Detecting the stepwise propagation of the Eastern Sicily thrust belt (Italy): insight from thermal and thermochronological constraints

An extensive dataset of vitrinite reflectance, FTIR parameters on organic matter, illite content in mixed layers illite‐smectite, apatite fission tracks and U‐Th/He dating has been used to reconstruct the stepwise propagation of the Eastern Sicily fold‐and‐thrust belt during Late Palaeogene and Neogene times. The results indicate that the fold‐and‐thrust belt is divisible into two levels of thermal maturity. These levels consist of a less evolved level of thermal maturity that records limited sedimentary burial and minor heating, and a more evolved level of thermal maturity that indicates tectonic burial and exhumation at different times. Deformation and exhumation of shallowly buried units are linked to wedge forward propagation by low‐angle thrusts, whereas the evolution of deeply buried units is associated with tectonic imbrications by duplex formation and steep thrusts. The two tectonic styles alternate during evolution of the fold‐and‐thrust belt under low erosion rates.     

Spatially controlled Fe and Si isotope variations: an alternative view on the formation of the Torres del Paine pluton

We present new Fe and Si isotope ratio data for the Torres del Paine igneous complex in southern Chile. The multi-composition pluton consists of an approximately 1 km vertical exposure of homogenous granite overlying a contemporaneous 250-m-thick mafic gabbro suite. This first-of-its-kind spatially dependent Fe and Si isotope investigation of a convergent margin-related pluton aims to understand the nature of granite and silicic igneous rock formation. Results collected by MC-ICP-MS show a trend of increasing δ⁵⁶Fe and δ³⁰Si with increasing silica content as well as a systematic increase in δ⁵⁶Fe away from the mafic base of the pluton. The marginal Torres del Paine granites have heavier Fe isotope signatures (δ⁵⁶Fe = +0.25 ± 0.02 2se) compared to granites found in the interior pluton (δ⁵⁶Fe = +0.17 ± 0.02 2se). Cerro Toro country rock values are isotopically light in both Fe and Si isotopic systems (δ⁵⁶Fe = +0.05 ± 0.02 ‰; δ³⁰Si = ?0.38 ± 0.07 ‰). The variations in the Fe and Si isotopic data cannot be accounted for by local assimilation of the wall rocks, in situ fractional crystallization, late-stage fluid exsolution or some combination of these processes. Instead, we conclude that thermal diffusion or source magma variation is the most likely process producing Fe isotope ratio variations in the Torres del Paine pluton.     

Late‐glacial to Holocene depositional architecture of the Ombrone palaeovalley system (Southern Tuscany,Italy): Sea‐level,climate and local control in valley‐fill variability

The Ombrone palaeovalley was incised during the last glacial sea‐level fall and was infilled during the subsequent Late‐glacial to Holocene transgression. A detailed sedimentological and stratigraphic study of two cores along the palaeovalley axis led to reconstruction of the post‐Last Glacial Maximum valley‐fill history. Stratigraphic correlations show remarkable similarity in the Late‐glacial to early‐Holocene succession, but discrepancy in the Holocene portion of the valley fill. Above the palaeovalley floor, about 60 m below sea‐level, Late‐glacial sedimentation is recorded by an unusually thick alluvial succession dated back to ca 18 cal kyr bp . The Holocene onset was followed by the retrogradational shift from alluvial to coastal facies. In seaward core OM1, the transition from inner to outer estuarine environments marks the maximum deepening of the system. By comparison, in landward core OM2, the emplacement of estuarine conditions was interrupted by renewed continental sedimentation. Swamp to lacustrine facies, stratigraphically equivalent to the fully estuarine facies of core OM1, represent the proximal expression of the maximum flooding zone. This succession reflects location in a confined segment of the valley, just landward of the confluence with a tributary valley. It is likely that sudden sediment input from the tributary produced a topographic threshold, damming the main valley course and isolating its landward segment from the sea. The seaward portion of the Ombrone palaeovalley presents the typical estuarine backfilling succession of allogenically controlled incised valleys. In contrast, in the landward portion of the system, local dynamics completely overwhelmed the sea‐level signal, following marine ingression. This study highlights the complexity of palaeovalley systems, where local morphologies, changes in catchment areas, drainage systems and tributary valleys may produce facies patterns significantly different from the general stratigraphic organization depicted by traditional sequence‐stratigraphic models.     

国内外前寒武纪条带状铁建造研究现状

条带状铁建造(BIFs)主要发育于早前寒武纪时期(3.8~1.8Ga),记录了早期地球演化的重要信息且蕴含丰富的铁矿石资源。本文梳理总结了国内外BIF相关领域的研究认识及存在问题:1统计对比显示,BIF沉积事件与地幔柱、地壳增生等重大地质事件相关;2稀土元素及Nd同位素示踪表明,Fe来源于海水与海底高温热液的混合溶液,其中高温热液与海水比例为1:1000;3 BIFs缺乏负Ce异常且富集重Fe同位素,暗示沉积时古海洋整体处于缺氧环境以避免Fe~(2+)发生氧化;4一些重要科学问题尚未解决,例如Si的主要来源、沉淀机制及条带成因等;5华北克拉通BIFs多形成于约2.54Ga,BIF类型、形成时代与富矿成因等问题有待深入研究。本文认为,加强国内外典型BIFs的对比研究并适当应用现代先进测试技术,有利于探索BIF沉积的精细过程及古老克拉通的早期演化。     

Biogenic volatile compound emissions from a temperate forest,China: model simulation

Emissions of biogenic volatile organic compounds (BVOC) were measured using a relaxed eddy accumulation (REA) technique on an above-canopy tower in a temperate forest (Changbai Mountain, Jilin province, China) during the 2010 and 2011 summer seasons. Solar global radiation and photosynthetically active radiation (PAR) were also measured. Based on PAR energy dynamic balance, an empirical BVOC emission and PAR transfer model was developed that includes the processes of BVOC emissions and PAR transfer above the canopy level, including PAR absorption and consumption, and scattering by gases, liquids, and particles (GLPs). Simulated emissions of isoprene and monoterpenes were in agreement with observations. The averages of the relative estimator biases for the flux were 39.3 % for isoprene, and 27.1 % for monoterpenes in the 2010 and 2011 growing seasons, with NMSE (normalized mean square error) values of 0.133 and 0.101, respectively. The observed and simulated mean diurnal variations of isoprene and monoterpenes in the 2010 and 2011 growing seasons were evaluated for the validation of the empirical model. Under observed atmospheric conditions, the sensitivity analysis showed that emissions of isoprene and monoterpenes were more sensitive to changes in PAR than to water vapor content or to the magnitude of the scattering factor. The emissions of isoprene and monoterpenes in the 2010 and 2011 growing seasons (from June to September) were estimated using this empirical model along with hourly observational data, with mean hourly emissions of 1.71 and 1.55 mg m^?2 h^?1 for isoprene, and 0.48 and 0.47 mg m^?2 h^?1 for monoterpenes in 2010 and 2011, respectively. As formaldehyde (HCHO) is considered as the main oxidation product of isoprene and monoterpenes, it is necessary to investigate the link between HCHO and BVOC emissions. GOME-2 HCHO vertical column densities (VCDs) can be used to estimate BVOC emission fluxes in the Changbai Mountain temperate forest.     

风云卫星数据服务评价指标的验证分析

简述了目前我国风云卫星数据服务以及气象服务效益评估业务的现状,利用层次分析法提出风云卫星数据服务评价的6个1级指标和19个2级指标。设计了风云卫星数据服务评测量表,并采用分半信度、因子分析等方法对量表作信度和效度分析,结果表明所设计的评测量表具有良好的信度和效度,确定了包括服务平台易用性、服务流程规范性、服务响应及时性、服务内容完整性、服务工作主动性、服务宣传广泛性等6个方面的风云卫星数据服务评价指标。