Paleomagnetic dating of the most recent silicic eruptive activity at Pantelleria (Strait of Sicily)

We report on the paleomagnetism of ten sites in the products of the most recent silicic eruptive cycle of Pantelleria, Strait of Sicily. Previously radiometrically dated at 5–10 ka, our comparison with proxies for geomagnetic field directions allows us to narrow considerably the time window during which these eruptions occurred. The strongly peralkaline composition causes the magmas to have low viscosities, locally resulting in strong agglutination of proximal fall deposits. This allows successful extraction of paleomagnetic directions from the explosive phases of eruptions. One of our sites was located in the Serra della Fastuca fall deposit, produced by the first explosive event of the eruptive cycle. The other nine sites were located in the most recent explosive (pumice fall and agglutinate from Cuddia del Gallo and Cuddia Randazzo) and effusive (Khaggiar lava) products. The (very similar) paleomagnetic directions gathered from eight internally consistent sites were compared to reference geomagnetic field directions of the last 5–10 ka. Directions from Cuddia del Gallo agglutinate and Khaggiar flows translate into 5.9- to 6.2-ka ages, whereas the Fastuca pumices yield a slightly older age of 6.2–6.8 ka. Hence, the most recent silicic eruptive cycle lasted at most a millennium and as little as a few centuries around 6.0 ka. Paleomagnetically inferred ages are in good agreement with published (and calibrated by us) ¹⁴C dates from paleosols/charcoals sampled below the studied volcanic units, whereas K/Ar data are more scattered and yield ∼30% older ages. Our data show that the time elapsed since the most recent silicic eruptions at Pantelleria is comparable to the quiescence period separating the two latest volcanic cycles.     

Sensitivity analysis of CDOM spectral slope in artificial and natural samples: an application in the central eastern Mediterranean Basin

In the past two decades, optical properties of chromophoric dissolved organic matter (CDOM) in marine environments have been extensively studied. Many of these studies report CDOM properties for the offshore environment where this complex mixture of optically active compounds is strongly diluted. Nevertheless, autochthonous and allochthonous sources have been identified and sinks related to photodegradation and bacterial activity have been demonstrated. The calculation of the spectral slope of the CDOM absorption curve has been proven to be useful and is often reported. However, a rigorous uncertainty analysis of the slope calculation is rarely reported. In this paper, we propose a method to evaluate the uncertainty of CDOM spectral slope calculated between 270 and 400 nm, using both naturally sampled and artificial solutions. We use these results to study the ultra-oligotrophic waters of the Mediterranean Sea (central eastern basin), where little is known about CDOM spatial distribution. We show that dilutions of both artificial and natural samples produce a Gaussian distribution of spectral slopes, indicating that consistent values may be determined, with a typical uncertainty of ±0.0004 nm⁻¹ when absorption at 300 nm was greater then 0.1 m⁻¹ (0.1 m pathlength). Comparing the distribution of spectral slopes from central eastern basin samples to a Gaussian distribution, we show differences between measurements that were significantly different. These values allow us to distinguish possible sources (algal derived CDOM), sinks (e.g. photo-bleaching) at different depths. We propose a subdivision of CDOM compounds into refractory and semilabile/refractory pools and evaluate the CDOM spectral slope of algal derived CDOM released at or near deep chlorophyll maximum.     

Hollow bridge-pier properties for response spectrum analysis

The present paper proposes equivalent stiffness and energy dissipation properties of reinforced concrete hollow bridge piers to be used in the context of response spectrum performance based assessment and design. The work is carried out by performing parametric numerical analysis using a 2D fibre model calibrated against experimental results and by varying the longitudinal steel reinforcement ratio, height over width ratio, normalised axial force, level of confinement and concrete class of a rectangular hollow section reinforced with Tempcore B500C steel. The results of the analysis are given in the form of charts and closed form expressions for the yield curvature and moment, ultimate ductility, post yielding stiffness ratio and energy dissipated of the section, and are translated to the member level through the plastic hinge length approach. Likewise, the parameters of a Takeda model derived from the parametric analysis are given for use in nonlinear time history analysis.     

Understanding the statistical properties of the percent model affinity index can improve biomonitoring related decision making

The percent model affinity (PMA) index is used to measure the similarity of two probability profiles representing, for example, an ideal profile (i.e. reference condition) and a monitored profile (i.e. possibly impacted condition). The goal of this work is to study the effects of sample size, evenness, true value of the index and number of classes on the statistical properties of the estimator of the PMA index. We derive and extend previous formulas of the expectation and variance of the estimator for estimated monitored profile and fixed reference profile. Using the obtained extension, we find that the estimator is asymptotically unbiased, converging faster when the profiles differ. When both profiles are estimated, we calculate the expectation using transformation rules for expectation and in addition derive the formula for the estimator’s variance. Since the computation of the probabilities in the variance formula is slow, we study the behavior of the variance with simulation experiments and assess whether it could be approximated with the variance for the fixed reference profile. Finally, we provide a set of recommendations for the users of the PMA index to avoid the most common caveats of the index.     

ESEEM of industrial quartz powders: insights into crystal chemistry of Al defects

A set of raw industrial materials, that is, pure quartz and quartz-rich mixtures, were investigated through electron paramagnetic resonance and electron spin echo-envelope modulation spectroscopies, with the aim of evaluating the effective role played by defect centres and of assessing whether they can be used to monitor changes in the physical properties of quartz powders with reference to their health effects. The obtained results point to two interactions of the Al defect centres with H⁺, hosted in sites within the channels parallel and perpendicular to the c axis of quartz, respectively. These two Al/H⁺ (h_Al) centres exhibit a weak chemical bond, and their relative amounts appear to be modified/controlled by the thermo-mechanical processes underwent by powders. Indeed, a mechanically promoted inter-conversion between the two kinds of site is suggested. As a consequence, the h_Al centres are effective in monitoring even modest activations of powders, through thermal or mechanical processes, and they are also supposed to play a specific, relevant role in quartz reactivity during the considered industrial processes.     

Rockfall risk assessment to persons travelling in vehicles along a road: the case study of the Amalfi coastal road (southern Italy)

The paper deals with the assessment of rockfall risk to persons travelling in vehicles along the SS163 road, an important transportation corridor supporting a high vehicle traffic within the well-known tourist area of the Amalfi Coast (southern Italy). To this aim, the Rockfall Hazard Rating System (RHRS) and quantitative risk assessment (QRA) procedures, in this latter case for three rockfall risk scenarios, are applied. With reference to a large portion (33.820 out of a total of 50.365 km) of the SS163 road, the obtained QRA results highlight that, although the estimated individual risk to life satisfies the adopted tolerable risk criterion, the computed societal risk cannot be tolerated. Starting from this result, site-specific QRA analyses—carried out with reference to some road sections chosen on the basis of the RHRS results—allow the detection of the SS163 portions where the individual risk to life exceeds the tolerable risk threshold and, then, the recourse to mitigation measures could reveal necessary. In this regard, RHRS and QRA methods can be considered complementary tools in prioritizing the road sections where construction funds can be profitably spent in order to mitigate the rockfall risk with reference to both direct consequences (life loss) and indirect ones (traffic delay and diversions).     

The impact of dredge-fill on Posidonia oceanica seagrass meadows: regression and patterns of recovery

Posidonia oceanica meadows can be severely damaged by dredge-fill operations. We report on the construction of gas pipelines that occurred between 1981 and 1993 in SW Sicily, Italy. A large portion of the meadow was mechanically removed, and the excavated trench was filled with a mosaic of substrates, ranging from sand to consolidated rock debris. Meadow loss and recovery were quantified over 7 years after the end of operations. We recorded an overall loss of 81.20 ha of meadow. Substrate strongly affected recovery as the percent cover by P. oceanica consistently increased on calcareous rubble, reaching values of 44.37 ± 3.05% in shallow sites after 7 years, whereas no significant increase occurred on other substrates. As in the Mediterranean Sea exploitation of coastal areas continues to grow with consequent impacts on P. oceanica meadows, this case study illustrates how artificial rubble-like materials could be employed to support the restoration of damaged meadows.     

Identifying rift zones on volcanoes: an example from La Réunion island,Indian Ocean

We describe a methodology for identifying complex rift zones on recent or active volcanoes, where structures hidden by recent deposits and logistical conditions might prevent carrying out detailed fieldwork. La Réunion island was chosen as a test-site. We used georeferenced topographic maps, aerial photos and digital terrain models to perform a statistical analysis of several morphometric parameters of pyroclastic cones. This provides a great deal of geometric information that can help in distinguishing the localisation and orientation of buried magma-feeding fractures, which constitute the surface expression of rift zones. It also allowed the construction of a complete GIS database of the pyroclastic cones. La Réunion is a perfect example where past and active volcanic rift zones are mostly expressed by clusters of monogenic centres. The data has been validated in the field and compared and integrated with the distribution and geometry of dyke swarms. Results show the presence of several main and secondary rift segments of different ages, locations and orientations, whose origin is discussed considering regional tectonics, local geomorphology, and volcano deformation.     

Degradation and Detoxification of Chlorophenols in Continuous‐Flow Fixed‐Bed Aerobic Reactors

An indigenous bacterial strain of Delftia sp. capable of degrading 2,4‐dicholorophenol and an indigenous bacterial community that degrades 2,4,6‐trichlorophenol (TCP) were employed to inoculate continuous down‐flow fixed‐bed reactors. Continuous‐reactors were constructed from PVC employing hollow PVC cylinders as support material. Synthetic wastewater was prepared by dissolving the corresponding chlorophenol in non‐sterile groundwater. Biodegradation was evaluated by spectrophotometry, chloride release, GC, and microbial growth. Detoxification was evaluated by using Daphnia magna as test organism. Delftia sp. was able to remove an average of 95.6% of DCP. Efficiency in terms of chemical oxygen demand (COD) was of 88.9%. The indigenous bacterial community that degrades TCP reached an average efficiency of 96.5 and 91.6% in terms of compound and COD removal, respectively. In both cases stoichiometric removal of chloride and detoxification was achieved. When synthetic wastewater feed was cut off for 7 days, both reactors showed a fast recovery after inflow restarting, reaching average outlet concentration values within 36 h. The promising behavior of the microorganisms and the low cost of the reactors tested allow us to suggest their possible application to remediation processes.     

Modelling a cohesive‐frictional debris flow: an experimental,theoretical, and field‐based study

The rheology of debris flows is difficult to characterize owing to the varied composition and to the uneven distribution of the components that may range from clay to large boulders, in addition to water. Few studies have addressed debris flow rheology from observational, experimental, and theoretical viewpoints in conjunction. We present a coupled rheological‐numerical model to characterize the debris flows in which cohesive and frictional materials are both present. As a first step, we consider small‐scale artificial debris flows in a flume with variable percentages of clay versus sand, and measure separately the rheological properties of sand–clay mixtures. A comparison with the predictions of a modified version of the numerical model BING shows a reasonable agreement between measurements and simulations. As application to a field case, we analyse a recent debris flow that occurred in Fjærland (Western Norway) for which much information is now available. The event was caused by a glacial lake outburst flood (GLOF) originating from the failure of a moraine ridge. In a previous contribution (Breien et al., Landslides, 2008 , 5: 271–280) we focused on the hydrological and geomorphological aspects. In particular we documented the marked erosion and reported the change in sediment transport during the event. In contrast to the laboratory debris flows, the presence of large boulders and the higher normal pressure inside the natural debris flow requires the introduction of a novel rheological model that distinguishes between mud‐to–clast supported material. We present simulations with a modified BING model with the new cohesive‐frictional rheology. To account for the severe erosion operated by the debris flow on the colluvial deposits of Fjærland, we also suggest a simple model for erosion and bulking along the slope path. Numerical simulations suggest that a self‐sustaining mechanism could partly explain the extreme growth of debris flows running on a soft terrain.