Wind profiles at the Boulder Tower

Analysis of wind profiles at the Boulder Tower (BAO) leads to these conclusions:

1. The variation of roughness with wind direction found earlier is confirmed. Roughness lengths measured on the tower are larger than those measured close to the surface.
2. The profiles and measurements of Reynolds stress are consistent with a von-Karman constant of 0.35.
3. The form φ_m=(1?15z/L)^-1/3 fits best in the range -0.6 < z/L < 0. In the range 0 < z/L < 0.5, θ _m ～ 1 + 4.7z/L provides a good fit to the observations. For z/L < 0.1, φ _m also depends on h, the thickness of the PBL. For z/L < -0.6, Φ _m approaches the constant 0.5, in contrast to all previous suggestions. For larger stabilities, the upper level is usually not in the surface layer, and wind ratios become independent of z/L.
4. With snow cover, the effective roughness diminishes to about 1 cm, even for directions for which the roughness length without snow is large.
5. Estimation of winds at 100 or 150 m from information near the surface is best for similarity theory provided that the ratio of height to Monin-Obukhov L is less than 0.1. For larger z/L, simple power laws seem more appropriate.

     

Elemental composition of sediment cores from a mangrove environment using neutron activation analysis

The geochemistry of Sepetiba Bay was studied in four sediment cores using a multi-element approach. Two cores were sampled in the more contaminated eastern part of the bay and two cores were sampled in the western region. The aim was to determine whether less common elements like the rare earths or the actinides are associated with contaminant metals like zinc in the Bay. Samples were analysed by instrumental neutron activation analysis that permits the quantification of total concentrations of metals (Ba, Co, Cr, Cs, Fe, Hf, Rb, Sc, Zn), rare earth elements (Ce, Eu, La, Lu, Sm and Yb), actinides (Th, U), non-metals and semi-metals (As, Br). Organic carbon and total sulphur were also analysed. The results show very strong zinc contamination in the top layers (more than 1000 μg g⁻¹) and background concentrations in the bottom (15 μg g⁻¹). Elements like chromium which would be expected to be released by the heavy industries of Sepetiba Bay, did not show a contamination profile, and concentrations remained close to those of natural environments. No evidence of any association between the zinc and other potential contaminant elements could be identified in this work.     

Morphology and mechanism of eruption of postglacial shield volcanoes in Iceland

Postglacial Icelandic shield volcanoes were formed in monogenetic eruptions mainly in the early Holocene epoch. Shield volcanoes vary in their cone morphology and in the areal extent of the associated lava flows. This paper presents the results of a study of 24 olivine tholeiite and 7 picrite basaltic shield volcanoes. For the olivine tholeiitic shields the median slope is 2.7°, the median height 60 m, the median diameter 3.6 km, the median aspect ratio (height against diameter) 0.019, and the median cone volume 0.2 km³. The picritic shield volcanoes are considerably steeper and smaller. A shield-volcano cone forms from successive lava lake overflows which are of shelly-type pahoehoe. A widespread apron surrounding the cone forms from tube-fed P-type pahoehoe. The slopes of the cones have (a) a planar or slightly convex form, (b) a concave form, or (c) a convex-concave form. A successive stage of a shield volcano is determined on the basis of cone morphology and lava assemblages. A shield-producing eruption has alternating episodes of lava lake overflows and tube-fed delivery to the distal parts of the flow field. In the late stages of eruption, the cone volume increases in response to the increased amount of rootless outpouring on the cone flanks. Normally, only a small percentage of the total erupted volume of a shield volcano, sometimes as little as 1–3%, is in the shield volcano cone itself, the main volume being in the apron of the shield.     

The heterogeneous formation of N2O over bulk condensed phases in the presence of SO2 at high humidities

In view of the uncertainty of the origin of the secular increase of N₂O, we studied heterogeneous processes that contribute to formation of N₂O in an environment that comes as close as possible to exhaust conditions containing NO and SO₂, among other constituents. The N₂O formation was followed using electron capture gas chromatography (ECD-GC). The other reactants and intermediates (SO₂, NO, NO₂ and HONO) were monitored using gas phase UV-VIS absorption spectroscopy. Experiments were conducted at 298 and 368 K as well as at dry and high humidity (approaching 100% rh) conditions. There is a significant heterogeneous rate of N ₂ O formation at conditions that mimic an exhaust plume from combustion processes.The simultaneous presence of NO, SO₂, O₂ in the gas phase and condensed phase water, either in the bulk liquid or adsorbed state has been confirmed to be necessary for the production of significant levels of N₂O. The stoichiometry of the overall reaction is: 2 NO+SO₂+H₂O N₂O+H₂SO₄. The maximum rate of N₂O formation occurred at the beginning of the reaction and scales with the surface area of the condensed phase and is independent of its volume. A significant rate of N₂O formation at 368 K at 100% rh was also observed in the absence of a bulk substrate. The diffusion of both gas and liquid phase reactants is not rate limiting as the reaction kenetics is dominated by the rate ofN₂O formation under the experimental conditions used in this work. The simultaneous presence of high humidity (90–100% rh at 368 K) and bulk condensed phase results in the maximum rate and final yield of N₂O approaching 60% and 100% conversion after one hour in the presence of amorphous carbon and fly-ash, respectively.Work performed in partial fulfillment of the requirements of Dr ès Sciences at EPFL.     

Forced vibrations of rectangular plates subjected to harmonic loading distributed over a rectangular subdomain

Quite frequently naval and ocean structural designers confront the problem of a plate or slab which supports a motor or engine which excites, dynamically, the structural element. Very often the excitation is treated as a concentrated force but, obviously, it acts over a finite area. The present study deals with the title problem for several combinations of boundary conditions by means of a variational approach and also using the finite element method. Dynamic displacement and bending moment amplitudes are determined.     

Distribution of macrobenthic assemblages along a marine gradient in Mediterranean eutrophic coastal lagoons

Coastal lagoons can be characterised by strong environmental changes along the outer marine‐inner brackish gradient, which are reflected in the patterns of distribution of organisms and composition of assemblages. Close to the sea the assemblages are dominated by marine animals, while in the innermost confined areas, there would be estuarine taxa and organisms typical of organically‐enriched areas. During the last decades, human impact has been severe in these habitats and has often profoundly altered the distribution of animals and plants along the gradient. In this study we have analysed the distribution of macrofauna along the outer marine‐inner brackish gradient in five Italian lagoons, affected by severe human disturbance on the Adriatic, Tyrrhenian and Sardinian coasts. We aimed to measure changes in the composition of assemblages according to the distance from the sea, consistent among lagoons and time, after the occurrence of eutrophication, repeated distrophic crisis and other human interventions. We considered existing data from campaigns done during 1994, 1995 and 1999. We arranged different datasets according to the available data, in order to measure the spatial distribution of macrofauna genera with distance from the sea and through time. Analyses showed differences among assemblages related to the gradient. Nevertheless, the species characterizing the assemblages were all typical of organically‐enriched areas, which testified to an impoverishment of diversity and functioning of all these systems.     

High-resolution Surveys for Geohazards and Shallow Gas: NW Adriatic (Italy) and Iskenderun Bay (Turkey)

The need for quantifying and understanding the distribution of shallow gas is both of academic interest and of relevance to offshore facilities. The combination of seafloor mapping, subbottom profiling, and multi-channel seismic data can provide information on regions of possible shallow gas, where the gas impacts the acoustic properties of the host material and the seafloor. In this paper, we present two case studies – one academic and one industry – that evaluate the distribution of shallow gas in two field areas in the Mediterranean. In the first case study, geophysical data from Iskenderun Bay, southeastern Turkey, indicate the presence and distribution of shallow gas. Pockmarks on the seafloor are associated with acoustic wipeout in the shallow subbottom data. Although deeper seismic data do not show bright spots or other indicators of possible gas, instantaneous frequency analysis clearly shows laterally restricted anomalies indicating gas-rich zones. The interpretation of possible shallow gas resulted in moving a proposed drilling location to a nearby area characterized by fewer (but still present) shallow gas signatures. In the second case study, cores acquired in the Po Delta, Adriatic Sea, provide quantitative ground-truthing of shallow gas – as suggested by geophysical data – and provide minimum estimates of the percentage of gas in the subsurface. Cores targeted on anomalous subbottom data yielded up to 41,000 ppm methane; cores with anomalous gas content are associated with thick recent flood deposits which may effectively isolate reactive terrigenous organic matter from biologic and physical re-working.     

Experimental evaluation of early patterns of colonisation of space on rocky shores and seawalls

The introduction of artificial structures in coastal areas can cause fragmentation and loss of natural habitats. Previous studies found that variation in colonisation of space at mid-shore levels could account for differences in mature assemblages between seawalls and vertical surfaces on adjacent rocky shores in Sydney Harbour (Australia). This study tests the model that the nature of the substratum is responsible for different patterns of early colonisation between vertical ledges of rocky shores and seawalls. According to this model, patterns in early colonisation would differ between cleared areas created on vertical surfaces on rocky shores and seawalls, but not between standard surfaces (panels) installed on each structure. Early colonisation of space differed between seawalls and rocky shores, regardless of the type of substratum (clearings versus panels). Differences in relative abundances between structures were evident on both types of substrata for some taxa, while they varied between substrata for others. No taxa, however, showed consistent differences between structures in only the clearings. In addition, the abundance of some taxa differed between panels on the different structures, suggesting that the effects of the substratum were modulated by factors operating differentially between rocky shores and seawalls.