The Last Pterosaurs: First Record from the Uppermost Maastrichtian of the Tremp Syncline (Northern Spain)

Pterosaur bones are for the first time reported from the Tremp Syncline(Spain) and the southern Pyrenees.They come from the Torrebilles-2 site(Isona,Lleida Province) in the upper Maastrichtian part of the Tremp Formation,which falls within the C29r magnetochron.Fragmentary long bones are referred to the Pterosauria based on their cortical thinness,micro-architecture,and histological features.They belong to very large to possibly giant individuals.The most complete specimen is possibly a partial right femur.The review of the Maastrichtian pterosaur record shows that only a few specimens can be referred to the C29r(which contains the K/Pg boundary).The identification of fragmentary remains could improve our knowledge about the abundance and distribution of these flying sauropsids just before the end-Cretaceous mass extinction.     

Millennial-scale shifts in microtidal ecosystems during the Holocene: dynamics and drivers of change from the Po Plain coastal record (NE Italy)

Framed into a robust stratigraphic context, multivariate analyses on the Holocene palaeobiological record (pollen, benthic foraminifers, ostracods) of the Po coastal plain (NE Italy) allowed the investigation of microtidal ecosystems variability and driving parameters along a 35-km-long land–sea transect. Millennial-scale ecosystem shifts are documented by coeval changes in the meiofauna, reflecting variations in organic matter–water depth (shallow-marine environments) and degree of confinement-salinity (back-barrier settings). In-phase shifts of vegetation communities track unsteady water-table levels and river dynamics in freshwater palustrine areas. Five environmental–ecological stages followed one another crossing four tipping points that mark changes in relative sea level (RSL), climate and/or fluvial regime. At the culmination of Mediterranean RSL rise, after the 8200 event, remarkable growth of peatlands took place in the Po estuary, while low accumulation rates typified the shelf. At the transgressive–regressive turnaround (~7000 cal a bp ), the estuary turned into a delta plain with tidally influenced interdistributary embayments. River flow regime oscillations after the Climate Optimum (post-5000 cal a bp ) favoured isolation of the bays and the development of brackish wetlands surrounded by wooded peatlands. The youngest threshold (~800 cal a bp ), which led to the establishment of the modern delta, reflects a major avulsion of the Po River.     

A Reliable Method for Determining the Oxidation State of Manganese at the Microscale in Mn Oxides via Raman Spectroscopy

Manganese oxides are important geomaterials, widespread in terrestrial and Martian environments. Characterisation of the oxidation state of Mn is a central issue in science; this task has been addressed up to the present by X‐ray spectroscopy or diffraction techniques. The former, however, requires access to synchrotron facilities, while the latter does not provide crystal‐chemical information at the local scale. In this work, we compare a large set of Raman data from well‐characterised samples, already published by the same authors of this paper or as found in the literature. We show a clear correlation between the oxidation state of Mn and the wavenumber of peculiar bands; octahedrally co‐ordinated Mn²⁺ is recognised by a band around 530 cm^?1, Mn³⁺ by a band around 580 cm^?1 and Mn⁴⁺ by a band around 630 cm^?1, while tetrahedrally co‐ordinated Mn²⁺ is recognisable by a band around 650 cm^?1. Strongly distorted Mn³⁺ octahedra are indicated by the appearance of Jahn–Teller modes. Our method allows a reliable, easily accessible tool to characterise the oxidation states of Mn in oxides, also suitable for microscale mapping. It provides a robust analytical basis for the use of these minerals as redox indicators in geology/geochemistry, in exoplanetary research or for monitoring technological processes.     

Anomalous heat flow belt along the continental margin of Brazil

International Journal of Earth Sciences - A comprehensive analysis of thermal gradient and heat flow data was carried out for sedimentary basins situated in the continental margin of Brazil (CMB)....     

Reliability of water content estimation by profile probe and its effect on slope stability

Shallow landslide failures are distributed worldwide and cause economic losses and fatalities. A proper evaluation of the possible occurrence of shallow landslides requires reliable characterization of water content. Volumetric water content (θ) is commonly estimated using dielectric sensors, which use manufacturers’ calibration curves developed for specific soil types. In this study, we present the experimental results achieved during a laboratory calibration of a capacitance probe (PR2/6 probe), tested on two sandy soils widely outcropping in Central Italy. The proposed equations demonstrate a more reliable estimation of θ with respect to the generalized soil equation provided by the manufacturer, which overestimates θ by up to 10 percentage points. Such overestimation could affect the evaluation of suction stress in partially saturated shallow soils affecting the slope stability analysis. Although the use of θ from correct calibration equations provides less precautionary factor of safety values, a reliable evaluation of the soil moisture condition is fundamental when mapping and predicting the spatial and temporal occurrence of shallow landslides. The use of the PR2/6 probe with the appropriate soil calibration equations in early warning monitoring systems will provide a more reliable forecast, minimizing the number of false alarms.     

Structure of regional dykes and local cone sheets in the Midhyrna-Lysuskard area, Snaefellsnes Peninsula (NW Iceland)

A detailed understanding of pāhoehoe emplacement is necessary for developing accurate models of flow field development, assessing hazards, and interpreting the significance of lava morphology on Earth and other planetary surfaces. Active pāhoehoe lobes on Kīlauea Volcano, Hawai'i, were examined on 21–26 February 2006 using oblique time series stereo-photogrammetry and differential global positioning system measurements. During this time, the local discharge rate for peripheral lava lobes was generally constant at 0.0061?±?0.0019 m³/s, but the areal coverage rate of the lobes exhibited a periodic increase every 4.13?±?0.64 min. This periodicity is attributed to the time required for the pressure within the liquid lava core to exceed the cooling-induced strength of its margins. The pāhoehoe flow advanced through a series of down-slope and cross-slope breakouts, which began as ～0.2-m-thick units (i.e., toes) that coalesced and inflated to become approximately meter-thick lobes. The lobes were thickest above the lowest points of the initial topography and above shallow to reverse-facing slopes, defined relative to the local flow direction. The flow path was typically controlled by high-standing topography, with the zone directly adjacent to the final lobe margin having an average relief that was a few centimeters higher than the lava-inundated region. This suggests that toe-scale topography can, at least temporarily, exert strong controls on pāhoehoe flow paths by impeding the lateral spreading of the lobe. Observed cycles of enhanced areal spreading and inflated lobe morphology are also explored using a model that considers the statistical likelihood of sequential breakouts from active flow margins and the effects of topographic barriers.     

Quantitative analysis of H2O and CO2 in cordierite using polarized FTIR spectroscopy

We report a FTIR (Fourier transform infrared) study of a set of cordierite samples from different occurrence and with different H₂O/CO₂ content. The specimens were fully characterized by a combination of techniques including optical microscopy, single-crystal X-ray diffraction, EMPA (electron microprobe analysis), SIMS (secondary ion mass spectrometry), and FTIR spectroscopy. All cordierites are orthorhombic Ccmm. According to the EMPA data, the Si/Al ratio is always close to 5:4; X _Mg ranges from 76.31 to 96.63, and additional octahedral constituents occur in very small amounts. Extraframework K and Ca are negligible, while Na reaches the values up to 0.84 apfu. SIMS shows H₂O up to 1.52 and CO₂ up to 1.11 wt%. Optically transparent single crystals were oriented using the spindle stage and examined by FTIR micro-spectroscopy under polarized light. On the basis of the polarizing behaviour, the observed bands were assigned to water molecules in two different orientations and to CO₂ molecules in the structural channels. The IR spectra also show the presence of small amounts of CO in the samples. Refined integrated molar absorption coefficients were calibrated for the quantitative microanalysis of both H₂O and CO₂ in cordierite based on single-crystal polarized-light FTIR spectroscopy. For H₂O the integrated molar coefficients for type I and type II water molecules (ν₃ modes) were calculated separately and are ^[I]ε?=?5,200?±?700?l?mol^?1?cm^?2 and ^[II]ε?=?13,000?±?3,000?l?mol^?1?cm^?2, respectively. For CO₂ the integrated coefficient is $ \varepsilon_{{{\text{CO}}_{ 2} }} $ ?=?19,000?±?2,000?l?mol^?1?cm^?2.     

The significance of Late Devonian ophiolites in the Variscan orogen: a record from the Vosges Klippen Belt

The present work examines the lithological, structural, geochemical and geochronological records from the Klippen Belt located in the southern Vosges Mountains (NE France). The Klippen Belt is represented by discontinuous exposures of serpentinized harzburgite, ophicalcite, gabbro, gneiss and polymictic conglomerate overlain by deep marine pelitic sediments. Structural data and Bouguer anomalies reveal that the Klippen Belt coincides with a significant discontinuity now occupied by a granitic ridge. Gabbro geochemistry indicates a MOR-type affinity similar to recent slow-spreading ridges, but positive Ba, Sr, Th or U anomalies do not exclude the influence of fluids expelled from a subduction zone. A Sm–Nd isochron age of 372?±?18?Ma is thought to reflect gabbro emplacement from a highly depleted mantle source (ε_Nd?=?+11.3), and U–Pb zircon ages from a gneiss sample indicate that the basement found in the Klippen has a Neoproterozoic origin. Combined data indicate the formation of a deep basin during Late Devonian rifting. The Klippen lithologies could testify for the presence of an ocean–continent transition environment subsequently inverted during the Early Carboniferous. Basin inversion during the Middle Visean was probably controlled by rift-related structures, and resulted in folding of the sedimentary successions as well as exhumation along thrust zones of deep parts of the basin represented by the Klippen Belt. Based on correlations with the neighbouring Variscan massifs, it is proposed that the southern Vosges sequences represent a back-arc basin related to the North-directed subduction of the southern Palaeotethys Ocean. This geodynamic reconstruction is tentatively correlated with similar ophiolitic remnants in the northern part of the French Massif Central (Brévenne) and with the evolution of the southern Black Forest. The Late Devonian ophiolites are interpreted as relicts of small back-arc marginal basins developed during general closure of the Palaeozoic subduction systems.     

Magnetic fabric of Pleistocene continental clays from the hanging-wall of an active low-angle normal fault (Altotiberina Fault,Italy)

Anisotropy of magnetic susceptibility (AMS) represents a valuable proxy able to detect subtle strain effects in very weakly deformed sediments. In compressive tectonic settings, the magnetic lineation is commonly parallel to fold axes, thrust faults, and local bedding strike, while in extensional regimes, it is perpendicular to normal faults and parallel to bedding dip directions. The Altotiberina Fault (ATF) in the northern Apennines (Italy) is a Plio-Quaternary NNW–SSE low-angle normal fault; the sedimentary basin (Tiber basin) at its hanging-wall is infilled with a syn-tectonic, sandy-clayey continental succession. We measured the AMS of apparently undeformed sandy clays sampled at 12 sites within the Tiber basin. The anisotropy parameters suggest that a primary sedimentary fabric has been overprinted by an incipient tectonic fabric. The magnetic lineation is well developed at all sites, and at the sites from the western sector of the basin it is oriented sub-perpendicular to the trend of the ATF, suggesting that it may be related to extensional strain. Conversely, the magnetic lineation of the sites from the eastern sector has a prevailing N–S direction. The occurrence of triaxial to prolate AMS ellipsoids and sub-horizontal magnetic lineations suggests that a maximum horizontal shortening along an E–W direction occurred at these sites. The presence of compressive AMS features at the hanging-wall of the ATF can be explained by the presence of gently N–S-trending local folds (hardly visible in the field) formed by either passive accommodation above an undulated fault plane, or rollover mechanism along antithetic faults. The long-lasting debate on the extensional versus compressive Plio-Quaternary tectonics of the Apennines orogenic belt should now be revised taking into account the importance of compressive structures related to local effects.     

The particular “rammed earth” of the Saadian sugar refinery of Chichaoua (XVIth century,Morocco): mineralogical,chemical and mechanical characteristics

This work focuses on the building material used in the Saadian sugar refinery of Chichaoua (about 70 km southwest of Marrakesh). The study involved a classification of different types of rammed earth, followed by their mineralogical characterization based on optical microscopy, scanning electron microscopy (SEM) and X-ray diffraction (XRD). These studies are complemented by chemical investigations, X-ray fluorescence, and thermal analysis (DTA and TGA). The results demonstrate the use of two types of earth for the realisation of rammed earth, the first one non-plastic, -grained with added lime, the other one of low plasticity, and fine grained without addition of lime. Mechanical tests on site and in laboratory how at the first type of material exhibits great strength, exceeding the values known for rammed earth.