Chemical mass balance of calcrete genesis on the Toledo granite (Spain)

The chemical mass balance of calcrete genesis is studied on a typical sequence developed in granite, in the Toledo mountains, Central Spain.

Field evidence and petrographic observations indicate that the texture and the bulk volume of the parent rock are strictly preserved all along the studied calcrete profile.

Microscopic observations indicate that the calcitization process starts within the saprolite, superimposed on the usual mechanisms of granite weathering: the fresh rock is first weathered to secondary clays, mainly smectites, which are then pseudomorphically replaced by calcite. Based on this evidence, chemical mass transfers are calculated, assuming iso-volume transformation from the parent rock to the calcrete.

The mass balance results show the increasing loss of matter due to weathering of the primary phases, from the saprolite towards the calcrete layers higher in the sequence. Zr, Ti or Th, which are classically considered as immobile during weathering, are also depleted along the profile, especially in the calcrete layer. This results from the prevailing highly alkaline conditions, which could account for the simultaneous precipitation of CaCO₃ and silicate dissolution.

The calculated budget suggests that the elements exported from the weathering profile are provided dominantly by the weathering of plagioclase and biotite. We calculate that 8–42% of the original Ca remains in granitic relics, while only 15% of the authigenic Ca released by weathering is reincorporated in the calcite. This suggests that 373 kg/m² of calcium (i.e., three times the original amount) is imported into the calcrete from allochtonous sources, probably due to aeolian transport from distant limestone formations.     

Towards fully data driven ground-motion prediction models for Europe

We have used the Artificial Neural Network method (ANN) for the derivation of physically sound, easy-to-handle, predictive ground-motion models from a subset of the Reference database for Seismic ground-motion prediction in Europe (RESORCE). Only shallow earthquakes (depth smaller than 25 km) and recordings corresponding to stations with measured $V_{s30}$ properties have been selected. Five input parameters were selected: the moment magnitude $M_{W}$ , the Joyner–Boore distance $R_{JB}$ , the focal mechanism, the hypocentral depth, and the site proxy $V_{S30}$ . A feed-forward ANN type is used, with one 5-neuron hidden layer, and an output layer grouping all the considered ground motion parameters, i.e., peak ground acceleration (PGA), peak ground velocity (PGV) and 5 %-damped pseudo-spectral acceleration (PSA) at 62 periods from 0.01 to 4 s. A procedure similar to the random-effects approach was developed to provide between and within event standard deviations. The total standard deviation ( $\sigma $ ) varies between 0.298 and 0.378 (log $_{10}$ unit) depending on the period, with between-event and within-event variabilities in the range 0.149–0.190 and 0.258–0.327, respectively. Those values prove comparable to those of conventional GMPEs. Despite the absence of any a priori assumption on the functional dependence, our results exhibit a number of physically sound features: magnitude scaling of the distance dependency, near-fault saturation distance increasing with magnitude, amplification on soft soils and even indications for nonlinear effects in softer soils.