New information on radionuclides concentration in phosphorites originating from Tunisia and Algeria

In this study we investigate the radiological hazard of naturally occurring radioactive material in Tunisian and Algerian phosphorite deposits. Eight samples of phosphorite were collected from the phosphorite mines. The Tunisian and Algerian phosphorites occur in the Late Paleocene and Lower Eocene (Ypresian-Lutetian) in age (Béji Sassi 1984 and Zaïer 1999). Activity concentrations in all the samples were measured by alpha spectrometry and gamma spectrometry. Alpha spectrometry analyses show that the specific activity values of ²³⁸U, ²³⁴U and ²³⁵U in the samples of Tunisian phosphorite were 327?±?7 (321–327), 326?±?6 (325–331) and 14.50?±?0.72 (13.90–15.57) Bq kg^?1, respectively. Specific activity measured by gamma spectrometry in the samples of the Tunisian and Algerian phosphorite shows a small difference. Specific activity levels of ⁴⁰K, ²²⁶Ra, ²³²Th, ²³⁵U and ²³⁸U in the phosphorite samples from Tunisia were, respectively, 71.10?±?3.80, 391.54?±?9.39, 60.38?±?3.74, 12.72?±?0.54 and 527.42?±?49.57 Bq kg^?1 and Algeria were 15.72?±?1.73, 989.65?±?12.52, 12.08?±?1.20, 47.50?±?1.52 and 1,148.78?±?7.30 Bq kg^?1, respectively. The measured value of specific activity of ²³²Th and ⁴⁰K in the Tunisian phosphorite samples is relatively higher than that found in the samples of Algerian phosphorite. The measured activity of uranium (²³⁸U) in the Tunisian phosphorite (527?±?49) Bq kg^?1 is lower than in Algerian phosphorite. The measured activity of ²³⁸U in the Tunisian phosphorite samples was (527–1,315?±?65) ²³⁸U Bq kg^?1 which is higher than its maximum background value of 110 Bq kg^?1 in soils of the various countries of the world (Tufail et al. Radiat Meas 41:443–451, 2006). Different geological origins of phosphorites deposits are the main reason for the large spread in worldwide specific activities. The obtained results of uranium concentrations in phosphorites of different types (Algerian and Tunisian) demonstrate that the uranium concentrations are mainly governed by the phosphatic material. The present study reveals that phosphorite deposits contain natural radioactivity higher than background level.     

Saturated and unsaturated River Nile/groundwater aquifer interaction systems in the Nile Valley, Egypt

Surface water bodies interact with underlying aquifer systems, creating a complex flow system and flow paths. In general, a surface water body may be classified as gaining, losing, or flow through on the basis of its interaction with the surrounding aquifer. In the Nile Valley, the quaternary aquifer system is in a direct hydraulic interaction with the River Nile, canals, and drains. In this study, a regional numerical model was developed and used to evaluate the interaction between surface water bodies and the quaternary aquifer system in the Nile Valley. The solution is considered for a quasi three-dimensional, steady-state groundwater flow. The model used simulates the interaction between surface water bodies and groundwater for saturated and unsaturated flow conditions. In addition, a hydrodynamic model was used to simulate different extreme (high and low) scenarios for Nile surface water levels along the distance between Old Aswan Dam and Delta Barrages. Model calibration shows close results, and the model was used to simulate surface water levels. Results indicate that the Nile River acts as a drain for the quaternary aquifer (gaining water from the aquifer), although in the reaches upstream of the main barrages, the Nile loses the water, recharging the aquifer. All other main canals are recharging the aquifer system. The seepage rate depends mainly on the difference in piezometric head between the aquifer system and surface water bodies, as well as the hydraulic conductance of the base layer sediments of the surface water body. The model was used to evaluate the regional water balance for the Nile Valley and to estimate the surface water bodies' gains and losses.     

The use of three physico-chemical methods in the study of the organic matter associated with the sedimentary phosphorites in Djebel Onk Basin, Algeria

The study of the organic matter (OM) associated with the phosphate ore of Kef Essennoun deposit (Djebel Onk mining basin, Algeria) was with a view to determine the decomposition degree of the OM within the pellets and the matrix, and the conditions of diagenesis. The sedimentary phosphates of this deposit are constituted of sub-rounded, phosphate-rich grains (pellets) dispersed in a surrounding, much poorer than pellets in P, matrix (or gangue). The survey of the OM associated with both pellets and matrix used several types of analyses: scanning electron microscopy (SEM), scanning electron microscope with energy-dispersive X-ray analysis, Fourier transform infrared spectroscopy and nuclear magnetic resonance spectroscopy. The results show the OM, dispersed approximately homogeneously, in the form of large flat particles, within the gangue and within the phosphatic pellets in the form of small particles. The O/C ratio showed that the OM is more oxidised in the matrix than within the pellets. The oxidation increased with the phosphatisation rate of the pellets and more with the carbonation rate of the matrix, but it decreased with the silicification degree in the siliceous carbonated matrix. Two major functional classes were distinguished within pellets: aliphatic and oxygenated ones, the latter being fundamentally present in humic OM. The presence and abundance of these humic compounds in pelletal phosphorites are known from the 1980s and considered as witnessing a formation of apatite in a strictly closed environment, inside the pellet.     

Define a protected buffer zone for Ismailia Canal, Egypt using Geographic Information Systems

Ismailia Canal is the principle source of drinking water supply to Suez Canal and Sinai governorates. However, Ismailia Canal is endangered from unwise activities in the surrounding environment. Drinking water resources protection can be implemented using land-use monitoring system or through land-use controls based on hydrogeologic mapping to study the impacts of development on water quality. Our approach is to protect the direct and indirect catchment areas for surface water supply, especially the sensitive areas, those that are more vulnerable to contamination than other areas. Remote sensing and geographic information system techniques are applied to construct and integrate the hydrogeological data, inventory for potential sources of contamination and mapping the sensitive areas in order to construct the a protected buffer zone for Ismailia Canal, and to constrain the development activities in all the surrounding areas of surface water supply. The sensitive areas are delineated, where extra protection is required, based on soils properties, geology, and specific hydrogeological criteria. Industrial areas, drains, and septic tanks in the surrounding villages are the common potential sources of contamination. The hydrologic relation between Ismailia Canal and groundwater has great variations. Comprehensive plan for water protection were composed. It includes maintaining three natural protection zones of at least 300-m width along the main course of the Canal and delineating vulnerable zones depending on the aerial extension of the sensitive areas within 10 km on both sides of the Canal. Specific protection measures are recommended over the sensitive areas. The natural ecosystems of swamps around Ismailia Canal should be conserved and the processes of continuous burial prevented.     

Hydrogeophysical study for additional groundwater supplies in El Heiz Area, Southern part of El Bahariya Oasis, Western Desert, Egypt

El Bahariya Oasis is a part of the great groundwater reservoir of the Western Desert of Egypt. The different stratigraphic units, the water-bearing zones, aquifer potentiality conditions, and the favorable locations for drilling new wells were evaluated by carrying out 24 Schlumberger vertical electrical soundings (VESs), along with the data of some wells drilled in the near vicinity of the measuring sites. The results of the interpreted field data revealed the presence of ten distinctive subsurface geoelectric layers; a thin surface, dry loose sand and gravel, sandy clay and shale interclations, saturated coarse sand layer, shale and clay, and saturated fine sandstone and saturated coarse sandstone. The aquifer is a multilayer aquifer with different thicknesses represented by the fourth, sixth, eighth, and tenth geoelectric layers. Results also revealed that the thicknesses of the water-bearing horizons increase towards the east direction, consequently the aquifer potentiality increases. Therefore, the best production well locations are in that direction. Depth to water starts from 40 m at VES no. 14 and increases gradually toward the east to reach 66 m at VES no. 5. Hydrogeochemical analysis of two groundwater samples taken from Ein El Ezza and well no. 2 showed that groundwater in the study area is suitable for agricultural purposes but not for human consumption due to the high iron content. Recommendations concerning site selection for drilling new productive groundwater wells are given.     

Using GIS modeling to assess the agricultural sustainability in Kafr El-Sheikh governorate, Nile Delta, Egypt

The evaluation of agricultural sustainability status helps in identifying specific indicators that constrain the achievement of sustainable agriculture. The agricultural sector in Egypt is facing major sustainability constraints such as scarce land and water resources, environmental degradation, and rapid population growth as well as institutional arrangement including land tenure and farm fragmentation, agricultural administration, lack of infrastructure, and credit utilization and high interest rates. This study aims to evaluate the agricultural sustainability in some areas in Kafr El-Sheikh governorate, north of the Nile Delta; the international framework for evaluating sustainable land management was used for realizing this objective. The map of the physiographic soils of the studied area was produced depending upon Landsat ETM⁺ images analysis; the results indicate that the area includes three main landscapes, i.e., alluvial, lacustrine, and marine plains. The characteristics of productivity, security, protection, economic viability, and social acceptability in the different mapping units were assessed. The obtained results show that the studied area includes two different class types, the first are the lands that are marginally below the requirement of sustainability and the second are those lands that do not meet sustainability requirements. The former class is represented by the physiographic units of alluvial plain, whereas the latter class is represented by the physiographic units of the lacustrine and marine plains. The sustainability constrains in the studied area are related to the soil productivity, economic viability, and social acceptability.     

Early Bartonian orthophragminids (Foraminiferida) from Reineche Limestone,north African platform,Tunisia: taxonomy and paleobiogeographic implications

The orthophragminids in lower Bartonian Reineche Limestone member, a fossiliferous shallow-marine unit exposed in Cap Bon peninsula in Tunisia, are represented by 17 species assigned to Discocyclinidae Galloway 1928 and Orbitoclypeidae Brönnimann 1946. These taxa, associated with nummulitids and alveolinids, belong to the lineages of Discocyclina Gümbel 1870, Nemkovella, 1987, Orbitoclypeus Silvestri 1907, and Asterocyclina Gümbel 1870, described for the first time from north Africa lying at the southern margin of Tethyan ocean during Paleogene. We identified Nemkovella evae, previously not recorded in upper Lutetian/lower Bartonian and younger Eocene deposits of northern Tethyan platforms, and erected a new subspecies, N. evae reinechensis n. ssp. A comparison of Reineche orthophraminids, assigned to orthophragmines zone (OZ) 12 and shallow benthic zone (SBZ 17), to the well-described coeval assemblages at northern Tethyan platforms in Italy, Hungary, Turkey, and to those in Kutch Basin in the Indian subcontinent suggests that some species are confined to certain paleogeographic domains. Orbitoclypeus haynesi, the only orbitoclypeid and the most abundant orthophragminid in lower Bartonian deposits in Kutch, appears to be the most common orbitoclypeid in Reineche Limestone. In Europe, this species is not known and is replaced by Orbitoclypeus varians, the most common orbitoclypeid in middle Eocene of central Europe. Both species occur in varying proportions in marine successions in Turkey. Asterocyclina sireli, identified so far only in Turkey, occurs in Reineche Limestone and in lower Bartonian deposits in Kutch. This species is recorded for the first time in the Indian subcontinent. Relying on present study, as well as our recent studies in Kutch Basin, we conclude that the generic and specific diversity of orthophragminids decreases eastward from the peri-Mediterranean region to Indian subcontinent and to the western Pacific.     

Coronal Hole Influence on the Observed Structure of Interplanetary CMEs

We report on the coronal hole (CH) influence on the 54 magnetic cloud (MC) and non-MC associated coronal mass ejections (CMEs) selected for studies during the Coordinated Data Analysis Workshops (CDAWs) focusing on the question if all CMEs are flux ropes. All selected CMEs originated from source regions located between longitudes 15E?–?15W. Xie, Gopalswamy, and St. Cyr (2013, Solar Phys., doi: 10.1007/s11207-012-0209-0 ) found that these MC and non-MC associated CMEs are on average deflected towards and away from the Sun–Earth line, respectively. We used a CH influence parameter (CHIP) that depends on the CH area, average magnetic field strength, and distance from the CME source region to describe the influence of all on-disk CHs on the erupting CME. We found that for CHIP values larger than 2.6 G the MC and non-MC events separate into two distinct groups where MCs (non-MCs) are deflected towards (away) from the disk center. Division into two groups was also observed when the distance to the nearest CH was less than 3.2×10⁵ km. At CHIP values less than 2.6 G or at distances of the nearest CH larger than 3.2×10⁵ km the deflection distributions of the MC and non-MCs started to overlap, indicating diminishing CH influence. These results give support to the idea that all CMEs are flux ropes, but those observed to be non-MCs at 1 AU could be deflected away from the Sun–Earth line by nearby CHs, making their flux rope structure unobservable at 1 AU.     

Influence of Degree of Saturation in the Electric Resistivity–Hydraulic Conductivity Relationship

The relationship between aquifer hydraulic conductivity and aquifer resistivity, either measured on the ground surface by vertical electrical sounding (VES) or from resistivity logs, or measured in core samples have been published for different types of aquifers in different locations. Generally, these relationships are empirical and semi-empirical, and confined in few locations. This relation has a positive correlation in some studies and negative in others. So far, there is no potentially physical law controlling this relation, which is not completely understood. Electric current follows the path of least resistance, as does water. Within and around pores, the model of conduction of electricity is ionic and thus the resistivity of the medium is controlled more by porosity and water conductivity than by the resistivity of the rock matrix. Thus, at the pore level, the electrical path is similar to the hydraulic path and the resistivity should reflect hydraulic conductivity. We tried in this paper to study the effect of degree of groundwater saturation in the relation between hydraulic conductivity and bulk resistivity via a simple numerical analysis of Archie’s second law and a simplified Kozeny-Carmen equation. The study reached three characteristic non-linear relations between hydraulic conductivity and resistivity depending on the degree of saturation. These relations are: (1) An inverse power relation in fully saturated aquifers and when porosity equals water saturation, (2) An inverse polynomial relation in unsaturated aquifers, when water saturation is higher than 50%, higher than porosity, and (3) A direct polynomial relation in poorly saturated aquifers, when water saturation is lower than 50%, lower than porosity. These results are supported by some field scale relationships.