Interplay between detrital and diagenetic processes since the last glacial maximum on the northwest Iberian continental shelf

Integrated analyses of magnetic, geochemical and textural data on six cores from the northwestern Iberian continental shelf allowed the reconstruction of the paleoenvironmental evolution of this area since the last glacial maximum (LGM). Four sedimentary units were identified, representing a succession from fluvial and subaerial settings to high and finally low-energy marine deposits subsequent to the post-LGM sea-level rise. The uppermost unit was deposited during the Holocene and its magnetic properties were controlled by the interplay between detrital input and early diagenetic reductive dissolution of magnetic minerals. Identification of a primary steady-state early diagenetic signal allowed the recognition of periods of increased detrital input, bounded by intervals of lower detrital input and intensified reductive diagenesis related to intensified upwelling in the area. These paleoenvironmental alternations are consistent with the climatic evolution of the late Holocene. During the Roman Warm Period and Medieval Warm Period, the combined effect of greater humidity and intense agricultural and mining activities led to a greater erosion and transport of detrital sediments to the shelf. In contrast, enhanced diagenetic reduction intervals, caused by upwelling intensification, were roughly coincident with the colder Dark Ages and the Little Ice Age.     

Improving Short- and Long-term Stability of Underground Gypsum Mine Using Partial and Total Backfill

The stability of underground mines represents a key issue for active and abandoned mines. Over the last few years, several collapses of underground mines in France have affected existing buildings and infrastructures. Many factors are generally identified as the cause of failures: pillar ageing, fractures, and pillars’ height to width ratio, etc. Among the treatment techniques available to prevent instability and reduce the deterioration of pillars, backfill is the most frequently used. A research programme, supported by the French Ministry of the Environment, was developed to study the operability of partial and total backfill using waste material in the Livry-Gargan gypsum mine (near Paris, France), where pillar height is 17 m. The paper focuses on: (1) the characterisation of the gypsum and fill material (laboratory and in situ tests), (2) the in situ measurements, involving 5 pillars equipped with 19 pressure cells, since 1999, (3) and numerical modelling of fractured pillars performed in order to improve understanding of the effects of backfill on the stability of room-and-pillar mines. The study clearly shows the operability and the advantages of partial and total backfill for short-term pillar stability. The induced horizontal pressure generated by backfill can reach 200 kPa. The use of numerical modelling also shows the effect of backfill on fractures and that backfill reduces indicatively the shear displacement and the opening of fractures. Numerical modelling helps in identifying the mechanisms of backfill and in a better understanding of the behaviour of backfilled mines.     

Ecological background to Plio-Pleistocene hominin occupation in North Africa: the vertebrate faunas from Ain Boucherit,Ain Hanech and El-Kherba,and paleosol stable-carbon-isotope studies from El-Kherba,Algeria

In contrast to well-studied paleoenvironments of Plio-Pleistocene hominin sites in East Africa, little is known about the ecology of the earliest North African human occupation sites. The recent studies at Ain Hanech and El-Kherba in northeastern Algeria have broadened the range of Plio-Pleistocene hominin ecology to include the earliest known archaeological sites documented in North Africa. Ain Hanech and El-Kherba are significant for yielding savanna-like faunas associated with Oldowan stone tools dated back to approximately 1.8 million years ago. This paper focuses on reconstructing the ecology of Ain Hanech and El-Kherba based on excavated faunas and stable carbon isotope of pedogenic carbonates from El-Kherba stratigraphic profile. The results point out to an overall open paleolandscape and a C₃ predominantly paleovegetation both woody and grasses. In addition, the stable-carbon-isotopic evidence shows a clear environmental change through time at El-Kherba, which likely impacted hominin foraging activities in level A.     

Diagenesis and reservoir quality analysis in the Lower Cretaceous Qishn sandstones from Masila oilfields in the Sayun–Masila Basin,eastern Yemen

Lower Cretaceous sandstones of the Qishn Formation have been studied by integrating sedimentological, petrological and petrophysical analyses from wells in the Masila oilfields of eastern Yemen. These analyses were used to define the origin, type of diagenesis and its relation to reservoir quality. The sandstones of the Qishn Formation are predominately quartz arenite to subarkose arenite with sublitharenite and quartz wackes displaying a range of porosities, averaging 22.33%. Permeability is likewise variable with an average of 2844.2 mD. Cementation coupled with compaction had an important effect on porosity destruction after sedimentation and burial. The widespread occurrence of early calcite cement suggests that the sandstones of the Qishn Formation lost significant primary porosity at an early stage of its diagenetic history. In addition to poikilotopic calcite, several different cements including kaolinite, illite, chlorite and minor illite–smectite occur as pore‐filling and pore‐lining cements, which were either accompanied by or followed the development of the early calcite cement. Secondary porosity development occurred due to partial to complete dissolution of early calcite cements and feldspar grains. The new data presented in this paper suggest the reservoir quality of Qishn sandstones is strongly linked to their diagenetic history; hence, the reservoir quality is reduced by clay minerals, calcite and silica cements but is enhanced by the dissolution of the unstable grains, in addition to partial or complete dissolution of calcite cements and unstable grains. Copyright © 2015 John Wiley & Sons, Ltd.     

Albian oceanic anoxic events in northern Tunisia: Biostratigraphic and geochemical insights

Albian pelagic successions of the Nebeur area in northwestern Tunisia consist of radiolarian-bearing and organic-rich black shale beds, which represent the lower part of the Fahdene Formation. The carbonate content of the organic-rich beds ranges between 40 and 48%. Total organic carbon (TOC) analyses via Rock Eval pyrolysis yielded values ranging between 0.7 and 2.8% and a mixed marine/terrestrial origin. T_max values vary between 424 and 450 °C, indicative of submature to mature organic matter. High resolution planktic foraminiferal and radiolarian biostratigraphy suggest that the black shales beds span the mid- to late Albian, confined to the middle part of the Ticinella primula zone, upper Biticinella breggiensis zone and lower appeninica + buxtorfi zone. Episodes of organic-rich deposition in the “Tunisian Trough” are interpreted as being the sedimentary record of the global oceanic anoxic events OAE1b, c, and d respectively. Age-diagnostic radiolarian assemblages recovered from late Albian organic-rich black shales lie within the UA13–UA14 boundary biochronozones. The abundance of radiolarian and calcispheres (i.e. pithonella) within the black shales suggests high productivity periods and eutrophic conditions probably triggered by upwelling currents.     

Atmospheric Lead in PM2.5 after Leaded Gasoline Phase‐out in Jeddah City,Saudi Arabia

The objective of the present study is the assessment of Jeddah ambient air quality in terms of PM_2.5, and the associated lead 7 years after phasing out leaded gasoline in Saudi Arabia. Twenty‐four air samples were collected at four locations throughout Jeddah during the period from December 23, 2008 to April 6, 2009. The collected PM_2.5‐samples were analyzed by ICP‐MS for determination of lead. The average atmospheric PM_2.5 concentration was 50.8 µg/m³. Atmospheric PM_2.5‐concentrations were higher than the 24‐h U.S. National Ambient Air Quality Standards (NAAQS) in 14 sample events. The average lead concentration for all samples was 0.07326 µg/m³. Atmospheric lead concentration was dependent on the sampling location. Concentrations at the two southern locations were higher than at the two northern locations. Southern locations had higher lead concentrations due to very high traffic density, in addition to their proximity to industrial zone. In general, the results of this study show a considerable decrease in atmospheric lead concentration 7 years after phasing out leaded gasoline. The study recommends further studies to accurately determine the current sources of atmospheric lead.     

Piles in fully liquefied soils with lateral spread

The paper provides a new analysis procedure for the assessment of the lateral response of isolated piles/drilled shafts in saturated sands as liquefaction and lateral soil spread develop in response to dynamic loading such as that generated by the earthquake shaking. The presented method accounts for: (1) the development of full liquefaction in the free-field soil that could trigger the lateral spread of the overlying crust layer; (2) the driving force exerted by the crust layer based on the interaction between the pile and the upper non-liquefied soil (crust) layer; and (3) the variation of the excess pore water pressure (i.e. post-liquefaction soil strength) in the near-field soil with the progressive pile deflection under lateral soil spread driving force. A constitutive model for fully liquefied sands under monotonic loading and undrained conditions is developed in order to predict the zone of post-liquefaction zero-strength of liquefied sand before it rebounds with the increasing soil strain in the near-field. The analytical and empirical concepts employed in the Strain Wedge (SW) model allow the modeling of such a sophisticated phenomenon of lateral soil spread that could accompany or follow the occurrence of seismic events without using modifying parameters or shape corrections to account for soil liquefaction.     

Geochemical Record of the Cenomanian–Turonian Anoxic Event in Tunisia: Is it Correlative and Isochronous to the Biotic Signal?

In Tunisia, five Bahloul spaced sections, Bargou, Jerisa, Guern Halfaya, Kherij and Gafsa were analyzed for biostratigraphy (foraminifera and radiolarians) and major and trace elements. This high-resolution biostratigraphic and chemostratigraphic integrated analyses for the Late Cenomanian–Early Turonian Bahloul Formation provide new insight into the palaeoceanographic evolution of the southern Tethyan margin. Relative low abundance of related terrigenous Ti/Al and K/Al ratios and enrichment of some productivity proxies such as Ba, Cu, and Ni (organic matter related trace elements) suggests that the Bahloul, deposited during a relatively short period (0.5 Ma), was of relatively elevated primary productivity and minimal detrital input. While higher D* values concurrent with lower Ti/Al ratios are interpreted as caused by enhanced fluvial material contribution, due to more humid climate during the OAE-2. Enhanced humidity triggered probably fluvial influxes, resulted in a sluggish water circulation and consequent anoxic/euxinic conditions favoring the preservation of organic matter at the bottom. Enrichments in redox-sensitive trace metals U, V, and Mo in the Bahloul Formation deposits and redox indices, such as V/(V+Ni), U/Th, V/Cr, and Ni/Co, indicate that oxygen-restricted conditions prevailed during the Late Cenomanian to earliest Turonian times and correlate well with relative abundances of some foraminiferal and radiolarian paleo-environmental relevant indicators. High Baxs values and Uauth may indicate anoxic conditions at least at the water–sediment interface during the Bahloul Formation deposition and provide information about low to moderate sulfate-reduction reactions.