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111.
Fabien Knoll Gilles Cuny Pierre-Olivier Mojon Raquel López-Antoñanzas 《Proceedings of the Geologists' Association. Geologists' Association》2014
The palaeontological content (charophytes and vertebrates) of organic-rich layers from the Middle Jurassic (Bathonian) of the Grands Causses at Mostuéjouls (Aveyron, France) has been examined. It is rich in gyrogonites of Porochara douzensis. The vertebrates of the lower layer include a single hybodontiform tooth, “semionotiform” teeth and scales, and one pycnodontiform tooth whereas the upper layer has yielded one hybodontiform tooth, a variety of actinopterygian remains (mostly Caturus sp. and indeterminate pycnodontiforms) and a few possible reptile remains. The variation in fauna between the two layers is ascribed to a different degree of marine influence. 相似文献
112.
Hydrous partial melting in the sheeted dike complex at fast spreading ridges: experimental and natural observations 总被引:5,自引:1,他引:4
Lydéric France Juergen Koepke Benoit Ildefonse Sarah B. Cichy Fabien Deschamps 《Contributions to Mineralogy and Petrology》2010,160(5):683-704
In ophiolites and in present-day oceanic crust formed at fast spreading ridges, oceanic plagiogranites are commonly observed
at, or close to the base of the sheeted dike complex. They can be produced either by differentiation of mafic melts, or by
hydrous partial melting of the hydrothermally altered sheeted dikes. In addition, the hydrothermally altered base of the sheeted
dike complex, which is often infiltrated by plagiogranitic veins, is usually recrystallized into granoblastic dikes that are
commonly interpreted as a result of prograde granulitic metamorphism. To test the anatectic origin of oceanic plagiogranites,
we performed melting experiments on a natural hydrothermally altered dike, under conditions that match those prevailing at
the base of the sheeted dike complex. All generated melts are water saturated, transitional between tholeiitic and calc-alkaline,
and match the compositions of oceanic plagiogranites observed close to the base of the sheeted dike complex. Newly crystallized
clinopyroxene and plagioclase have compositions that are characteristic of the same minerals in granoblastic dikes. Published
silicic melt compositions obtained in classical MORB fractionation experiments also broadly match the compositions of oceanic
plagiogranites; however, the compositions of the coexisting experimental minerals significantly deviate from those of the
granoblastic dikes. Our results demonstrate that hydrous partial melting is a likely common process in the root zone of the
sheeted dike complex, starting at temperatures exceeding 850°C. The newly formed melt can either crystallize to form oceanic
plagiogranites or may be recycled within the melt lens resulting in hybridized and contaminated MORB melts. It represents
the main MORB crustal contamination process. The residue after the partial melting event is represented by the granoblastic
dikes. Our results support a model with a dynamic melt lens that has the potential to trigger hydrous partial melting reactions
in the previously hydrothermally altered sheeted dikes. A new thermometer using the Al content of clinopyroxene is also elaborated. 相似文献
113.
Numerical resolution of well-balanced shallow water equations with complex source terms 总被引:3,自引:0,他引:3
This paper presents a well-balanced numerical scheme for simulating frictional shallow flows over complex domains involving wetting and drying. The proposed scheme solves, in a finite volume Godunov-type framework, a set of pre-balanced shallow water equations derived by considering pressure balancing. Non-negative reconstruction of Riemann states and compatible discretization of slope source term produce stable and well-balanced solutions to shallow flow hydrodynamics over complex topography. The friction source term is discretized using a splitting implicit scheme. Limiting value of the friction force is derived to ensure stability. This new numerical scheme is validated against four theoretical benchmark tests and then applied to reproduce a laboratory dam break over a domain with irregular bed profile. 相似文献
114.
The surface charge of colloidal particles is usually determined by potentiometric titration. These acid-base titrations make it possible to measure the pH of point-of-zero charge (pzc) for oxide minerals. This macroscopic property is the most important parameter used in surface complexation modeling to reproduce experimental data. The pzc values of goethite reported in the literature vary between 7.0 and 9.5. Carbonate adsorption and/or surface morphology are thought to account for this wide range.We demonstrate a procedure for the removal of the carbonate ions that initially adsorb on goethite and strongly affect the titration curves and pzc determination. We also investigated the crystal-face-specific reactivity of two morphologically different goethites. The z-profiles obtained from atomic force microscopy (AFM) images showed that the goethite with the smallest specific surface area (S = 49 m2/g, denoted G49) exhibits 70% of the (001) face, whereas this value is only 30% for the goethite with largest specific surface area (S = 95 m2/g, denoted G95). This morphologic difference results in slightly different pzc values: 9.0 for G49 goethite and 9.1 for G95 geothite. These experimental pzc values have been correlated with multisite complexation calculations using both the full-site and the 1-pK approaches. We used the full-site approach to consider all of the configurations of hydrogen bond interactions with surface site. The resulting mean charges gave estimated pzc values of 8.9 and 9.2 for the (001) and (101) faces, respectively. Considering these theoretical pzc values for individual faces and the face distributions obtained from AFM analysis, the calculated pzc values are in full agreement with the experimental pzc values. However, this morphologic difference is more expressed in surface charge values than in the pzc values. Indeed, the surface charge of G49 goethite is much higher than that of G95 goethite, and the 1-pK calculations make it possible to fit the titration data satisfactorily. 相似文献
115.
This study aims at understanding the physico-chemical interactions between the saturated brine and the rocks enclosing the
underground salt workings in Lorraine (eastern France). These anhydrite-rich and argillaceous rocks were characterized in
terms of mineralogy, micro-texture and connected porosity. Then, the two main lithofacies, massive anhydrite and anhydrite-rich
argillite, were immersed in brine during more than 1 year. During this batch experiment, the argillites were affected by macroscopic
splitting, contrarily to the massive anhydrite. Micro-texture and brine chemical analyses clearly show the swelling due to
the hydration of anhydrite into gypsum inside the argillites, whereas hydration occurs superficially on the massive anhydrite,
due to its very low permeability. Anhydrite–gypsum transformation is promoted by the presence of dissolved strontium and potassium
in saturated brine. The low activity of water in saturated brine does not allow the clay fraction to swell significantly during
the experiment. Thus, the expansion resulting from the hydration of anhydrite into gypsum might be responsible of the splitting
of argillite in a saturated brine environment. The superficial anhydrite hydration on massive anhydrite can be explained by
the low amount of connected porosity (less than 1%). 相似文献