Spatial and temporal prokaryotic variability in the northern Adriatic Sea

The prokaryotic community, both in terms of abundance and activity (exoenzymatic hydrolysis of proteins, polysaccharides and phosphorylated molecules and leucine uptake), was investigated seasonally for a 3‐year period (2004–2006) in the Gulf of Venice (northern Adriatic Sea). By focusing on spatial and temporal variability, the prokaryote dynamics showed significant variations on a horizontal and seasonal scale, but no substantial differences were observed among years. The basin‐scale variability was mainly influenced by allochthonous inputs from the Po river and the Venice Lagoon, which were the main source of nutrients, acting as a ‘bottom up’ control on prokaryotes. On a seasonal scale, all the microbial parameters (except the polysaccharide degradation) showed significant variations following the temperature fluctuations. The annual rate of change was very low for all the chemical, physical and biological parameters and only the abundance and phosphatase activity of the prokaryotes differed significantly among years.     

Design storm prediction and hydrologic modeling using a web-GIS approach on a free-software platform

The aim of this work has been to implement a set of procedures useful to automatise the evaluation, the design storm prediction and the flood discharge associated with a selected risk level. For this purpose a Geographic Information System has been implemented using Grass 5.0.One of the main topics of such a system is a georeferenced database of the highest intensity rainfalls and their assigned duration recorded in Sicily. This database contains the main characteristics for more than 250 raingauges, as well as the values of intense rainfall events recorded by these raingauges. These data are managed through the combined use of the PostgreSQL and GRASS-GIS 5.0 databases. Some of the best-known probability distributions have been implemented within the Geographical Information System in order to determine the point and/or areal rain values once duration and return period have been defined. The system also includes a hydrological module necessary to compute the probable flow, for a selected risk level, at points chosen by the user.A peculiarity of the system is the possibility to querying the model using a web-interface. The assumption is that the rising needs of geographic information, and dealing with the rising importance of peoples participation in the decision process, requires new forms for the diffusion of territorial data. Furthermore, technicians as well as public administrators needs to get customized and specialist data to support planning, particularly in emergencies. In this perspective a Web-interface has been developed for the hydrologic system. The aim is to allow remote users to access a centralized database and processing-power to serve the needs of knowledge without complex hardware/software infrastructures.     

Thermal expansion along the NaAlSi2O6–NaFe3+Si2O6 and NaAlSi2O6–CaFe2+Si2O6 solid solutions

The high temperature volume and axial parameters for six C2/c clinopyroxenes along the NaAlSi₂O₆–NaFe³⁺Si₂O₆ and NaAlSi₂O₆–CaFe²⁺Si₂O₆ joins were determined from room T up to 800°C, using integrated diffraction profiles from in situ high temperature single crystal data collections. The thermal expansion coefficient was determined by fitting the experimental data according to the relation: ln(V/V ₀) = α(T − T ₀). The thermal expansion coefficient increases by about 15% along the jadeite–hedenbergite join, whereas it is almost constant between jadeite and aegirine. The increase is related to the Ca for Na substitution into the M2 site; the same behaviour was observed along the jadeite–diopside solid solution, which presents the same substitution at the M2 site. Strain tensor analysis shows that the major deformation with temperature occurs in all samples along the b axis; on the (010) plane the higher deformation occurs in jadeite and aegirine at a direction almost normal to the tetrahedral–octahedral planes, and in hedenbergite along the projection of the longer M2–O bonds. The orientation of the strain ellipsoid with temperature in hedenbergite is close to that observed with pressure in pyroxenes. Along the jadeite–aegirine join instead the high-temperature and high-pressure strain are differently oriented.     

Water incorporation in synthetic and natural MgAl2O4 spinel

The solubility and incorporation mechanisms of water in synthetic and natural MgAl₂O₄ spinel have been investigated in a series of high-pressure/temperature annealing experiments. In contrast to most other nominally anhydrous minerals, natural spinel appears to be completely anhydrous. On the other hand, non-stoichiometric Al-rich synthetic (defect) spinel can accommodate several hundred ppm water in the form of structurally-incorporated hydrogen. Infrared (IR) spectra of hydrated defect spinel contain one main O-H stretching band at 3343-3352 cm⁻¹ and a doublet consisting of two distinct O-H bands at 3505-3517 cm⁻¹ and 3557-3566 cm⁻¹. IR spectra and structural refinements based on single-crystal X-ray data are consistent with hydrogen incorporation in defect spinel onto both octahedral and tetrahedral O-O edges. Fine structure of O-H bands in IR spectra can be explained by partial coupling of interstitial hydrogen with cation vacancies, or by the effects of Mg-Al disorder on the tetrahedral site. The concentration of cation vacancies in defect spinel is a major control on hydrogen affinity. The commercial availability of large single crystals of defect spinel coupled with high water solubility and similarities in water incorporation mechanisms between hydrous defect spinel and hydrous ringwoodite (Mg₂SiO₄) suggests that synthetic defect spinel may be a useful low-pressure analogue material for investigating the causes and consequences of water incorporation in the lower part of Earth’s mantle transition zone.     

Understanding hydrological processes in glacierized catchments: Evidence and implications of highly variable isotopic and electrical conductivity data

The spatial and temporal characterization of geochemical tracers over Alpine glacierized catchments is particularly difficult, but fundamental to quantify groundwater, glacier melt, and rain water contribution to stream runoff. In this study, we analysed the spatial and temporal variability of δ²H and electrical conductivity (EC) in various water sources during three ablation seasons in an 8.4‐km² glacierized catchment in the Italian Alps, in relation to snow cover and hydro‐meteorological conditions. Variations in the daily streamflow range due to melt‐induced runoff events were controlled by maximum daily air temperature and snow covered area in the catchment. Maximum daily streamflow decreased with increasing snow cover, and a threshold relation was found between maximum daily temperature and daily streamflow range. During melt‐induced runoff events, stream water EC decreased due to the contribution of glacier melt water to stream runoff. In this catchment, EC could be used to distinguish the contribution of subglacial flow (identified as an end member, enriched in EC) from glacier melt water to stream runoff, whereas spring water in the study area could not be considered as an end member. The isotopic composition of snow, glacier ice, and melt water was not significantly correlated with the sampling point elevation, and the spatial variability was more likely affected by postdepositional processes. The high spatial and temporal variability in the tracer signature of the end members (subglacial flow, rain water, glacier melt water, and residual winter snow), together with small daily variability in stream water δ²H dynamics, are problematic for the quantification of the contribution of the identified end members to stream runoff, and call for further research, possibly integrated with other natural or artificial tracers.     

Comparison of three geostatistical methods for hydrofacies simulation: a test on alluvial sediments

The hydrodispersive properties of porous sediments are strongly influenced by the heterogeneity at fine scales, which can be modeled by geostatistical simulations. In order to improve the assessment of the properties of three different geostatistical simulation methods (Sequential indicator simulation, SISIM; Transition probability geostatistical simulation, T-PROGS; Multiple point simulation, MPS) a comparison test at different scales was performed for a well-exposed aquifer analogue. In the analysed volume (approximately 30,000?m³) four operative hydrofacies have been recognised: very fine sand and silt, sand, gravelly sand and open framework gravel. Several equiprobable realizations were computed with SISIM, MPS and T-PROGS for a test volume of approximately 400?m³ and for the entire volume, and the different outcomes were compared with visual inspection and connectivity analysis of the very or poorly permeable structures. The comparison of the different simulations shows that the geological model is best reproduced when the simulations are realised separately for each highest rank depositional element and subsequently merged. Moreover, the three methods yield different images of the volume; in particular MPS is efficient in mapping the geometries of the most represented hydrofacies, whereas SISIM and T-PROGS can account for the distribution of the less represented facies.     

Early Berriasian ammonites from Shal, Talesh region (NW Alborz Mountains, Iran)

An early Berriasian (Berriasella jacobi Zone) ammonite fauna is described for the first time from the Alborz Mountains in northwest Iran. It has been collected from a section located near the village of Shal (Talesh region); in addition to rare phylloceratids, lytoceratids and Neolissoceras, the majority of ammonites belong to the neocomitid subfamily Berriasellinae. With the exception of a new genus and species, Taleshites fuersichi, these taxa are common in European and North African Tethyan successions. Associated calpionellids confirm the early Berriasian age of the ammonite-bearing levels.     

Vesta's mineralogical composition as revealed by the visible and infrared spectrometer on Dawn

The Dawn spacecraft mission has provided extensive new and detailed data on Vesta that confirm and strengthen the Vesta–howardite–eucrite–diogenite (HED) meteorite link and the concept that Vesta is differentiated, as derived from earlier telescopic observations. Here, we present results derived by newly calibrated spectra of Vesta. The comparison between data from the Dawn imaging spectrometer—VIR—and the different class of HED meteorites shows that average spectrum of Vesta resembles howardite spectra. Nevertheless, the Vesta spectra at high spatial resolution reveal variations in the distribution of HED‐like mineralogies on the asteroid. The data have been used to derive HED distribution on Vesta, reported in Ammannito et al. (2013), and to compute the average Vestan spectra of the different HED lithologies, reported here. The spectra indicate that, not only are all the different HED lithologies present on Vesta, but also carbonaceous chondritic material, which constitutes the most abundant inclusion type found in howardites, is widespread. However, the hydration feature used to identify carbonaceous chondrite material varies significantly on Vesta, revealing different band shapes. The characteristic of these hydration features cannot be explained solely by infalling of carbonaceous chondrite meteorites and other possible origins must be considered. The relative proportion of HEDs on Vesta's surface is computed, and results show that most of the vestan surface is compatible with eucrite‐rich howardites and/or cumulate or polymict eucrites. A very small percentage of surface is covered by diogenite, and basaltic eucrite terrains are relatively few compared with the abundance of basaltic eucrites in the HED suite. The largest abundance of diogenitic material is found in the Rheasilvia region, a deep basin, where it clearly occurs below a basaltic upper crust. However, diogenite is also found elsewhere; although the depth to diogenite is consistent with one magma ocean model, its lateral extent is not well constrained.     

High-pressure X-ray study of LiCrSi2O6 clinopyroxene and the general compressibility trends for Li-clinopyroxenes

High-pressure single-crystal X-ray diffraction measurements of synthetic LiCrSi₂O₆ clinopyroxene (with space group P2₁/c) were performed in a diamond-anvil cell up to 7.970 GPa. No phase transition has been observed within the pressure range investigated, but the elastic behavior at lower pressures (up to ~2.5 GPa) is affected by an anomalous softening due to the proximity of the phase transition to the HT-C2/c phase at 330 K and at ambient pressure. A third-order Birch–Murnaghan equation of state fitted to the compression data above 2.5 GPa yields a bulk modulus K _T0 = 93(2) GPa and its first derivative K′ = 8.8(6). The structural data measured up to 7.970 GPa confirm that the space group P2₁/c is maintained throughout the whole pressure range investigated. The atomic parameters, obtained from the integrated diffraction intensities, suggest that the Li coordination polyhedron changes its coordination number from 5 to 6 at 6–7 GPa by means of the approach of the bridging O atom, related to the increased kinking of the B tetrahedral chain. Furthermore, at higher pressures, the structural evolution of LiCrSi₂O₆ provides evidence in the variation of kinking angles and bond lengths of a potential phase transition above 8 GPa to the HP-C2/c space group. A comparison of the Li-clinopyroxenes (M1 = Cr, Al, Sc, Ga, Mg + Fe) previously investigated and our sample shows that their elastic behavior and structural mechanisms of compression are analogous.     

Plio-Quaternary changes of the normal fault architecture in the Central Apennines (Italy)

Abstract

The definition of the active fault geometry and kinematics in young evolving orogens may be difficult owing to changes in the structural architecture which may occur with a frequence of few hundred thousand years. Cases from the central Apennines well illustrate this problem. The Avezzano-Bussi and Vallelonga-Salto Valley fault systems (65 and 85 km long, respectively) show clear evidence of Pliocene-early Pleistocene activity and have been responsible for the formation of intermontane basins. Available geological data, however, indicate that only minor segments (the Tre Monti and Trasacco faults, both 7 km long) of the mentioned faults have to be considered active during the late Pleistocene-Holocene, as faults accommodating minor deformations inside an intermontane basin. The L'Aquila fault system underwent significant geometrical and kinematic modifications during the Quaternary, with the reactivation of minor portions of parallel normal faults to draw a new system of en-echelon normal-oblique left-lateral faults. The Laga Mts. fault experienced an along-fault activity migration. The portion of the fault which was active earlier during the Quaternary shows a significant decrease or end of the activity while a portion previously not active displays impressive evidence of late Pleistocene-Holocene displacements. Structural changes in the intermontane basins bounded by the Colfiorito fault system also indicate that the intensity of the tectonic activity decreased during the Quaternary. Not defining the structural evolution in the above mentioned cases would imply wrong conclusions for both the fault geometry and kinematics which may be delivered for seismotectonics and seismic hazard assessment. This typically leads to overestimate the fault length and the expected magnitude or to the increase in the number of seismogenic sources affecting an area. Finally, the definition of the structural evolution permits to select between different geometrical options in terms of active faulting framework (e.g. a system of parallel normal faults vs. a system of en-echelon normal oblique faults as in the case of the L'Aquila fault system) related to different geometries at depth (detachment normal fault vs. high-angle oblique fault). © 2001 Éditions scientifiques et médicales Elsevier SAS