北祁连西段牛毛泉东金矿地质特征、成矿时代及成因分析

牛毛泉东金矿位于北祁连造山带与阿尔金断裂的结合部位,该地区被誉为西北的"金三角"。牛毛泉东金矿为该地区近年来新发现的受脆韧性剪切带控制的金矿床,金矿体产于阴沟群安山质凝灰岩、安山质凝灰熔岩中的近东西向脆韧性剪切蚀变带,矿化受构造控制显著,成矿具有多阶段性,金主要形成于硫化物-石英-金矿化阶段。矿脉两侧热液蚀变强烈,与成矿有关的蚀变主要为硅化。通过石英流体包裹体测得金矿石中流体包裹体的均一温度112～191℃;成矿流体盐度0.35%～7.86%,平均4.77%;密度为0.92～0.96 g/cm^3,平均0.95 g/cm^3,显示成矿流体具有浅层低温热液特征。对黄铁绢英岩型矿石中绢云母⁴⁰Ar-³⁹Ar测年获得坪年龄为(296.7±2.8) Ma,对应于北祁连陆内伸展拉张构造演化过程。矿床的地质特征及成矿时代与邻近的寒山金矿类似,并受同一条韧性脆性断裂构造带控制,均为低硫浅成低温热液型金矿,主成矿时代为华力西晚期。牛毛泉东金矿的发现及成因研究对指导区域找矿方向具有重要的意义。     

A Quantitative Evaluation of Shale Gas Content in Different Occurrence States of the Longmaxi Formation: A New Insight from Well JY-A in the Fuling Shale Gas Field,Sichuan Basin

Comprehensive quantitative evaluation of shale gas content and the controlling factors in different occurrence states is of great significance for accurately assessing gas-bearing capacity and providing effective well-production strategies. A total of 122 core samples from well JY-A in the Fuling shale gas field were studied to reveal the characteristics of S_1 l shale,15 of which were selected to further predict the shale gas content in different occurrence states, which are dependent on geological factors in the thermal evolution process. Geological parameters were researched by a number of laboratory programs, and the factors influential in controlling shale gas content were extracted by both PCA and GRA methods and prediction models were confirmed by the BE method using SPSS software. Results reveal that the adsorbed gas content is mainly controlled by TOC, Ro, SSA, PD and pyrite content, and the free gas content is mainly controlled by S_2, quartz content, gas saturation and formation pressure for S_1 l in well JY-A. Three methods, including the on-site gas desorption method, the empirical formula method, and the multiple regression analysis method were used in combination to evaluate the shale gas capacity of well JY-A, all of which show that the overall shale gas content of well JY-A is in the range of 2.0–5.0 m~3/t and that the free gas ratio is about 50%, lower than that of well JY-1. Cause analysis further confirms the tectonics and preservation conditions of S_1 l in the geological processes, especially the influence of eastern boundary faults on well JY-A, as the fundamental reasons for the differences in shale gas enrichment in the Jiaoshiba area.     

Cyclostratigraphic Calibration of the Upper Ordovician (Sandbian–Katian) Pagoda and Linhsiang Formations in the Yichang Area, South China

正1 Introduction The Sandbian-Katian is a critical period for the transition from"hot-house"in the Lower Ordovician to"ice-house"in the end-Ordovician (Trotter et al.,2008).During this interval,the South China Block was located in the equatorial region (Torsvik and Cocks,2016),with the widespread accumulation of Pagoda and Linhsiang formations (Zhan and Jin,2007).Although these strata have been investigated for decades and their     

Analyses of the Compositional Characteristics and Sources of the Organochlorine Pesticides in the Surface Sediments of Guanghai Bay,Taishan City,Guangdong Province

Organochlorine pesticides (OCPs) are a class of toxic and harmful persistent organic pollutants widely found in environment. Hexachlorocyclohexane (HCHs) and DDTs are two of the most widely used OCPs (Qiu et al., 2004), so it is important to find out their compositional characteristics and sources in surface sediments. Guanghai Bay is located in the south of Guanghai Bay Industrial Park in Taishan City, Guangdong Province. It borders Huangmaohai to the east and Zhenhai Bay to the west, covering an area of about 236 square kilometers. In this study, surface sediments were collected at 16 sites in Guanghai Bay (Fig. 1). After the surface sediments were pretreated, GC‐MS was used to analyze OCPs. A total of 14 OCPs were detected and their content was shown in Table 1. The concentration of ΣOCPs ranged between 0.507～0.860ng·g‐1, with an average of 0.680 ng?g‐1. In general, the content of ΣOCPs was the highest at No. A12 site. The concentrations of these 14 detected OCPs ordered as dieldrin > epoxy heptachlor > P, P'‐DDD > γ‐HCH >endrin >aldrin > P, P'‐DDE >mirex >hexachlorobenzene >P, P'‐DDT > α‐HCH > δ‐HCH >β‐HCH > heptachlor.     

陕西岐山蓟县系碳氧同位素特征及其古环境意义

陕西岐山二郎沟蓟县系剖面位于华北克拉通南缘,发育一套浅海相碳酸盐岩,自下而上出露龙家园组和巡检司组。两个岩组共采集、测试了碳、氧同位素样品184件,结果显示δ13 C值落在-1.747‰～1.144‰之间,总体上较稳定,平均值为-0.523‰;δ~(18)O值整体在-8.662‰～-2.540‰之间,大部分落在-5.5‰至-3‰,平均值为-4.469‰,低幅高频振荡。碳同位素旋回性较明显,可以进一步划分出4个旋回。碳、氧同位素曲线与燕山地区蓟县系已有研究结果相似性较高,其中,巡检司组近顶部出现的约为2‰的负偏事件,可大致对应于蓟县剖面雾迷山组顶部至洪水庄组的负偏事件。碳同位素的升降趋势及藻类数量(叠层石)丰度变化表明当时海平面在不断变化。此外,二郎沟剖面研究结果还与俄罗斯南乌拉尔阿孜瓦尔组以及加拿大霍恩比湾群的碳、氧同位素曲线也颇为相近,符合全球中元古代碳同位素组成特别稳定的特征,是对全球统一的古海洋背景的响应。     

重庆南川三泉奥陶系宝塔组碳同位素特征及地层对比

对重庆市南川区三泉镇宝塔组进行连续而高密度的碳、氧同位素和牙形刺采样与分析。分析结果显示,碳同位素值及曲线形态与晚奥陶世凯迪期碳同位素正漂移事件Gutternberg Inorganic Carbon Excursion (GICE)一致,并显示出的三个次级峰值。宝塔组自下而上发育牙形刺:Protopangerodus insculptus带和Hamarodus brevirameus带。通过与四川盆地及周缘地区其他剖面宝塔组碳同位素曲线的对比,发现GICE事件在不同剖面发育程度不完全一致,南部发育较北部更全,宝塔组起始沉积时间有差异。通过与湖北、安徽、塔里木盆地、北美和瑞典地区的对比,认为中扬子地区宝塔组可能发育不完全;塔里木盆地其浪组与四川盆地宝塔组可对比;再次证实GICE事件具有全球性属性,其多次波动的特征可能与地球古海洋环境变化和奥陶纪生物大辐射有密切关系。