Reconnaissance geochemical survey in the Marahiq area,Wadi Allaqi region,south Egypt: a preliminary assessment of stream sediments for gold placer and environmental hazard

The Marahiq area represents a portion of the Pan-African belt from the Neoproterozoic age in south Egypt and includes metamorphosed ultramafic rocks, metavolcanic rocks, and granodiorite pluton. The area is characterized by the ancient abandoned Au mine and the recent active talc mines. The present paper provides a preliminary assessment of stream sediments for gold (Au) placer and environmental hazard. Steam sediments from 36 stations were analyzed using ICP-MS for determining the concentration of 53 elements. Various statistical techniques, graphical representations, a set of complementary sediment quality assessment methods, and different mapping methods have been applied. The results showed that Au and the investigated elements were influenced by long history of the ancient mining activities and weathering processes, leading to elevate Au and some heavy metal(loid)s concentrations and exhibit enrichment ratios as follows: Te > As > Au > Cu > Cd > Co > Ni > V. Whereas Cd, Co, and V were attributed to geogenic origin, As, Au, Cu, Ni, and Te were derived from anthropogenic mining activities. It is found that the anomalies of Au and the element of interest are indicative of Au placer and point out a new perspective Au-sulfide mineralization hosted along the favorable tectonic zones that were the main source of Au placer. Both As and Te are good pathfinders to explore Au placer and related mineralization. Environmentally, the excess of As, Cu, Ni, and Te could generate moderate levels of contamination and low level of ecological risk in the sediments. Although As, Cu and Ni posed medium–low potentially adverse effects and low toxicity levels, they cannot cause harmful influences on biological life. Accordingly, streambed sediments are considered as safe and acceptable as inoffensive materials for environmental management. Overall, this study is as reference values for governmental organizations for appraising future environmental pollution in the area. Also, it is fruitful for Au placer and promising with success for Au exploration along the shear zones and strike-slip faults.     

Geochemical evaluation and environmental application of Yemeni natural zeolite as sorbent for Cd<Superscript>2+</Superscript> from solution: kinetic modeling,equilibrium studies,and statistical optimization

Yemeni natural zeolite was characterized by XRD, SEM, FTIR and XRF as well as its applicability as a sorbent material for Cd²⁺ ions in aqueous solutions. The zeolitic sample is clinoptilolite-K of heulandite group with intermediate Si/Al ratio. The removal% of Cd²⁺ by natural clinoptilolite was investigated as a function of contact time, zeolite dose, pH and initial concentration of Cd²⁺ ions. Kinetic experiments indicated that sorption of Cd²⁺ follows two steps: rapid ion exchange process on the outer surface is followed by slow adsorption process on the inner surface of clinoptilolite. The equilibrium was attained after 120 min, and the results were fitted well with pseudo-second order and Elovich kinetic models. The Cd²⁺ removal% is strongly dependent on pH value and increases with the increasing pH value. Equilibrium sorption isotherm of Cd²⁺ by clinoptilolite was described well using the Langmuir, Freundlich, and Temkin isotherms models. However, the data relatively well fitted with Freundlich model (R ² = 0.97) rather than by the other models. Response surface methodology in conjunction with central composite rotatable statistical design was used to optimize the sorption process. The model F-value indicated the high significance of second-order polynomial model to represent the interaction between the operating parameters. From the Design Expert’s optimization function, the predicted optimum conditions for maximum removal% of Cd²⁺ (80.77%) are 116 min contact time, 0.27 gm dose, and pH 7 at an initial Cd²⁺ concentration of 25 mg/L.     

Comparison of DRASTIC and DC resistivity modeling for assessing aquifer vulnerability in the central Nile Delta,Egypt

DRASTIC indexing and integrated electrical conductivity (IEC) modeling are approaches for assessing aquifer vulnerability to surface pollution. DRASTIC indexing is more common, but IEC modeling is faster and more cost-effective because it requires less data and fewer processing steps. This study aimed to compare DRASTIC indexing with IEC modeling to determine whether the latter is sufficient on its own. Both approaches are utilized to determine zones vulnerable to groundwater pollution in the Nile Delta. Hence, assessing the nature and degree of risk are important for realizing effective measures toward damage minimization. For DRASTIC indexing, hydrogeological factors such as depth to aquifer, recharge rate, aquifer media, soil permeability, topography, impact of the vadose zone, and hydraulic conductivity were combined in a geographical information system environment for assessing the aquifer vulnerability. For IEC modeling, DC resistivity data were collected from 36 surface sounding points to cover the entire area and used to estimate the IEC index. Additionally, the vulnerable zones identified by both approaches were tested using a local-scale resistivity survey in the form of 1D and 2D resistivity imaging to determine the permeable pathways in the vadose zone. A correlation of 0.82 was obtained between the DRASTIC indexing and IEC modeling results. For additional benefit, the obtained DRASTIC and IEC models were used together to develop a vulnerability map. This map showed a very high vulnerability zone, a high-vulnerability zone, and moderate- and low-vulnerability zones constituting 19.89, 41, 27, and 12%, respectively, of the study area. Identifying where groundwater is more vulnerable to pollution enables more effective protection and management of groundwater resources in vulnerable areas.     

Combined hydrogeological and nitrate modelling to manage water resources of the Middle Soummam Aquifer,Northeast of Algeria

Water management is one of the most challenges in Algeria, a semi-arid Mediterranean country confronted to a serious water stress. The country will have to endure, beyond 2025, a situation of chronic water penury, adding an excessive pollution of the majority of groundwater reservoirs. The management of water resources by combined approach using hydrogeological model and nitrates evolution model was experimented in the Middle Soummam valley. The alluvial aquifer, offering good hydrodynamic and geometrical characteristics, is over-exploited, providing in drinking water Akbou and Tazmalt cities and irrigation perimeters. If exploitation continues at these steady paces, the depletion of the water resource and the hydrochemical imbalance will be inevitable. On the one hand, the results of hydrodynamic model, based on an increase of the water takings and simulated needs from 24.71 Mm³/year in 2015 into 39.69 Mm³/year in 2030, show a critical withdrawal. The aquifer budget expresses the inversion of flow between the wadi and the aquifer where the wadi feeds the groundwater reservoir. This hydrodynamic inversion was attributed to simulated pumping rates which increased and exceeded 100,000 m³/day, but the aquifer was partially relieved by the weight of the exploitation through Tichy Haf dam. The water management strategy adopted in this study was based on management measures promoting zones, which have been delimited between Tazmalt and Akbou, and containing important water quantities available in the axis of the valley. However, according to the depleted in isotopes of ¹⁸O and ²H, which could be explained by the influence of a paleoclimatic effect and suggested that the aquifer recharge would have largely been made under a colder climate, pumped groundwater could be old, and the implementation of new pumping sites has been studied minutely. On the other hand, the hydrogeochemical modelling allowed following nitrates concentrations in order to project their evolution. Four wells on 25 react in face to the imposed conditions in each scenario simulated until 2030, showing inertia of pollution, and confirmed after three series of tests. This inertia would be related to the hydraulic gradients and hydraulic conductivities, aquifer thickness and recharge. The low hydraulic gradients lead to a rather slow flow velocity and thus to an inertia in the dispersion of nitrates, with a mass transport weakened by the hydrodynamic conditions. It is also related to the aquifer thickness; when the aquifer is powerful (65–85 m), the stock of water would be important and allows a dilution process. The reverse is true for the simulated boreholes where the concentrations remain invariant; the aquifer is less powerful (32–37 m). Finally, the recharge effect through the rain was evoked; the aquifer is unconfined, and the rain water and pollution that reached the piezometric level can remain in position in slow hydrodynamic conditions. The methodology was demonstrated through a combination of monitoring and modelling for both water quantity and quality and the importance to use numerical models to support water resources management strategy in the Mediterranean aquifers.     

Effect of sodium sulphate on the shear strength of clayey soils stabilised with additives

The effect of sulphates on the soil stabilisation using mineral additives such as lime, cement and fly ash has been reported by several researchers. The effect of sodium sulphate (Na₂SO₄) (0–6% by dry weight of soil) on the behaviour of the grey clayey soil (GS) and red clayey soil (RS) stabilised with lime (L) (0–8%), natural pozzolana (NP) (0–20%) and with a combination of lime-natural pozzolana (L–NP) was investigated. The soil specimens were subjected to testing of direct shear strength after 7, 30, 60 and 120 days of curing period. In the absence of Na₂SO₄, the results show that both clayey soils can be successfully stabilised with L or with a combination of L–NP, which substantially increases their shear strength and produces high values of shear parameters. However, at short curing period and for any content of Na₂SO₄, a further increase in shear strength and shear parameters is observed. Moreover, after 30 days of curing, the RS specimens stabilised with L or with NP alone are altered when the Na₂SO₄ is greater than 2%, whereas the GS specimens are not altered. However, the alteration of RS specimens is little when the L and NP are combined on curing with a high content of Na₂SO₄. Generally, the effect of Na₂SO₄ on both stabilised clayey soils depends on the curing time, percentage of additives used and their type, mineralogical composition of stabilised soils and Na₂SO₄ content.     

Identification and mapping of clay minerals in the region of Djebel Meni (Northwestern Algeria) using hyperspectral imaging,EO-1 Hyperion sensor

Applied in Djebel Meni (Northwestern of Algeria), this research highlights the results obtained from the supervised classification using the Spectral Angle Mapper (SAM) algorithm, through introducing the spectral signatures of illite, kaolinite, and montmorillonite, via Jet Propulsion Laboratory (JPL) spectral library. These results were compared to the ones of the SAM classification, which use spectral signatures obtained by the Sequential Maximum Angle Convex Cone (SMACC) endmembers extraction algorithm. This implies the ability to detect and identify any object present on the Earth’s surface, whether its nature is mineral, vegetal, or human made, from hyperspectral imaging. By extracting the spectral signatures with the SMACC algorithm and matching them to the current signatures of JPL spectral library, comparing spectral signatures with another is not an easy task. Indeed, for a better comparison and a more appropriate interpretation in the use of the SAM classification, the results obtained were very relatively convincing because, regarding very strong similarities. It appears also that the signatures extracted with SMACC occupy the same areas as those of the JPL spectral library. This method of detection and identification of any present object on the Earth’s surface is rather conclusive.     

Water use efficiency of olive tree under two water treatments in Tunisian semi-arid conditions

Olive trees are grown under high evaporative demand and less precipitations that are variable in time and space especially in semi-arid conditions. The objective of this work is to determine the most efficient water treatment applied in an olive field (Olea europaea L. cv Chemlali) from the 98th to the 294th Julian day, in Tunisian semi-arid conditions. The choice of this time frame was done to control the effect of irrigation on the trees behavior in the irrigation period of the year (from April to October) and determine the most sensitive phenological stages to irrigation. For this reasons, two water treatments were applied: T100% (irrigation at 100% of Available Water Content (AWC)) and T50% (irrigation at 50% AWC). The results show that, according to leaf water potential, carbon isotope discrimination, and olive production parameters, the T50% AWC water treatment is the most efficient. The leaf water potential of the two water treatments applied has not exceeded ?2.5 MPa during the whole experiment which indicates that the trees of the two water treatments were not stressed. The T50% AWC shows a water use efficiency of 5.18 g/l compared to 2.93 g/l for T100% water treatment. This result demonstrate that Chemlali cultivar valorizes better low quantities of water rather than high quantities, so saving 50% of water resources applied will ensure the sustainability of water resources and stability of olive production.     

Groundwater chemical and fecal contamination assessment of the Jerba unconfined aquifer,southeast of Tunisia

Located in the southeast of Tunisia, on the Mediterranean Sea, Jerba Island has a semiarid climate condition. The surface water scarcity has made groundwater the main source to supply the domestic, touristic, and agricultural water demand. Unconfined aquifer is a vulnerable costal aquifer system that undergoes several phenomena. This work aims at assessing the geochemical and bacteriological groundwater quality, defining groundwater pollution sources and promoting sustainable development and effective management of groundwater resources in Jerba Island. Data were collected after the wet season in 2014 from 79 wells. Electric conductivity, pH, TDS, and major and fecal tracers (total coliforms, thermotolerant coliforms, Escherichia coli, and Salmonella) were analyzed. Geochemical modeling including the relationships between geochemical tracers Na⁺ vs. Cl^?, Ca²⁺ vs. Cl^?, K⁺ vs. Cl^?, representative ionic ratios (Br^?/Cl^?, Na⁺/Cl^?, Mg²⁺/Ca²⁺), and statistical analysis were used to specify major process contributing to groundwater pollution and main factors controlling groundwater mineralization in the island. Groundwater varieties were hydrochemically classified into three types in terms of salinity values: group 1 (8.86%) to fresh water, group 2 (27.84%) to brackish water, and group 3 (63.29%) belongs to saline water. In addition, groundwater quality revealed high concentrations in chemical pollution tracers (Na⁺, Cl^?, SO₄ ^2?, and NO₃ ^?) and fecal tracers. Besides, most of the sampled wells were contaminated with nitrate (50.63%). Also, thermotolerant coliforms and E. coli were detected in all groundwater samples (96.2% of wells). Results indicated that the Jerba shallow aquifer was under serious threat from both natural and anthropogenic contamination. However, the wild discharge of domestic effluents, septic tanks, and sewage were the main origins of underground water contamination in Jerba Island. The reduction of fecal sources, through constructing normalized latrines is thus recommended.     

Micro-CT and FIB–SEM imaging and pore structure characterization of dolomite rock at multiple scales

With improvements of imaging techniques and computational power, Digital Rock Physics (DRP) has been increasingly used to determine transport and elastic properties of reservoir core plugs. Since numerical computations highly rely on accurate 3D representations of the porous microstructure of the rocks, the imaging technique and the scale at which the imaging is performed is a critical parameter. In this paper, we introduce a multiscale imaging workflow that uses both micro-X-ray tomography (micro-XCT) and focused ion beam combined with scanning electron microscope (FIB–SEM) to characterize a dolomite rock from the microscale to the nanoscale. This allows for the accurate capture of the different heterogeneities that exist in the carbonate (texture, mineralogy, pore size). The reconstructed microporous structures were then used to successfully predict elastic and permeability properties of selected carbonate.     

Evaluating the Baluti Formation at Sararu village,Ora Anticline,Iraqi Kurdistan: a stratigraphic and geochemical approach

Here, we report that a lithostratigraphic unit that outcrops at Sararu village, 6 km northeast of Qumri village that had previously been assigned to the Baluti Formation is not Triassic in age and therefore can not be a correlative equivalent of the Baluti Formation. The outcropping unit at Sararu comprises intercalation of calcareous mudstones and limestones, and is indeed lithologically similar to the Baluti Formation (Late Triassic). The Baluti Formation (also known as the Baluti Shale) is known from a typical section found at the Gara Anticline and from many deep drilled oil exploration wells. It is generally composed of alternations of the shales, limestones, dolomites, and dolomitic limestones. It is underlain by the Kurra Chine Formation (Upper Triassic) and overlain by the Sarki Formation (Lower Jurassic). In this study, detailed field observations, an assessment of stratigraphic successions, studies of microfossils such as age-specific planktonic foraminifera (e.g., Globotruncana bulloides), and age-specific biomarkers (oleanane index and C28/C29 regular sterane index) reveal that the lithostratigraphic unit at Sararu village can not be a correlative equivalent of the Baluti Formation, and it is more likely from the Upper Cretaceous. There are a number of Upper Cretaceous formations found in this part of Kurdistan, but based on fossil-type and palaeoenvironmental associations, the Hadiena Formation, from the Upper Cretaceous, is considered as the most likely correlative equivalent to the calcareous mudstone and limestone succession found at Sararu village.