Mineral chemistry and petrogenesis of chromitites from the Khoy ophiolite complex,Northwestern Iran: Implications for aggregation of two ophiolites

The Khoy ophiolitic complex in Northwestern Iran is a part of the Tethyan ophiolite belt, and is divided into two sections: the Eastern ophiolite in Qeshlaq and Kalavanes (Jurassic–Cretaceous) and the Western ophiolite in Barajouk, Chuchak and Hessar (Late Cretaceous). Our chromitites can be clearly classified into two groups: high‐Al chromitites (Cr# = 0.38–0.44) from the Eastern ophiolite, and high‐Cr chromitites (Cr# = 0.54–0.72) from the Western ophiolite. The chromian spinels in high‐Al chromitite include primary mineral inclusions mainly as Na‐bearing diopside and pargasite with subordinate rutile and their formation was probably related to reaction between a MORB (mid‐ocean‐ridge basalt)‐like melt with depleted harzburgite, possibly in a back‐arc setting. Their host harzburgites contain clinopyroxene with higher contents of Al₂O₃, Na₂O, Cr₂O₃, and TiO₂ relative to Western harzburgites and are possibly residue after moderate partial melting (~15 %) whereas the Western harzburgite is residue after high partial melting (~25 %). The chromian spinel in the Western Khoy chromitites contains inclusions such as clinopyroxene, olivine and platinum group mineral‐bearing sulfides. These Western chromitites were possibly formed at two stages during arc growth and are divided into the moderately high‐Cr# chromitites (Barajouk and Hessar) and the high‐Cr# chromitites (Chuchak A and C). The former crystallized from island‐arc‐tholeiite (IAT) melts during reaction with the host depleted harzburgites, whereas the latter crystallized from boninitic melts (second stage melt) during reaction with highly depleted harzburgite in a supra‐subduction‐zone environment. Based on the mineral chemistry of chromian spinels, pyroxenes, and mineral inclusions, the chromitites and the host peridotites from the Eastern and Western Khoy ophiolites were formed in a back‐arc basin and arc‐related setting, respectively. The Khoy ophiolitic complex is a tectonic aggregate of the two different ophiolites formed in two different tectonic settings at different ages.     

The biostratigraphy of the uppermost calcareous nannofossils of Cretaceous deposit in both Shahdar and Namazgah sections (NE Iran)

A moderately various calcareous nannofossil assemblage of 44 species assigned to 24 genera is identified in samples collected from the Shahdar section and 18 genera and 43 species in Namazgah section. Testing of calcareous nannofossil has permitted recognition of few important coccolith events in stratigraphic interval occupied by the uppermost layers of Cretaceous in the Shahdar and Namazgah sections. These events are correlated to the CC24–CC26 of Sissingh (Geol Minjbouw 56: 37–65, 1977) in two sections. According to these biozones, the age of the studied sections in Shahdar and Namazgah is Early Maastrichtian–Late Maastrichtian. On the basis of paleoecological interpretation, the last layers related to the Cretaceous deposits in two sections were deposited in shallow marine environment in relatively low latitude, and the depth of the basin from the Cretaceous deposits toward Fajan Formation is minimized.     

The Gol-e-Zard Zn-Pb Deposit,Lorestan Province,Iran: a Metamorphosed SEDEX Deposit简

The Gol-e-Zard Zn-Pb deposit is one of several sediment-hosted Zn-Pb deposits found in the central part of the Sanadaj-Sirjan Zone, known as the Isfahan-Malayer belt, western Iran. Mineralization occurs in Upper Triassic to Jurassic phyllites and meta-sandstones. Sphalerite and galena are the most abundant metallic ores, with minor chalcopyrite. Calcite and quartz are the main gangue minerals. Fissure filling, replacement textures and especially mineralized faults, suggest an epigenetic stage in the Gol-e-Zard deposit formation. Geochemical studies of mineralized rocks show high concentrations of Zn, Pb and Cu,（Zn and Pb 〉 10000 ppm and Cu average 3000 ppm）. LREE enrichment（LREE〉HREE, La/Lu average 1.44） and positive Eu anomalies（Eu/Eu＊〉1 average 1.67） indicate reducing conditions during the deposition of deposit. However, some samples do not display negative Ce anomalies, which indicate that localized oxidizing conditions are also present. This study indicates that the Gol-e-Zard deposit formed due to circulating hydrothermal fluids in a marine environment. A SEDEX-type genesis, which is defined by circulating hydrothermal fluids through sediments in a marine environment, and syngenetic precipitation of Zn and Pb sulphides, is suggested for the Gol-e-Zard deposit. Emplacement of some granitoid intrusions such as the Aligudarz granitoid intrusion remobilized mineralizing fluids and metamorphosed the Gol-e-Zard deposit.     

Lower Miocene oyster shells from the Southeast Zagros Basin (Zade Mahmud area, Iran) and their paleoecology

The Guri limestone Member of the Mishan Formation in the Zagros Basin consists of thick bedded limestone bearing benthic foraminifera and oyster shells. Seven species of Ostreidae and Gryphaeidae were identified as belonging to four genera (Crassostrea, Cubitostrea, Ostrea, and Hyotissa), i.e., Cubitostrea frondosa, Ostrea (Cubitostrea) dubertreti, Cubitostrea digitalina, Crassostrea gryphoides, Hyotissa virleti, Ostrea vesitata, and Ostrea plicatula. These fossils are reported for the first time from Iran. Miocene deposits in the studied area contain a rich benthic foraminiferal fauna dominated by Pseudotaberina, Meandropsina, Miogypsina, Flosculinella, Borelis, and other larger benthic foraminifera. We assign these sediments to a Burdigalian age based on Borelis melo curdica–Borelis melo melo Assemblage Zone. Paleoecological considerations also revealed that the beds were deposited in a near-shore non-agitated and shallow-water environment with moderate to low sedimentation rate. The studied oysters are located in one of more important paleogeographic settings in the world and very similar to many other Tethyan regions. The presence of these oysters suggests that the Zade Mahmud area located at margins of a sea way that connected the north and south of Zagros Basin during Burdigalian.     

Impact of season and road on stream crossings and river water quality in Darabkola,hyrcanian forest

Nutrients are important building blocks for healthy aquatic ecosystems and are generally nontoxic; but they can change with alteration in environmental parameters. The main objective of this study was to consider the seasonal variability of NO ₃ ^– , PO ₄ ^3– and total suspended solids (TSS) concentrations in water. The study sites, stream crossings (L30, L15) and river (R), are located in the hyrcanian forests, district 1 of Darabkola forest. The sampling was conducted in winter and spring. Water samples were taken into plastic bottles, labeled, and carried out to the laboratory for NO ₃ ^– , PO ₄ ^3– and TSS analysis. T-test results showed that there was a seasonal change in nutrient concentrations (p < 0.05) except for NO ₃ ^– concentration at L30. Also, there was no significant seasonal change in TSS concentrations at all stations. Pearson correlation analysis did not reveal the same trend. Further analysis showed that the effect of road age on water quality parameters was statistically significant for PO ₄ ^3– in spring and winter. Atmospheric precipitation plays vital role in nutrient loss and increasing concentration of suspended sediment. To prevent soil erosion from activities and discharge of wastes in the vicinity of river and stream an effective management should be planned and enforced.     

Anthropogenic Decline of Ancient,Sustainable Water Systems: Qanats

Qanat is an ancient underground structure to abstract groundwater without the need for external energy. A recognized world heritage, Qanat has enabled civilization in arid and semi-arid regions that lack perennial surface water resources. These important structures, however, have faced significant challenges in recent decades due to increasing anthropogenic pressures. This study uses remote sensing to investigate land-use changes and the loss of 15,983 Qanat shafts in the Mashhad plain, northeast of Iran, during the past six decades. This entails obtaining a rare aerial imagery from 1961, as well as recent satellite imagery, over a region with the highest density of Qanats in Iran, the birthplace of Qanat. Results showed that only 5.59% of the Qanat shafts in 1961 remained intact in 2021. The most prominent Qanat-impacting land-use changes were agriculture and urban areas, that accounted for 42.93 and 31.81% Qanat shaft destruction in the study area, respectively. This study also showed that groundwater table decline, demographic changes, and reduction in the appeal of working in the Qanat maintenance and construction industry among the new generation are existential threats to Qanats, and may result in the demise of these ancient structures in the future. Findings of this study can be used for urban planning in arid and semi-arid areas with the aim of protecting these historic water structures.     

Arsenic in the Muteh gold mining district, Isfahan, Iran

Following the appearance of symptoms of arsenic toxicity in the inhabitants of villages in the Muteh gold mining region, central Iran, the concentration of this element in various parts of biogeochemical cycle is investigated. For this purpose, rock, groundwater, soil, plant, livestock hair and wool, and human hair samples are collected and analysed. Total arsenic content ranges from 23 to 2,500?mg/kg in rock samples, 7?C1,061???g/l in water, 12?C232?mg/kg in soil, 0.5?C16?mg/kg in plant samples, 4.10?C5.69?mg/kg in livestock hair and wool, and 0.64?C5.82?mg/kg in human hair. Arsenic concentration in various parts of biogeochemical cycle near the gold deposit in a metamorphic complex, and also close to the gold-processing plant, is very high and decreases exponentially with increasing distance from them. Arsenic concentration in water from a well close to the Muteh gold mine is above 1?mg/L. Arsenic in hair samples taken from local inhabitants is above the recommended levels, and the control samples in Shahre-Kord city. Arsenic concentration is higher in male population and correlates positively with age. It is suggested that arsenic resulting from the decomposition of ore mineral such as orpiment (As₂S₃), realgar (As₂S₂) and arsenopyrite (FeAsS) is responsible for polluting natural resources and the human intake via drinking water and the food chain. Gold mining and processing has undoubtedly enhanced the release of arsenic and intensified the observed adverse effects in Muteh area.     

Realization of rainfed wheat and barley production environment based on drought patterns in the northeast Iran

Theoretical and Applied Climatology - High spatiotemporal climate variability in the northeast Iran has led to increased production risk for rainfed crops. Hence, to explore potential opportunities...     

Applicability of generalized additive model in groundwater potential modelling and comparison its performance by bivariate statistical methods

Groundwater is the most valuable natural resource in arid areas. Therefore, any attempt to investigate potential zones of groundwater for further management of water supply is necessary. Hence, many researchers have worked on this subject all around the world. On the other hand, the Generalized Additive Model (GAM) has been applied to environmental and ecological modelling, but its applicability to other kinds of predictive modelling such as groundwater potential mapping has not yet been investigated. Therefore, the main purpose of this study is to evaluate the performance of GAM model and then its comparison with three popular GIS-based bivariate statistical methods, namely Frequency Ratio (FR), Statistical Index (SI) and Weight-of-Evidence (WOE) for producing groundwater spring potential map (GSPM) in Lorestan Province Iran. To achieve this, out of 6439 existed springs, 4291 spring locations were selected for training phase and the remaining 2147 springs for model evaluation. Next, the thematic layers of 12 effective spring parameters including altitude, plan curvature, slope angle, slope aspect, drainage density, distance from rivers, topographic wetness index, fault density, distance from fault, lithology, soil and land use/land cover were mapped and integrated using the ArcGIS 10.2 software to generate a groundwater prospect map using mentioned approaches. The produced GSPMs were then classified into four distinct groundwater potential zones, namely low, moderate, high and very high classes. The results of the analysis were finally validated using the receiver operating characteristic (ROC) curve technique. The results indicated that out of four models, SI is superior (prediction accuracy of 85.4%) following by FR, GAM and WOE, respectively (prediction accuracy of 83.7, 77 and 76.3%). The result of groundwater spring potential map is helpful as a guide for engineers in water resources management and land use planning in order to select suitable areas to implement development schemes and also government entities.