Low temperature behaviour of natural saline fluid inclusions in saddle dolomite (Paleozoic,NW Spain)

The origin of many dolomites is still a matter of debate because of many possible chemical and hydrological conditions of formation. Fluid inclusion studies have been applied in order to improve knowledge about paleofluids responsible for the precipitation of dolomite, and used to define temperatures and salinities. The combination of Raman Spectroscopy and microthermometry is tested here to improve the analytical method to identify the main ion species present in individual inclusions. Natural samples of saddle dolomite from the Cambrian Láncara Fm., Cantabrian Mountains (NW Spain), contain zoned crystals with two‐phase aqueous fluid inclusions (liquid‐rich). The most stable phase assemblage in these inclusions at −150 °C consists of ice, hydrohalite and an unknown salt hydrate. The latter melts between −47 and −41 °C, probably representing a eutectic temperature. Subsequently, ice melts in the range of −32.5 to −29 °C and, finally, hydrohalite melts between −9 and −3.5 °C. Salinities can be calculated in the fluid system H₂O–NaCl with addition of another salt, either CaCl₂ or MgCl₂, and result in 7.5–10.6 eq. mass% NaCl and 17.0–21.0 eq. mass% CaCl₂. Dependent on the rate of cooling runs, three different types of metastability may occur, i.e. the absence of hydrohalite, the unknown salt‐hydrate is not formed, and the nucleation of only ice. Salinity calculations from those melting temperatures differ substantially from equilibrium behaviour values. The unknown salt‐hydrate needs to be further specified by comparison to standard solutions. The method gives an opportunity to characterize the major compounds in complex fluid systems active during dolomitization, thus contributing to a better understanding of the ‘dolomite problem’.     

An anthropogenic origin of the “Sirente crater,” Abruzzi,Italy

Abstract— In this paper, we review the recent hypothesis, based mostly on geomorphological features, that a ～130 m‐wide sag pond, surrounded by a saddle‐shaped rim from the Sirente plain (Abruzzi, Italy), is the first‐discovered meteoritic crater of Italy. Sub‐circular depressions (hosting ponds), with geomorphological features and size very similar to those exhibited by the main Sirente sag, are exposed in other neighboring intermountain karstic plains from Abruzzi. We have sampled present‐day soils from these sag ponds and from the Sirente sags (both the main “crater” and some smaller ones, recently interpreted as a crater field) and various Abruzzi paleosols from excavated trenches with an age range encompassing the estimated age of the “Sirente crater.” For all samples, we measured the magnetic susceptibility and determined the Ni and Cr contents of selected specimens. The results show that the magnetic susceptibility values and the geochemical composition are similar for all samples (from Sirente and other Abruzzi sags) and are both significantly different from the values reported for soils contaminated by meteoritic dust. No solid evidence pointing at an impact origin exists, besides the circular shape and rim of the main sag. The available observations and data suggest that the “Sirente crater,” together with analogous large sags in the Abruzzi intermountain plains, have to be attributed to the historical phenomenon of “transumanza” (seasonal migration of sheep and shepherds), a custom that for centuries characterized the basic social‐economical system of the Abruzzi region. Such sags were excavated to provide water for millions of sheep, which spent summers in the Abruzzi karstic high pasture lands, on carbonatic massifs deprived of natural superficial fresh water. Conversely, the distribution of the smaller sags from the Sirente plain correlates with the local pattern of the calcareous bedrock and, together with the characteristics of their internal structure, are best interpreted as natural dolines. In fact, reported radiocarbon ages for the formation of the main sag pond and of the smaller sags differ (significantly) by more than two millennia, thus excluding that they were all contemporaneously formed by a meteoritic impact.     

Sensitivity of PSHA results to ground motion prediction relations and logic-tree weights

Epistemic uncertainty in ground motion prediction relations is recognized as an important factor to be considered in probabilistic seismic hazard analysis (PSHA), together with the aleatory variability that is incorporated directly into the hazard calculations through integration across the log-normal scatter in the ground motion relations. The epistemic uncertainty, which is revealed by the differences in median values of ground motion parameters obtained from relations derived for different regions, is accounted for by the inclusion of two or more ground motion prediction relations in a logic-tree formalism. The sensitivity of the hazard results to the relative weights assigned to the branches of the logic-tree, is explored through hazard analyses for two sites in Europe, in areas of high and moderate seismicity, respectively. The analyses reveal a strong influence of the ground motion models on the results of PSHA, particularly for low annual exceedance frequencies (long return periods) and higher confidence levels. The results also show, however, that as soon as four or more relations are included in the logic-tree, the relative weights, unless strongly biased towards one or two relations, do not significantly affect the hazard. The selection of appropriate prediction relations to include in the analysis, therefore, has a greater impact than the expert judgment applied in assigning relative weights to the branches of the logic-tree.