Daily, weekly and seasonal relationships among VOCs, NOx x and O3 in a semi-urban area near Barcelona

Daily, weekly, and seasonal patterns of O₃, NOx _x and VOCs and their relationship to meteorological conditions were studied in a semi-urban site near Barcelona by means of five-day long campaigns that included weekend and labor days in December, March, June, and October. The plant protection thresholds for ozone and NO₂ were exceeded, respectively, on all the studied days in summer and on all the studied days. Ozone formation was predominantly local and relied on photochemical processes with VOCs playing a controlling role. Formaldehyde, acetaldehyde, methanol, toluene, isoprene, and acetone (in this order) presented the highest O₃ formation potential during the studied periods. These results highlight the important role in O₃ formation played by VOC species such as acetaldehyde, methanol, and acetone, that all have a significant biogenic component. Thus, these VOCs must be taken into account in the discussion of any ozone abatement strategy.     

Water Resources Management Issues in the Danube River Basin District—Examples from Serbia

Water Resources - This paper aims to present water resources management problems in Serbia and recommend possible solutions. Key issues involve water quality and water quantity. Water quality is...     

Age,stratigraphy, sedimentology and tectonic setting of the Sigri Pyroclastic Formation and its fossil forests,Early Miocene,Lesbos, Greece

The Petrified Forest of Lesbos comprises silicified tree fossils at multiple stratigraphic levels within the Lower Miocene Sigri Pyroclastic Formation. Our objective was to understand the interplay of tectonic setting, structural evolution, volcanological setting and basin evolution in the preservation of this remarkable natural monument. Sections were logged for lithology, sedimentary structures and hydrothermal alteration. Orientations of fallen fossil trees were measured. Samples were taken for mineralogical and geochemical analysis. ⁴⁰Ar/³⁹Ar dating was carried out on mineral separates from four samples. Widespread andesite‐dacite domes, the Eressos Formation, intrude and overlie metamorphic basement and are overlain by the Sigri Pyroclastic Formation, which comprises several hundreds of metres of pyroclastic flow tuffs (unwelded ignimbrites) interbedded with fluvial conglomerate and volcaniclastic sandstone. The Sigri Pyroclastic Formation ranges in age from 21.5 to 22 Ma, where it overlies the lacustrine Gavathas Formation, to younger than 18.4 Ma. Tuffs and fluvial conglomerates in the Sigri Pyroclastic Formation coarsen eastwards, and petrified trees and soil horizons occur throughout the Formation. The recurrence of pyroclastic flows was approximately one every 20 ka, so destructive flows were relatively infrequent, allowing the development of climax vegetation between most eruptions. Conglomerate‐filled channels show that rivers flowed westwards. Tree fall directions indicate NW to N movement of pyroclastic flows, implying a source near the younger Mesotopos–Tavari caldera to the south. The basin, which formed in a NNE‐trending dextral strike‐slip regime, provided some topographic steering. Following the Sigri Pyroclastic Formation at ca. 18 Ma, there was a rapid increase in the pace of volcanic activity, with the eruption of thick lava sequences and welded ignimbrites, and intrusion of dykes and laccoliths in SW Lesbos. Rapid burial by permeable tuffs, silica from alteration of volcanic ash, and later hydrothermal circulation all contributed to the preservation of the petrified trees.     

Spatial analysis of stream power using GIS: SLk anomaly maps

The stream length‐gradient index (SL) shows the variation in stream power along river reaches. This index is very sensitive to changes in channel slope, thus allowing the evaluation of recent tectonic activity and/or rock resistance. Nevertheless, the comparison of SL values from rivers of different length is biased due to the manner in which the index is formulated, thus making correlations of SL anomalies along different rivers difficult. Therefore, when undertaking a comparison of SL values of rivers of different lengths, a normalization factor must be used. The graded river gradient (K) has already been used in some studies to normalize the SL index. In this work, we explore the relationships between the graded river gradient (K), the SL index and the stream power, proposing the use of a re‐named SLk index, which enables the comparison of variable‐length rivers, as well as the drawing of SLk anomaly maps. We present here a GIS‐based procedure to generate SLk maps and to identify SLk anomalies. In order to verify the advantages of this methodology, we compared an SLk map of the NE border of the Granada basin with both simple river profile–knickpoint identification and with an SL map. The results show that the SLk map supplies good results with defined anomalies and suitably reflects the main tectonic and lithological features of the study area. Copyright © 2008 John Wiley & Sons, Ltd.     

Lunar physical librations due to rotation of the ecliptic

Irregularities of the Moon's rotation due to rotation of the ecliptical plane were derived for all three libration components. Optimum values of coefficients in the linearized equations of motion, which strongly affect the magnitude of the resulting terms, were determined by comparing the rotation relative to the moving and to the fixed reference ecliptical system. Ecliptic rotation causes monthly oscillations of the Moon's polar axis of 6.1 and deviations of 0.3 from uniform rotation along that axis with a period of 18.6 yr.     

Accumulation of potentially toxic elements in sediments in Budi Lagoon,Araucania Region,Chile

The concentrations of Cd, Cu, Mn, Ni, Pb, Fe and Zn were determined in superficial sediments extracted from nine zones of Budi Lagoon, located in the Araucanía Region (Chile). The concentrations of these metals were determined by flame atomic absorption spectroscopy and the method was validated using certified reference material (marine sediment). The concentration ranges found for the trace elements were: Pb < 0.5; Cd < 0.2–3.9; Cu 21.8–61.9; Ni 31.2–59.4; Zn 54.5–94.8 mgkg^?1 (dry weight). The elements that registered the highest concentrations were Mn 285.4–989.8 mgkg^?1 and Fe 4.8–10.6 %. The lagoon cluster analysis of the stations was divided into three groups (Temo station with high Cu and low Mn concentrations, Bolleco, Comué, Allipén and Deume 3 stations presented highest Cd concentration, and another group Botapulli, Río Budi, Deume 2 and Deume 1 stations presented low levels of Cd). The textural characteristics of the sediment were determined (gravel, sand and mud) and the results were correlated with the concentrations of the metals in the various study zones. The sediments of Budi Lagoon presented high levels of Fe and Mn, which are of natural origin and exceed the maximum values recorded by many authors. With respect to the recorded concentrations for Cd, Cu, Ni and Zn, are within the ranges published by other authors in similar works. The Pb element was not detected. The results were subjected to statistical analysis to evaluate the correlations between the content of the elements and obtain the site of sediment.     

Long-Term Profiles of Wind and Weibull Distribution Parameters up to 600 m in a Rural Coastal and an Inland Suburban Area

An investigation of the long-term variability of wind profiles for wind energy applications is presented. The observations consists of wind measurements obtained from a ground-based wind lidar at heights between 100 and 600 m, in combination with measurements from tall meteorological towers at a flat rural coastal site in western Denmark and at an inland suburban area near Hamburg in Germany. Simulations with the weather research and forecasting numerical model were carried out in both forecast and analysis configurations. The scatter between measured and modelled wind speeds expressed by the root-mean-square error was about 10 % lower for the analysis compared to the forecast simulations. At the rural coastal site, the observed mean wind speeds above 60 m were underestimated by both the analysis and forecast model runs. For the inland suburban area, the mean wind speed is overestimated by both types of the simulations below 500 m. When studying the wind-speed variability with the Weibull distribution, the shape parameter was always underestimated by the forecast compared to both analysis simulations and measurements. At the rural coastal site although the measured and modelled Weibull distributions are different their variances are nearly the same. It is suggested to use the shape parameter for climatological mesoscale model evaluation. Based on the new measurements, a parametrization of the shape parameter for practical applications is suggested.     

Satellite Remote Sensing as a Reconnaissance Tool for Assessing Nautical Chart Adequacy and Completeness

National hydrographic offices need a better means of assessing the adequacy of existing nautical charts in order to plan and prioritize future hydrographic surveys. The ability to derive bathymetry from multispectral satellite imagery is a topic that has received considerable attention in scientific literature. However, published studies have not addressed the ability of satellite-derived bathymetry to meet specific hydrographic survey requirements. Specifically, the bathymetry needs to be referenced to a chart datum and statistical uncertainty estimates of the bathymetry should be provided. Ideally, the procedure should be based on readily-available, low-cost software, tools, and data. This paper describes the development and testing of a procedure using publicly-available, multispectral satellite imagery to map and portray shallow-water bathymetry in a GIS environment for three study sites: Northeast United States, Nigeria, and Belize. Landsat imagery and published algorithms were used to derive estimates of the bathymetry in shallow waters, and uncertainty of the satellite-derived bathymetry was then assessed using a Monte Carlo method. Results indicate that the practical procedures developed in this study are suitable for use by national hydrographic offices.     

Fold-Axis Parallel Extension along the Southern Ending of the Quito (Ecuadorian Andes) Fault System: Implications in River Network and Aquifer Geometry

Geotectonics - Extension parallel to fold axis represents a rarely documented tectonic process that occur in different tectonic settings such as large-scale orogenic belts, mountain ranges, and...     

Trends of AOT40 at three sites in the Catalan Pyrenees over the last 16 years

Ozone mixing ratios were monitored at three stations at different altitudes along the Catalan Pyrenees from 1994 to 2009. The AOT40 greatly exceeded the critical level for the protection of forest and semi-natural vegetation set by the UNECE’s CLRTAP and the target value and long-term objective for the protection of vegetation set by the European Directive 2008/50/EC. The AOT40 showed an overall increasing trend over time with a slight decrease during the last 3 years, although longer-term records of ozone levels are required before affirming with certainty a declining or stabilising trend. These results indicate that plant life in the Pyrenean region can be at risk of ozone damage due to the high ozone mixing ratios detected. Nevertheless, more effort is warranted to determine the uptake of ozone by vegetation in this mountainous range. An ozone flux-based index that takes into account the local environmental conditions, plant phenology, and nocturnal uptake of ozone would provide a more accurate assessment of the risk from ozone for the particular vegetation in each area.