On multicomponent gas diffusion and coupling concepts for porous media and free flow: a benchmark study

Computational Geosciences - Multicomponent gas transport in porous media and at the interface between porous media and free flow occurs in a wide range of technical and environmental systems....     

Multitemporal terrestrial laser scanning point clouds for thaw subsidence observation at Arctic permafrost monitoring sites

This paper investigates different methods for quantifying thaw subsidence using terrestrial laser scanning (TLS) point clouds. Thaw subsidence is a slow (millimetre to centimetre per year) vertical displacement of the ground surface common in ice-rich permafrost-underlain landscapes. It is difficult to quantify thaw subsidence in tundra areas as they often lack stable reference frames. Also, there is no solid ground surface to serve as a basis for elevation measurements, due to a continuous moss–lichen cover. We investigate how an expert-driven method improves the accuracy of benchmark measurements at discrete locations within two sites using multitemporal TLS data of a 1-year period. Our method aggregates multiple experts’ determination of the ground surface in 3D point clouds, collected in a web-based tool. We then compare this to the performance of a fully automated ground surface determination method. Lastly, we quantify ground surface displacement by directly computing multitemporal point cloud distances, thereby extending thaw subsidence observation to an area-based assessment. Using the expert-driven quantification as reference, we validate the other methods, including in-situ benchmark measurements from a conventional field survey. This study demonstrates that quantifying the ground surface using 3D point clouds is more accurate than the field survey method. The expert-driven method achieves an accuracy of 0.1 ± 0.1 cm. Compared to this, in-situ benchmark measurements by single surveyors yield an accuracy of 0.4 ± 1.5 cm. This difference between the two methods is important, considering an observed displacement of 1.4 cm at the sites. Thaw subsidence quantification with the fully automatic benchmark-based method achieves an accuracy of 0.2 ± 0.5 cm and direct point cloud distance computation an accuracy of 0.2 ± 0.9 cm. The range in accuracy is largely influenced by properties of vegetation structure at locations within the sites. The developed methods enable a link of automated quantification and expert judgement for transparent long-term monitoring of permafrost subsidence. © 2020 The Authors. Earth Surface Processes and Landforms published by John Wiley & Sons Ltd     

Holocene sedimentation in the Strait of Otranto between the Adriatic and Ionian Seas (Mediterranean)

An extensive radiograph study of 24 undisturbed, up to 206-cm long box and gravity cores from the western part of the Strait of Otranto revealed a great variety of primary bedding structures and secondary burrowing features.     

Calcium Isotopes (δ44/40Ca) in MPI-DING Reference Glasses, USGS Rock Powders and Various Rocks: Evidence for Ca Isotope Fractionation in Terrestrial Silicates

We report δ^44/40Ca_{(SRM 915a)} values for eight fused MPI‐DING glasses and the respective original powders, six USGS igneous rock reference materials, the U‐Th disequilibria reference material TML, IAEA‐CO1 (Carrara marble) and several igneous rocks (komatiites and carbonatites). Sample selection was guided by three considerations: (1) to address the need for information values on reference materials that are widely available in support of interlaboratory comparison studies; (2) support the development of in situ laser ablation and ion microprobe techniques, which require isotopically homogenous reference samples for ablation; and (3) provide Ca isotope values on a wider range of igneous and metamorphic rock types than is currently available in the scientific literature. Calcium isotope ratios were measured by thermal ionisation mass spectrometry in two laboratories (IFM‐GEOMAR and Saskatchewan Isotope Laboratory) using ⁴³Ca/⁴⁸Ca‐ and ⁴²Ca/⁴³Ca‐double spike techniques and reported relative to the calcium carbonate reference material NIST SRM 915a. The measurement uncertainty in both laboratories was better than 0.2‰ at the 95% confidence level. The impact of different preparation methods on the δ^44/40Ca_{(SRM 915a)} values was found to be negligible. Except for ML3‐B, the original powders and the respective MPI‐DING glasses showed identical δ^44/40Ca_{(SRM 915a)} values; therefore, possible variations in the Ca isotope compositions resulting from the fusion process are excluded. Individual analyses of different glass fragments indicated that the glasses are well homogenised on the mm scale with respect to Ca. The range of δ^44/40Ca_{(SRM 915a)} values in the igneous rocks studied was larger than previously observed, mostly owing to the inclusion of ultramafic rocks from ophiolite sections. In particular, the dunite DTS‐1 (1.49 ± 0.06‰) and the peridotite PCC‐1 (1.14 ± 0.07‰) are enriched in ⁴⁴Ca relative to volcanic rocks (0.8 ± 0.1‰). The Carrara marble (1.32 ± 0.06‰) was also found to be enriched in ⁴⁴Ca relative to the values of assumed precursor carbonates (< 0.8‰). These findings suggest that the isotopes of Ca are susceptible to fractionation at high temperatures by, as yet, unidentified igneous and metamorphic processes.     

River discharge reduces reef coral diversity in Palau

Coral community structure is often governed by a suite of processes that are becoming increasingly influenced by land-use changes and related terrestrial discharges. We studied sites along a watershed gradient to examine both the physical environment and the associated biological communities. Transplanted corals showed no differences in growth rates and mortality along the watershed gradient. However, coral cover, coral richness, and coral colony density increased with increasing distance from the mouth of the bay. There was a negative relationship between coral cover and mean suspended solids concentration. Negative relationships were also found between terrigenous sedimentation rates and the richness of adult and juvenile corals. These results have major implications not only for Pacific islands but for all countries with reef systems downstream of rivers. Land development very often leads to increases in river runoff and suspended solids concentrations that reduce coral cover and coral diversity on adjacent reefs.     

Future makers or future takers? A scenario analysis of climate change and the Great Barrier Reef

The extent to which nations and regions can actively shape the future or must passively respond to global forces is a topic of relevance to current discourses on climate change. In Australia, climate change has been identified as the greatest threat to the ecological resilience of the Great Barrier Reef, but is exacerbated by regional and local pressures. We undertook a scenario analysis to explore how two key uncertainties may influence these threats and their impact on the Great Barrier Reef and adjacent catchments in 2100: whether (1) global development and (2) Australian development is defined and pursued primarily in terms of economic growth or broader concepts of human well-being and environmental sustainability, and in turn, how climate change is managed and mitigated. We compared the implications of four scenarios for marine and terrestrial ecosystem services and human well-being. The results suggest that while regional actions can partially offset global inaction on climate change until about mid-century, there are probable threshold levels for marine ecosystems, beyond which the Great Barrier Reef will become a fundamentally different system by 2100 if climate change is not curtailed. Management that can respond to pressures at both global and regional scales will be needed to maintain the full range of ecosystem services. Modest improvements in human well-being appear possible even while ecosystem services decline, but only where regional management is strong. The future of the region depends largely on whether national and regional decision-makers choose to be active future ‘makers’ or passive future ‘takers’ in responding to global drivers of change. We conclude by discussing potential avenues for using these scenarios further with the Great Barrier Reef region's stakeholders.     

Atmospheric Chemistry in Giant Planets, Brown Dwarfs, and Low-Mass Dwarf Stars: I. Carbon, Nitrogen, and Oxygen

The chemical species containing carbon, nitrogen, and oxygen in atmospheres of giant planets, brown dwarfs (T and L dwarfs), and low-mass stars (M dwarfs) are identified as part of a comprehensive set of thermochemical equilibrium and kinetic calculations for all elements. The calculations cover a wide temperature and pressure range in the upper portions of giant planetary and T-, L-, and M-dwarf atmospheres. Emphasis is placed on the major gases CH₄, CO, NH₃, N₂, and H₂O but other less abundant gases are included. The results presented are independent of particular model atmospheres, and can be used to constrain model atmosphere temperatures and pressures from observations of different gases. The influence of metallicity on the speciation of these key elements under pressure-temperature (P-T) conditions relevant to low-mass object atmospheres is discussed. The results of the thermochemical equilibrium computations indicate that several compounds may be useful to establish temperature or pressure scales for giant planet, brown dwarf, or dwarf star atmospheres. We find that ethane and methanol abundance are useful temperature probes in giant planets and methane dwarfs such as Gl 229B, and that CO₂ can serve as a temperature probe in more massive objects. Imidogen (NH) abundances are a unique pressure-independent temperature probe for all objects. Total pressure probes for warmer brown dwarfs and M dwarfs are HCN, HCNO, and CH₂O. No temperature-independent probes for the total pressure in giant planets or T-dwarf atmospheres are identified among the more abundant C, N, and O bearing gases investigated here.