Estimation of southern resident killer whale exposure to exhaust emissions from whale-watching vessels and potential adverse health effects and toxicity thresholds

Southern resident killer whales in British Columbia and Washington are exposed to heavy vessel traffic. This study investigates their exposure to exhaust gases from whale-watching vessels by using a simple dispersion model incorporating data on whale and vessel behavior, atmospheric conditions, and output of airborne pollutants from the whale-watching fleet based on emissions data from regulatory agencies.Our findings suggest that current whale-watching guidelines are usually effective in limiting pollutant exposure to levels at or just below those at which measurable adverse health effects would be expected in killer whales. However, safe pollutant levels are exceeded under worst-case conditions and certain average-case conditions. To reduce killer whale exposure to exhaust we recommend: vessels position on the downwind side of whales, a maximum of 20 whale-watching vessels should be within 800 m at any given time, viewing periods should be limited, and current whale-watch guidelines and laws should be enforced.     

CO<Subscript>2</Subscript>-driven large mafic explosive eruptions: the Pozzolane Rosse case study from the Colli Albani Volcanic District (Italy)

Generally, the intensity and magnitude of explosive volcanic activity increase in parallel with SiO₂ content. Pyroclastic-flow-forming eruptions in the Colli Albani ultrapotassic volcanic district (Italy) represent the most striking exception on a global scale, with volumes on the order of tens of cubic kilometres and K-foiditic compositions (SiO₂ even <42 wt.%). Here, we reconstruct the pre-eruptive scenario and event dynamics of the ~456 ka Pozzolane Rosse (PR) eruption, the largest mafic explosive event of the Colli Albani district. In particular, we focus on the driving mechanisms for the unusually explosive eruption of a low-viscosity, mafic magma. Geologic, petrographic and geochemical data with mass balance calculations, supported by experimental data for Colli Albani magma compositions, provide evidence for significant ingestion of carbonate wall rocks by the Pozzolane Rosse K-foiditic magma. Moreover, the scattered occurrence of cored bombs in Pozzolane Rosse pyroclastic-flow deposits records carbonate entrainment even at the eruptive time scale, as also tested quantitatively by thermal modelling of magma–carbonate interaction and carbonate assimilation experiments. We suggest that the addition of free CO₂ from decarbonation of country rocks was the major factor controlling magma explosivity. High CO₂ activity in the volatile component, coupled with magma depressurisation, produced extensive leucite crystallisation at short time scales, resulting in a dramatic increase in magma viscosity and volatile pressurisation, which was manifested a change of eruptive dynamics from early effusion to the Pozzolane Rosse's highly explosive eruption climax.     

Evaluation of site effects in the Aterno river valley (Central Italy) from aftershocks of the 2009 L��Aquila earthquake

A temporary network of 33 seismic stations was deployed in the area struck by the 6th April 2009, Mw 6.1 (Scognamiglio et?al. in Seism Res Lett 6/81, 2010), L??Aquila earthquake (central Italy), with the aim to investigate the site amplification within the Aterno river Valley. The seismograms of 18 earthquakes recorded by 14 of the 33 stations were used to evaluate the average horizontal to vertical spectral ratio (HVSR) for each site and the standard horizontal spectral ratio (SSR) between a site and a reference station. The obtained results have been compared to the geological and geophysical information in order to explain the resonance frequencies and the amplification levels with respect to surface geology of the valley. The results indicate that there is no uniform pattern of amplification, because of the complex geologic setting, as the thickness and degree of cementation of the deposits is highly variable.     

Biota: sediment partitioning of aluminium smelter related PAHs and pulp mill related diterpenes by intertidal clams at Kitimat, British Columbia

The question of polycyclic aromatic hydrocarbon (PAH) bioavailability and its relationship to specific PAH sources with different PAH binding characteristics is an important one, because bioavailability drives PAH accumulation in biota and ultimately the biochemical responses to the PAH contaminants. The industrial harbour at Kitimat (British Columbia, Canada) provides an ideal location to study the bioavailability and bioaccumulation of sediment hydrocarbons to low trophic level biota. Samples of soft shell clams (Mya arenaria) and intertidal sediment collected from multiple sites over six years at various distances from an aluminium smelter and a pulp and paper mill were analysed for 106 PAHs, plant diterpenes and other aromatic fraction hydrocarbons. Interpretation using PAH source ratios and multivariate data analysis reveals six principal hydrocarbon sources: PAHs in coke, pitch and emissions from anode combustion from the aluminium smelter, vascular plant terpenes and aromatised terpenes from the pulp and paper mill, petroleum PAHs from shipping and other anthropogenic activities and PAHs from natural plant detritus. Harbour sediments predominantly contain either pitch or pyrogenic PAHs from the smelter, while clams predominantly contain plant derived PAHs and diterpenes from the adjacent pulp mill. PAHs from the smelter have low bioavailability to clams (Biota-Sediment Accumulation Factors; BSAFs <1 for pitch and coke; <10 for anode combustion, decreasing to ∼0.1 for the mass 300 and 302 PAHs), possibly due to binding to pitch or soot carbon matrices. Decreases in PAH isomer ratios between sediments and clams likely reflect a combination of variation in uptake kinetics of petroleum PAHs and compound specific metabolism, with the importance of petroleum PAHs decreasing with increasing molecular weight. Plant derived compounds exhibit little natural bioaccumulation at reference sites, but unsaturated and aromatised diterpenes released from resins by industrial pulping processes are readily accumulated by the clams (BSAFs >500). Thus while most of the smelter associated PAHs in sediments may not be bioavailable to benthic organisms, the plant terpenes (including retene, totarol, ferruginol, manool, dehydroabietane and other plant terpenes that form the chemical defence mechanism of conifers) released by pulp mills are bioavailable and possess demonstrated toxic properties. The large scale release of plant terpenes by some of the many pulp mills located in British Columbia and elsewhere represents a largely undocumented risk to aquatic biota.     

Extrusion vs. accretion at the frictional–viscous décollement transition in experimental thrust wedges: the role of convergence velocity

In many cases, thrust wedges accreted at shallow crustal levels show an across‐strike rheological variability along the basal décollement, notably from brittle to ductile behaviour. In this paper, we illustrate the results of sandbox analogue modelling research devoted to studying the influence of convergence velocity on wedge architecture when laterally juxtaposed frictional and viscous materials occur along the basal décollement of accreting thrust wedges. Our results show that slow convergence favours a near symmetrical distribution of thrust vergence within wedge sectors accreted above viscous décollement material, whereas fast convergence favours vergence asymmetry. In particular, at fast convergence rates the hinterlandward extrusion of viscous décollement material at the toe of the frictional wedge is favoured and contributed to accommodate a significant amount of the total contraction. Terra Nova, 18, 241–247, 2006     

The Cosmic Foreground Explorer (COFE): A balloon-borne microwave polarimeter to characterize polarized foregrounds

The COsmic Foreground Explorer (COFE) is a balloon-borne microwave polarimeter designed to measure the low-frequency and low-ℓ characteristics of dominant diffuse polarized foregrounds. Short duration balloon flights from the Northern and Southern Hemispheres will allow the telescope to cover up to 80% of the sky with an expected sensitivity per pixel better than 100 μK/deg² from 10 GHz to 20 GHz. This is an important effort toward characterizing the polarized foregrounds for future CMB experiments, in particular the ones that aim to detect primordial gravity wave signatures in the CMB polarization angular power spectrum.     

Fault‐bend folding as an end‐member solution of (double‐edge) fault‐propagation folding

Fault‐bend folding is the most commonly used kinematic mechanism to interpret the architecture and evolution of thrust‐related anticlines in thrust wedges. However, its basic requirement of an instantaneous propagation of the entire fault before hangingwall deformation, limits its kinematic effectiveness. To overcome this limitation, we used the interdependence between fold shape and fault slip vs. propagation rate (S/P ratio) implemented in double‐edge fault‐propagation folding. We show that very small S/P values produce fault‐propagation anticlines that, when transported forelandward along an upper décollement layer, closely resemble fault‐bend anticlines. Accordingly, if small geometric discrepancies between the two solutions are accepted, transported double‐edge fault‐propagation provides an effective kinematic alternative to fault‐bend folding. Even at very low S/P values, it in fact predicts a fast but finite propagation rate of the fault. We thus propose that double‐edge fault‐propagation folding provides a broadly applicable model of fault‐related folding that includes fault‐bend folding as an end‐member kinematic solution. Terra Nova, 18, 270–275, 2006     

Regional variations of higher Rayleigh-mode phase velocities: a spatial-filtering method

Summary. Application of both spatial filtering and multiple-frequency filtering techniques allows one to isolate a higher-mode surface wave and to find the regional variation of its dispersion. The method is applied to four sets of long-period records across the United States for intermediate earthquakes located in the New Hebrides. The first and second higher Rayleigh modes show lower phase velocities in the western part of the States than in the eastern part. Furthermore, an oceanic phase-velocity curve is determined between 50 and 130 s for the first higher Rayleigh mode on the full path across the Pacific Ocean.