that control the presence or absence of a triaxial anisotropy. A linear relationship between saturation magnetization (M _s ) and coercitivity (B _c ) in measurements at increasing temperatures is observed in samples where anisotropy is either uniaxial or biaxial while those with significant triaxial anisotropies have a power–law relationship between M _s and B _c .     

Sorption of lead by chemically modified rice bran

In this work, the effectiveness of native and chemically modified rice bran to remove heavy metal Pb(II) ions from aqueous solution was examined. Chemical modifications with some simple and low-cost chemicals resulted in enhancement of the adsorption capacities and had faster kinetics than native rice bran. Experiments were conducted in shake flasks to monitor the upshot of parameters over a range of pH, initial Pb(II) concentrations and contact times using a batch model study. The sorption capacities q (mg g^?1) increased in the following order: NaOH (147.78), Ca(OH)₂ (139.08), Al(OH)₃ (127.24), esterification (124.28), NaHCO₃ (118.08), methylation (118.88), Na₂CO₃ (117.12) and native (80.24). The utmost uptake capacity q (mg g^?1) was shown by NaOH-pretreated rice bran. The results showed that, using NaOH-modified rice bran, the chief removal of Pb(II) was 74.54 % at pH 5, primary Pb(II) concentration 100 mg L^?1 and contact time 240 min. Equilibrium isotherms for the Pb(II) adsorption were analyzed by Langmuir and Freundlich isotherm models. The Langmuir isotherm model, showing Pb(II) sorption as accessible through the high value of the correlation coefficient (R ² = 0.993), showed a q _max value of 416.61 mg g^?1. The kinetic model illustrated adsorption rates well, depicted by a second order, which gives an indication concerning the rate-limiting step. Thermodynamic evaluation of the metal ion ?G ^o was carried out and led to the observation that the adsorption reaction is spontaneous and endothermic in nature. NaOH chemically modified rice bran was a superb biosorbent for exclusion of Pb(II) and proved to be excellent for industrial applications.     

Fe,Mn, P and S Speciation in Sediments from the Capivara Hydroelectric Dam Lake (Brazil) as an Indicator of Anthropogenic Influences

The conservation of large water resources is essential for the preservation of human life. The quantification and, more importantly, the speciation of chemical substances that indicate the presence of anthropogenic contamination in water resources are of great importance. This paper presents the results of analysis for the determination of organic, inorganic and total phosphorus, pseudo‐sulfur, and iron and manganese, in five fractions, in water sediments collected from the Capivara Hydroelectric Power Plant, Brazil. A study on the seasonal variation of these parameters was conducted, with data having been collected in the winter and in the summer, at two sites along the dam, 5 km apart, close to the city of Primeiro de Maio. Phosphorous was found in sediments and adjacent soil in the organic form (OP), and was used as an indicator of anthropogenic influence on the reservoir banks. Speciation of potentially toxic Mn showed that it is present in the exchangeable fraction of the 0–5 cm depth layer (sediment/water interface), making its transfer to the water column possible. Results from this study showed that domestic and industrial effluent treatment measures are needed for the preservation of the quality of aquatic environments.     

On radiative forcing of sulphate aerosol produced from ion-promoted nucleation mechanisms in an atmospheric global model

A significant fraction of the total number of particles present in the atmosphere is formed by nucleation in the gas phase. Nucleation and the subsequent growth process influence both number concentration of particles and their size distribution besides chemical and optical properties of atmospheric aerosols. Sulphate aerosol nucleation mechanisms promoted by ions have been evaluated here in a tropospheric interactive chemistry-aerosol module for mass and number concentration in a global atmospheric model. The indirect radiative forcing of sulphate particles is assessed in this model; indirect radiative forcing is different for ion-induced (IIN) and ion-mediated (IMN) mechanisms. The indirect radiative forcing in 10-year simulation runs has been calculated as ?1.42?W/m² (IIN) and ?1.54?W/m² (IMN). The 5% emission of primary sulphate particles in simulations changes the indirect radiative forcing from ?1.42 to ?1.44?W/m² for IIN case, and from ?1.54 to ?1.55 W/m² for the IMN case. More precisely, owing to greater nucleation rates, IMN mechanisms produces greater cooling than the IIN mechanisms in the backdrop that both mechanisms produce almost identical distribution of CDNC in their pre-industrial runs. The inclusion of primary particles in simulations with IIN and IMN mechanisms increases both CDNC and the indirect radiative forcing.     

Recognition of the hydrogeological potential using electrical sounding in the Khemisset-Tiflet region,Morocco

The low recharge of reservoirs and the increasing demand for water limit the potential of mobilized resources, especially in arid to semi-arid areas like Morocco. Integrated management is essential to safeguard this resource. In respect with this perspective, this work provides the analysis of hydrogeological potential of Khemisset-Tiflet region, which falls within the action area of the Sebou Hydraulic Basin Agency. The basis of our studies was as follows:(1) The interpretation of the existing geoelectric data;(2) application of geophysical methods for non-destructive reconnaissance and their integration into a Geographic Information System(GIS). The analysis demonstrates that: The map of the isohypses and the geoelectric cross-section of the substratum of the superficial roof aquifer show clearly a plunge associated with development of the Paleozoic roof in the South and the direction of flow of the surface water is from south to north, from the upper zone to the north of the El Kansera dam. These conclusions constitute very useful contribution for any resource management projects in this area.     

Morphodynamic interactions of continental shelf,beach and dunes: the Cabopino dune system in southern Mediterranean Spain

The complex morphodynamic interactions between nearshore, shoreface and dune systems are usually simplified by studying these zones and their associated processes in isolation. However, the established relationships between each of them suggests that an integrated approach is required to examine the genesis, evolution and adaptation of the entire morphodynamic system. The Cabopino dune system in the southern Spanish Mediterranean Sea provides a clear example of a linked morphodynamic system in which a relatively large dune system has been generated and grown through the supply of sediments from an adjacent littoral supply environment. Here, we present a conceptual model of how the nearshore has provided suitable conditions for beach and dune development. We purport that synchronization of sediment activation in the marine and aeolian sections of the system have played a major role in this microtidal setting in which temporal aspects are not only tied to storm action, but to large sedimentary features moving alongshore. © 2019 John Wiley & Sons, Ltd.