An ESA NEOCC Effort to Eliminate High Palermo Scale Virtual Impactors

In this work we summarize the initial results of a targeted effort of the ESA NEO Coordination Centre to obtain additional observational data in order to eliminate or reduce the impact probability estimate of a subset of the known near-Earth objects representing the highest fraction of the total known impact risk, as measured by the Palermo Scale.     

Options to overcome the barriers to pricing European agricultural emissions

Although agriculture could contribute substantially to European emission reductions, its mitigation potential lies untapped and dormant. Market-based instruments could be pivotal in incentivizing cost-effective abatement. However, sector specificities in transaction costs, leakage risks and distributional impacts impede its implementation. The significance of such barriers critically hinges on the dimensions of policy design. This article synthesizes the work on emissions pricing in agriculture together with the literature on the design of market-based instruments. To structure the discussion, an options space is suggested to map policy options, focusing on three key dimensions of policy design. More specifically, it examines the role of policy coverage, instruments and transfers to farmers in overcoming the barriers. First, the results show that a significant proportion of agricultural emissions and mitigation potential could be covered by a policy targeting large farms and few emission sources, thereby reducing transaction costs. Second, whether an instrument is voluntary or mandatory influences distributional outcomes and leakage. Voluntary instruments can mitigate distributional concerns and leakage risks but can lead to subsidy lock-in and carbon price distortion. Third, the impact on transfers resulting from the interaction of the Common Agricultural Policy (CAP) with emissions pricing will play a key role in shaping political feasibility and has so far been underappreciated.

POLICY RELEVANCE

Following the 2015 Paris Agreement, European climate policy is at a crossroads. Achieving cost-effectively the 2030 and 2050 European targets requires all sectors to reduce their emissions. Yet, the cornerstone of European climate policy, the European Union Emissions Trading System (EU ETS), covers only about half of European emissions. Major sectors have been so far largely exempted from carbon pricing, in particular transport and agriculture. While transport has been increasingly under the spotlight as a possible candidate for an EU ETS sectoral expansion, policy discussions on pricing agricultural emissions have been virtually absent. This article attempts to fill this gap by investigating options for market-based instruments to reduce agricultural emissions while taking barriers to implementation into account.     

Late Oligocene-early Miocene sedimentary evolution of the foreland basins in the Sicilian mobile belt: the example of the Peloritani area

In the northeastern corner of Sicily (Peloritani Mountains) thin bodies of hercynian crystalline basement, covered by Meso-Cenozoic veneers of sedimentary rocks, represent the highest and innermost Africa-vergent group of thrust units of the Sicilian Belt. The Peloritani tectonic edifice consists of a set of prevalently middle- to high-grade crystalline rocks (so-called Fondachelli Unit, Mandanici Unit and Aspromonte Unit) and thrusts over a thin tectonic wedge made of prevalently Mesozoic to Tertiary sedimentary covers overlying pre-Triassic low-grade metamorphic rocks (Longi-Taormina Unit). The tectonic bodies of the Peloritani thrust system are overlain by thick clastic sequences of late Oligoceneearly Miocene age (the so-called Stilo-Capo d'Orlando Formation). Previous work has pointed out the 'molassic' character of these clastic sequences, which postdate the main deformation phase of the Peloritani belt, started during Oligocene time. New structural data on the crystalline and sedimentary terrains, sedimentological analysis of the outcropping Oligo-Miocene foreland clastic deposits and their geometric relationships with the substrate, make it possible to recognize the syn-tectonic character and the timing of deformation of these basin-fill deposits, which are expressed by prograding clastic fans in the active margin of a foreland-foredeep system. This system has progressively been involved in the accretion of the Sicilian Belt and migration during the early Miocene towards the more external areas represented by the Sicilide sector. Seen in this light, three different lithological units have been distinguished to prdvide a framework for a review of the palaeotectonic significance of the overall Oligo-Miocene terrigenous covers of the Peloritani Thrust belt     

Multi-methodological investigation of kunzite, hiddenite, alexandrite, elbaite and topaz, based on laser-induced breakdown spectroscopy and conventional analytical techniques for supporting mineralogical characterization

Gem-quality alexandrite, hiddenite and kunzite, elbaite and topaz minerals were characterized through a multi-methodological investigation based on EMPA-WDS, LA-ICP-MS, and laser-induced breakdown spectroscopy (LIBS). With respect to the others, the latter technique enables a simultaneous multi-elemental composition without any sample preparation and the detection of light elements, such as Li, Be and B. The criteria for the choice of minerals were: (a) the presence of chromophore elements in minor contents and/or as traces; (b) the presence of light lithophile elements (Li, Be and B); (c) different crystal chemistry complexity. The results show that LIBS can be employed in mineralogical studies for the identification and characterization of minerals, and as a fast screening method to determine the chemical composition, including the chromophore and light lithophile elements.     

Drying and dying of a subducted slab: Coupled Li and B isotope variations in Western Anatolia Cenozoic Volcanism

In lavas spanning ~ 10Ma of subduction-related volcanism in Western Anatolia, we observe remarkably similar patterns of δ⁷Li and δ¹¹B variation. In this setting, magmatism records a transition from calc–alkaline to ultrapotassic character, consistent with overall lower mean extents of melting, and a changing mantle source that reflects a fractionating, higher temperature slab input consistent with the gradual cessation of subduction. Subsequent rift-related intraplate magmatism record δ⁷Li signatures within the range observed for MORBs and OIBs, indicating an abrupt transition to a mantle source unmodified by subduction.     

Regional variations of higher Rayleigh-mode phase velocities: a spatial-filtering method

Summary. Application of both spatial filtering and multiple-frequency filtering techniques allows one to isolate a higher-mode surface wave and to find the regional variation of its dispersion. The method is applied to four sets of long-period records across the United States for intermediate earthquakes located in the New Hebrides. The first and second higher Rayleigh modes show lower phase velocities in the western part of the States than in the eastern part. Furthermore, an oceanic phase-velocity curve is determined between 50 and 130 s for the first higher Rayleigh mode on the full path across the Pacific Ocean.     

(Na,Ca)(Ti3+,Mg)Si2O6-clinopyroxenes at high pressure: influence of cation substitution on elastic behavior and phase transition

A compressional study of (Na,Ca)(Ti³⁺,Mg)Si₂O₆-clinopyroxenes was carried out at high pressures between 10⁻⁴ and 10.2 GPa using in situ single-crystal X-ray diffraction, Raman spectroscopy and optical absorption spectroscopy. Compressional discontinuities accompanied by structural changes, in particular, the appearance of two distinct Ti³⁺–Ti³⁺ distances within the octahedral chains at 4.37 GPa, provide evidence for the occurrence of a phase transition in NaTi³⁺Si₂O₆. Equation-of-state parameters are K ₀ = 115.9(7) GPa with K′ = −0.9(3) and K ₀ = 102.7(8) GPa with K′ = 4.08(5) for the low- and high-pressure range, respectively. The transition involves a C2/c–P [`1] \overline{1} symmetry change, which can be confirmed by the occurrence of new modes in Raman spectra. Since no significant discontinuity in the evolution of the unit-cell volume with pressure has been observed, the transition appears to be second-order in character. The influence of the coupled substitution Na⁺Ti³⁺↔Ca²⁺Mg²⁺ on the static compression behavior and the structural stability has been investigated using a sample of the intermediate composition (Na_0.54Ca_0.46)(Mg_0.46Ti_0.54)Si₂O₆. No evidence for a deviation from continuous compression behavior has been found, neither in lattice parameter nor in structural data and the fit of a third-order Birch–Murnaghan equation-of-state to the pressure–volume data yields a bulk modulus of K ₀ = 109.1(5) GPa and K′ = 5.02(13). Raman and polarized absorption spectra have been compared to NaTiSi₂O₆ and reveal major similarities. The main driving force for the phase transition in NaTi³⁺Si₂O₆ is the localization of the Ti³⁺ d-electron and the accompanying distortion, which is suppressed in the (Na,Ca)(Ti³⁺,Mg)Si₂O₆-clinopyroxene.     

Biogenic iron oxyhydroxide formation at mid-ocean ridge hydrothermal vents: Juan de Fuca Ridge

Here we examine Fe speciation within Fe-encrusted biofilms formed during 2-month seafloor incubations of sulfide mineral assemblages at the Main Endeavor Segment of the Juan de Fuca Ridge. The biofilms were distributed heterogeneously across the surface of the incubated sulfide and composed primarily of particles with a twisted stalk morphology resembling those produced by some aerobic Fe-oxidizing microorganisms. Our objectives were to determine the form of biofilm-associated Fe, and identify the sulfide minerals associated with microbial growth. We used micro-focused synchrotron-radiation X-ray fluorescence mapping (μXRF), X-ray absorption spectroscopy (μΕXAFS), and X-ray diffraction (μXRD) in conjunction with focused ion beam (FIB) sectioning, and high resolution transmission electron microscopy (HRTEM). The chemical and mineralogical composition of an Fe-encrusted biofilm was queried at different spatial scales, and the spatial relationship between primary sulfide and secondary oxyhydroxide minerals was resolved. The Fe-encrusted biofilms formed preferentially at pyrrhotite-rich (Fe_1−xS, 0 ? x ? 0.2) regions of the incubated chimney sulfide. At the nanometer spatial scale, particles within the biofilm exhibiting lattice fringing and diffraction patterns consistent with 2-line ferrihydrite were identified infrequently. At the micron spatial scale, Fe μEXAFS spectroscopy and μXRD measurements indicate that the dominant form of biofilm Fe is a short-range ordered Fe oxyhydroxide characterized by pervasive edge-sharing Fe-O₆ octahedral linkages. Double corner-sharing Fe-O₆ linkages, which are common to Fe oxyhydroxide mineral structures of 2-line ferrihydrite, 6-line ferrihydrite, and goethite, were not detected in the biogenic iron oxyhydroxide (BIO). The suspended development of the BIO mineral structure is consistent with Fe(III) hydrolysis and polymerization in the presence of high concentrations of Fe-complexing ligands. We hypothesize that microbiologically produced Fe-complexing ligands may play critical roles in both the delivery of Fe(II) to oxidases, and the limited Fe(III) oxyhydroxide crystallinity observed within the biofilm. Our research provides insight into the structure and formation of naturally occurring, microbiologically produced Fe oxyhydroxide minerals in the deep-sea. We describe the initiation of microbial seafloor weathering, and the morphological and mineralogical signals that result from that process. Our observations provide a starting point from which progressively older and more extensively weathered seafloor sulfide minerals may be examined, with the ultimate goal of improved interpretation of ancient microbial processes and associated biological signatures.     

A site effect study in the Verchiano valley during the 1997 Umbria-Marche (Central Italy) earthquakes

Strong site effects were observed during the two M _W 5.7 and M _W 6.0 main shocks of the Colfiorito seismic crisis which occured on September 26, 1997 in Umbria-Marche (Central Italy).The most obvious indications of these effects are the dramatic differences in damage shown by buildings of similar construction in neighboring villages.Such observations were specifically made in the Verchiano valley in the fault area, 15 km south of Colfiorito where the Verchiano village and the Colle and Camino hamlets were heavily damaged (MCS intensity IX-X) since the first main shock of 1997/09/26,while in contrast, the Curasci village located 2 km eastwards remains almost intact.In order to study the anomalous ground motion amplifications in this area, an array of 11, 3-components seismo- and accelero-meters was set up during the 1997/10/20-24 period, extending from the western side of the valley, up to the top of Mount San Salvatore, going accross the Colle and Curasci hamlets.During the experiment, 67 aftershocks enlightened the valley from the Colfiorito (10 km north) and the Sellano (6 km south) active swarms.Seismic refraction experiments were conducted at the same time in the 500 m wide, 1500 m long Verchiano valley in order to determine the thickness and main characteristics of the alluvial infilling.The main results are: (i) compared to the valley side ground motion, and for all the events, recordings in the central part of the valley (piana di Verchiano) show relative amplification of 10 with a clear lengthening of the seismogram duration by a factor of 2 – (ii) broad band relative amplification of 6–8 is also clearly identified at the top of the Mount San Salvatore overhanging the valley – (iii) any of the site effect measurements done explains by itself the strongly contrasted damage observed at Colle and Curasci: i.e. the modification of the near-field radiation pattern by interaction with the free heterogeneous surface may have induced local shadow zones that saved Curasci.