Non-adiabatic interactions in excitedC 2 H molecules and their relationship toC 2 formation in comets

A unified picture of the photodissociation of theC ₂ H radical has been developed using the results from the latest experimental and theoretical work. This picture shows that a variety of electronic states ofC ₂ are formed during the photodissociation of theC ₂ H radical even if photoexcitation accesses only one excited state. This is because the excited states have many avoided corssings and near intersections where two electronic states come very close to one another. At these avoided crossings and near intersections, the excited radical can hop from one electronic state to another and access new final electronic states of theC ₂ radical. The complexity of the excited state surfaces also explains the bimodal rotational distributions that are observed in all of the electronic states studied. The excited states that dissociate through a direct path are limited by dynamics to produceC ₂ fragments with a modest amount of rotational energy, whereas those that dissociate by a more complex path have a greater chance to access all of phase space and produce fragments with higher rotational excitation. Finally, the theoretical transition moments and potential energy curves have been used to provide a better estimate of the photochemical lifetimes in comets of the different excited states of theC ₂ H radical. The photochemically active states are the 2²₊, 2²II, 3²II, and 3²₊, with photodissociation rate constants of 1.0×10^–6, 4.0×10^–6, 0.7×10^–6, and 1.3×10^–6s^–1, respectively. These rate constants lead to a total photochemical lifetime of 1.4×10⁵ s.     

Prediction of rainfall using artificial neural networks for synoptic station of Mashhad: a case study

In this paper, we have utilized ANN (artificial neural network) modeling for the prediction of monthly rainfall in Mashhad synoptic station which is located in Iran. To achieve this black-box model, we have used monthly rainfall data from 1953 to 2003 for this synoptic station. First, the Hurst rescaled range statistical (R/S) analysis is used to evaluate the predictability of the collected data. Then, to extract the rainfall dynamic of this station using ANN modeling, a three-layer feed-forward perceptron network with back propagation algorithm is utilized. Using this ANN structure as a black-box model, we have realized the complex dynamics of rainfall through the past information of the system. The approach employs the gradient decent algorithm to train the network. Trying different parameters, two structures, M₅₃₁ and M₇₄₁, have been selected which give the best estimation performance. The performance statistical analysis of the obtained models shows with the best tuning of the developed monthly prediction model the correlation coefficient (R), root mean square error (RMSE), and mean absolute error (MAE) are 0.93, 0.99, and 6.02 mm, respectively, which confirms the effectiveness of the developed models.     

Effects of irradiated Ergosan on the growth performance and mucus biological components of rainbow trout <Emphasis Type="Italic">Oncorhynchus mykiss</Emphasis>

Effects of irradiated and non-irradiated Ergosan extract (alginic acid) on rainbow trout growth performance and skin mucosal immunity were compared. Ergosan was irradiated at 30 kGy in a cobalt-60 irradiator. A total of 252 fish (128.03±9.4 g) were randomly divided into four equal groups, given the basal diet either unsupplemented with Ergosan (control group) or supplemented with crude Ergosan (5 g/kg), ethanol-extracted Ergosan (0.33 g/kg) or irradiated Ergosan (0.33 g/kg) according to this protocol: basal diet for 15 days, treatment diet for 15 days, basal diet for 10 days and treatment diet for 15 days. Highest growth performance was observed in fish fed irradiated Ergosan (P <0.05). Dietary administration of different Ergosan types did not cause any changes in mucus protein level, but improved alkaline phosphatase level and hemagglutination titer compared with the control (basal diet without Ergosan) on day 55 of feeding trial (P <0.05). Furthermore, the highest value of lysozyme activity was observed in gamma-irradiated Ergosan on day 55. In conclusion, gamma-irradiated Ergosan at 0.33 g/kg was found to improve growth performance and mucus biological components significantly in comparison with the control group (basal diet without Ergosan).     

Investigation on the Distribution of Gold Across the Ahar Area (NW Iran) Using Stream‐Sediment and BLEG Methods

The Ahar area is located in NW Iran. The main part of the area is covered by Eocene andesitic and andesi‐basaltic rocks within which several granitoid intrusives of Oligocene age are emplaced. This caused vast hydrothermal alterations and Cu and Au mineralization. In this regard, this contribution aims to explore the distribution of gold across the region based on systematic sampling of stream sediments and using the secondary geochemical halos, as well as the bulk leach extractable gold (BLEG) method. Meanwhile, the results obtained from these two methods will be compared in order to find out if the anomalous zones match with each other. For this, 620 stream sediment samples of ?80 mesh grain size and 422 BLEG samples were collected and analyzed by Fire Assay and atomic absorption spectroscopy (AAS) methods, respectively. For BLEG samples, gold was first dissolved using KCN before being analyzed by the AAS method. Furthermore, 84 rock samples were also collected during the field control surveys and were analyzed by Fire Assay and ICP‐OES methods for gold and other elements, respectively. After determining the distribution characteristics and statistical parameters of gold in each group of samples, anomaly maps of gold for each method were prepared, revealing almost similar anomalous zones across the region. Based on these maps, most of the discovered anomalies correlate well with granitoid intrusives of Oligocene age and the related hydrothermal alterations, which have occurred within the intrusives and the host andesitic‐basaltic rocks of Eocene age, especially at the NE and central parts of the area and east of Ahar. Some silicic veins and veinlets have been observed during field surveys in these parts, within which high concentrations of Au and sometimes Cu are determined. Another anomalous zone is located over the hydrothermal alterations within trachy‐andesitic and andesitic volcanics of Pliocene age at the SE part of the quadrangle, where vast alterations caused by volcanic fumaroles and epithermal mineralization of gold and Pb–Zn is discovered. In this regard, the SE and NE parts of the area and the east Ahar area are proposed, in order of importance, for further detailed investigations.     

Burdigalian–Serravalian calcareous nannoplanktons from Qom Formation, North-Center Iran

The aim of this study is to determine calcareous nannofossil species found in Kamar-Kuh area and demonstrate this use for biostratigraphic studies. The Qom Formation is widely distributed in Kamar-Kuh section and has nine members(a–f). In this study, 12 samples were taken and prepared with smear slide. Some of the determined species are listed below, and some of them are photographed by light and scanning microscope. According to obtained nannofossils, 16 species, nine genera, and six families were determined. Obtained nannofossils indicated age of Burdigalian–Serravalian (middle Miocene) for this section.     

The source of fluoride toxicity in Muteh area,Isfahan, Iran

Endemic dental fluorosis has been observed in most inhabitants of three villages of Muteh area, located in northwest of Isfahan province, with mottled enamel related to high levels of fluoride in drinking water (1.8–2.2 ppm). Forty-seven groundwater samples from six villages were collected and fluoride concentrations along with physico-chemical parameters were analyzed. Fluoride concentration in this area varies from 0.2 to 9.2 mg/l with highest fluoride level at Muteh gold mine (Chahkhatun mine). Fluoride concentration positively correlates with pH and HCO₃ ⁻ indicating that alkaline pH provides a suitable condition for leaching of fluoride from surrounding rocks. The district is mainly covered by three lithological units, namely, metamorphic and granite rocks, alluvial sediments, and carbonate rocks. Factor analysis shows that parameters can be classified into four components: electrical conductivity (EC), total dissolved solids (TDS), Cl⁻, Na⁺ and K⁺, pH and F⁻, SO₄ ²⁻and Mg²⁺, HCO₃ ⁻ and Ca₂ ⁺. The groundwaters from the three geological units were compared using Mann–Whitney U test. The order of median fluoride concentration is: metamorphic and granite rocks > alluvial sediments > carbonate rocks. Hence, the fluoride content is most probably related to fluoride-bearing minerals such as amphibole and mica group minerals in metamorphic and granitic rocks. The concentration of fluoride in drinking water wells located near the metamorphic complex in Muteh area is above 2 ppm.     

Mineral chemistry and petrogenesis of chromitites from the Khoy ophiolite complex,Northwestern Iran: Implications for aggregation of two ophiolites

The Khoy ophiolitic complex in Northwestern Iran is a part of the Tethyan ophiolite belt, and is divided into two sections: the Eastern ophiolite in Qeshlaq and Kalavanes (Jurassic–Cretaceous) and the Western ophiolite in Barajouk, Chuchak and Hessar (Late Cretaceous). Our chromitites can be clearly classified into two groups: high‐Al chromitites (Cr# = 0.38–0.44) from the Eastern ophiolite, and high‐Cr chromitites (Cr# = 0.54–0.72) from the Western ophiolite. The chromian spinels in high‐Al chromitite include primary mineral inclusions mainly as Na‐bearing diopside and pargasite with subordinate rutile and their formation was probably related to reaction between a MORB (mid‐ocean‐ridge basalt)‐like melt with depleted harzburgite, possibly in a back‐arc setting. Their host harzburgites contain clinopyroxene with higher contents of Al₂O₃, Na₂O, Cr₂O₃, and TiO₂ relative to Western harzburgites and are possibly residue after moderate partial melting (~15 %) whereas the Western harzburgite is residue after high partial melting (~25 %). The chromian spinel in the Western Khoy chromitites contains inclusions such as clinopyroxene, olivine and platinum group mineral‐bearing sulfides. These Western chromitites were possibly formed at two stages during arc growth and are divided into the moderately high‐Cr# chromitites (Barajouk and Hessar) and the high‐Cr# chromitites (Chuchak A and C). The former crystallized from island‐arc‐tholeiite (IAT) melts during reaction with the host depleted harzburgites, whereas the latter crystallized from boninitic melts (second stage melt) during reaction with highly depleted harzburgite in a supra‐subduction‐zone environment. Based on the mineral chemistry of chromian spinels, pyroxenes, and mineral inclusions, the chromitites and the host peridotites from the Eastern and Western Khoy ophiolites were formed in a back‐arc basin and arc‐related setting, respectively. The Khoy ophiolitic complex is a tectonic aggregate of the two different ophiolites formed in two different tectonic settings at different ages.     

Landslide susceptibility mapping using Genetic Algorithm for the Rule Set Production (GARP) model

Investigation on landslide phenomenon is necessary for understanding and delineating the landslide prone and safer places for different land use practices. On this basis, a new model known as genetic algorithm for the rule set production was applied in order to assess its efficacy to obtain a better result and a more precise landslide susceptibility map in Klijanerestagh area of Iran. This study considered twelve landslide conditioning factors (LCF) like altitude, slope, aspect, plan curvature, profile curvature, topographic wetness index (TWI), distance from rivers, faults, and roads, land use/cover, and lithology. For modeling purpose, the Genetic Algorithm for the Rule Set Production (GARP) algorithm was applied in order to produce the landslide susceptibility map. Finally, to evaluate the efficacy of the GARP model, receiver operating characteristics curve as well as the Kappa index were employed. Based on these indices, the GARP model predicted the probability of future landslide incidences with the area under the receiver operating characteristics curve (AUC-ROC) values of 0.932, and 0.907 for training and validating datasets, respectively. In addition, Kappa values for the training and validating datasets were computed as 0.775, and 0.716, respectively. Thus, it can be concluded that the GARP algorithm can be a new but effective method for generating landslide susceptibility maps (LSMs). Furthermore, higher contribution of the lithology, distance from roads, and distance from faults was observed, while lower contribution was attributed to soil, profile curvature, and TWI factors. The introduced methodology in this paper can be suggested for other areas with similar topographical and hydrogeological characteristics for land use planning and reducing the landslide damages.     

Intertidal gastropod assemblages shaped by key environmental variables across the northern Persian Gulf and the Gulf of Omanss

Variations in environmental factors can alter the species distribution pattern in intertidal rocky shores. The Persian Gulf (PG) and the Gulf of Oman (GO) vary substantially with respect to environmental and oceanographic conditions. The abundance and biodiversity of intertidal rocky gastropods in five locations across the northern PG and the GO were compared, and the environmental variables underlying the distribution pattern of these organisms were investigated. A total of 67 gastropod species were identified. The largest average density (294 ind./m²) and diversity (N = 43) for gastropods occurred in the Hotel Lipar station (LIP) located in Chabahar Bay in the GO. Clypeomorus bifasciata (107.43 ind./m²) followed by Cerithium caeruleum (94.67 ind./m²) were the most abundant species. Planaxis sulcatus and Siphonaria spp. occurred in all locations during both sampling occasions. Species richness and abundance of gastropods showed significant differences between LIP and remaining locations. A significant difference was found in assemblage structure across locations. In general, the species richness and density in the locations at GO were significantly larger than those locations in the PG, suggesting that the harsh environmental condition in the PG might be the forcing factor for this diminish. Distinct grouping was observed in both assemblage structure and species composition between locations in the PG and the GO. The spatial and temporal distribution patterns of gastropods assemblages were significantly correlated with variation in salinity and substrate rugosity.