The role of organic coatings in the enrichment of marine particles with selenium. The fixation of selenite on an adsorbed amino acid

The enrichment of marine particles with selenium cannot be explained as that with metals present in cationic form by complexation with anionic functional groups of adsorbed organic matter. Physicochemical data obtained using a model system are reported. The surface of the particles is modelized by a mercury electrode whose surface charge density can be easily changed, covered by a layer of adsorbed polymers. Studies with different kinds of macromolecules and salts show a specific interaction between adsorbed polyalanine and selenite. The results can be explained by the concordance of the distances between two oxygen atoms in this oxyanion and between two amine groups of the adsorbed polypeptide. A similar mechanism could occur in marine aggregates whatever their nature, as long as they contain amine groups at their surface which result in this concordance. Some prospects derived from the results are discussed.     

Circumstellar dust and circumstellar extinction curves

We have calculated the circumstellar extinction curves produced by dust grains which absorb and scatter the stellar radiation in the shells of pre-main-sequence stars. A Monte Carlo method was used to model the radiative transfer in non-spherical shells. The dependence on the particle size distribution and the dust shell parameters has been examined.The application of the theoretical results to explain the extinction and polarization of the Herbig Be star HD 45677 shows that the dust shell is not disk-like and that very small grains are absent in it.     

Field Placement and Evaluation of Stabilized Dredged Material (SDM) from the New York/New Jersey Harbor

Since the 1997 local ban on ocean dumping of dredged sediments, the States of New York and New Jersey have pursued a policy of environmentally sound solutions to the management of dredged material, including beneficial use of stabilized dredged material (SDM) in transportation applications. A pilot study was initiated in 1998 to evaluate the use of SDM in the construction of highway embankments. Utilizing 80,000 cubic yards of dredged material, two embankments were constructed from SDM on a commercial development area adjacent to the Harbor. Geotechnical properties and handling of SDM were evaluated both during and one year post - construction. This article presents the evaluation of the embankments themselves, including constructability and performance. The results demonstrate that SDM satisfies most of the geotechnical criteria for fill construction, except those for durability, requiring proper coverage and protection similar to that provided for fills constructed on cohesive soils. This same characteristic precludes long term stockpiling of SDM prior to final placement, limiting applications to those that have schedules overlapping with dredging projects. Increased costs for the use of SDM can be as high as $8 per cubic yard over traditional fills; however, this cost may be recouped through management fees collected from dredging projects.     

The OSIRIS‐REx target asteroid (101955) Bennu: Constraints on its physical,geological, and dynamical nature from astronomical observations

We review the results of an extensive campaign to determine the physical, geological, and dynamical properties of asteroid (101955) Bennu. This investigation provides information on the orbit, shape, mass, rotation state, radar response, photometric, spectroscopic, thermal, regolith, and environmental properties of Bennu. We combine these data with cosmochemical and dynamical models to develop a hypothetical timeline for Bennu's formation and evolution. We infer that Bennu is an ancient object that has witnessed over 4.5 Gyr of solar system history. Its chemistry and mineralogy were established within the first 10 Myr of the solar system. It likely originated as a discrete asteroid in the inner Main Belt approximately 0.7–2 Gyr ago as a fragment from the catastrophic disruption of a large (approximately 100‐km), carbonaceous asteroid. It was delivered to near‐Earth space via a combination of Yarkovsky‐induced drift and interaction with giant‐planet resonances. During its journey, YORP processes and planetary close encounters modified Bennu's spin state, potentially reshaping and resurfacing the asteroid. We also review work on Bennu's future dynamical evolution and constrain its ultimate fate. It is one of the most Potentially Hazardous Asteroids with an approximately 1‐in‐2700 chance of impacting the Earth in the late 22nd century. It will most likely end its dynamical life by falling into the Sun. The highest probability for a planetary impact is with Venus, followed by the Earth. There is a chance that Bennu will be ejected from the inner solar system after a close encounter with Jupiter. OSIRIS‐REx will return samples from the surface of this intriguing asteroid in September 2023.     

Hydrological response to climate change in a glacierized catchment in the Himalayas

The analysis of climate change impact on the hydrology of high altitude glacierized catchments in the Himalayas is complex due to the high variability in climate, lack of data, large uncertainties in climate change projection and uncertainty about the response of glaciers. Therefore a high resolution combined cryospheric hydrological model was developed and calibrated that explicitly simulates glacier evolution and all major hydrological processes. The model was used to assess the future development of the glaciers and the runoff using an ensemble of downscaled climate model data in the Langtang catchment in Nepal. The analysis shows that both temperature and precipitation are projected to increase which results in a steady decline of the glacier area. The river flow is projected to increase significantly due to the increased precipitation and ice melt and the transition towards a rain river. Rain runoff and base flow will increase at the expense of glacier runoff. However, as the melt water peak coincides with the monsoon peak, no shifts in the hydrograph are expected.     

A statistical analysis for pattern recognition of small cloud particles sampled with a PMS-2DC probe

Although small particles (size between 25 m and 200 m) are frequently observed within ice and water clouds, they are not generally used properly for the calculation of structural, optical and microphysical quantities. Actually neither the exact shape nor the phase (ice or water) of these particles is well denned since the existing pattern recognition algorithms are only efficient for larger particle sizes. The present study describes a statistical analysis concerning small hexagonal columns and spherical particles sampled with a PMS-2DC probe, and the corresponding images are classified according to the occurrence probability of various pixels arrangements. This approach was first applied to synthetic data generated with a numerical model, including the effects of diffraction at a short distance, and then validated against actual data sets obtained from in-cloud flights during the pre-ICE89 campaign. Our method allows us to differentiate small hexagonal columns from spherical particles, thus making possible the characterization of the three dimensional shape (and consequently evaluation of the volume) of the particles, and finally to compute e.g., the liquid or the ice water content.     

Sediment routing in the Zagros foreland basin: Drainage reorganization and a shift from axial to transverse sediment dispersal in the Kurdistan region of Iraq

In the northwestern sector of the Zagros foreland basin, axial fluvial systems initially delivered fine-grained sediments from northwestern source regions into a contiguous basin, and later transverse fluvial systems delivered coarse-grained sediments from northeastern sources into a structurally partitioned basin by fold-thrust deformation. Here we integrate sedimentologic, stratigraphic, palaeomagnetic and geochronologic data from the northwestern Zagros foreland basin to define the Neogene history of deposition and sediment routing in response to progressive advance of the Zagros fold-thrust belt. This study constrains the depositional environments, timing of deposition and provenance of nonmarine clastic deposits of the Injana (Upper Fars), Mukdadiya (Lower Bakhtiari) and Bai-Hasan (Upper Bakhtiari) Formations in the Kurdistan region of Iraq. Sediments of the Injana Formation (~12.4–7.75 Ma) were transported axially (orogen-parallel) from northwest to southeast by meandering and low-sinuosity channel belt system. In contrast, during deposition of the Mukdadiya Formation (~7.75–5 Ma), sediments were delivered transversely (orogen-perpendicular) from northeast to southwest by braided and low-sinuosity channel belt system in distributive fluvial megafans. By ~5 Ma, the northwestern Zagros foreland basin became partitioned by growth of the Mountain Front Flexure and considerable gravel was introduced in localized alluvial fans derived from growing topographic highs. Foredeep accumulation rates during deposition of the Injana, Mukdadiya and Bai-Hasan Formations averaged 350, 400 and 600 m/Myr respectively, suggesting accelerated accommodation generation in a rapidly subsiding basin governed by flexural subsidence. Detrital zircon U-Pb age spectra show that in addition to sources of Mesozoic-Cenozoic cover strata, the Injana Formation was derived chiefly from Palaeozoic-Precambrian (including Carboniferous and latest Neoproterozoic) strata in an axial position to the northwest, likely from the Bitlis-Puturge Massif and broader Eastern Anatolia. In contrast, the Mukdadiya and Bai-Hasan Formations yield distinctive Palaeogene U-Pb age peaks, particularly in the southeastern sector of the study region, consistent with transverse delivery from the arc-related terranes of the Walash and Naopurdan volcano-sedimentary groups (Gaveh-Rud domain?) and Urumieh-Dokhtar magmatic arc to the northeast. These temporal and spatial variations in stratigraphic framework, depositional environments, sediment routing and compositional provenance reveal a major drainage reorganization during Neogene shortening in the Zagros fold-thrust belt. Whereas axial fluvial systems initially dominated the foreland basin during early orogenesis in the Kurdistan region of Iraq, transverse fluvial systems were subsequently established and delivered major sediment volumes to the foreland as a consequence of the abrupt deformation advance and associated topographic growth in the Zagros.     

Whipple telescope observations of LS I +61 303: 2004–2006

In this paper we present the results of the past two years observations on the galactic microquasar LS I +61 303 with the Whipple 10 m gamma-ray telescope. The recent MAGIC detection of the source between 200 GeV and 4 TeV suggests that the source is periodic with very high energy (VHE) gamma-ray emission linked to its orbital cycle. The entire 50-hour data set obtained with Whipple from 2004 to 2006 was analyzed with no reliable detection resulting. The upper limits obtained in the 2005–2006 season covered several of the same epochs as the MAGIC Telescope detections, albeit with lower sensitivity. Upper limits are placed on emission during the orbital phases of 0→0.1 and 0.8→1, phases which are not included in the MAGIC data set.      

阿尔金断裂带晚第四纪左旋走滑速率及其构造运动转换模式讨论

在高分辨率SPOT卫星数字影像和大比例尺航片处理、断错地貌制图、野外核实与位移测量基础上, 利用宇宙成因核素(¹⁰Be, ²⁶Al)、碳十四(¹⁴C)和热释光(TL)等多种测年手段, 厘定了各断错地貌面的形成年龄, 得到了阿尔金断裂带不同段落全新世左旋走滑速率: 阿克赛以西的中、西段左旋走滑速率可达(17.5±2) mm/a, 肃北-石包城段为(11±3.5) mm/a左右, 疏勒河口段减少到(4.8±1) mm/a左右, 东端宽滩山段仅约(2.2±0.2) mm/a, 左旋走滑速率突变点位于阿尔金断裂带中东段存在分支活动逆断层向南东扩展的肃北、石包城和疏勒河等三联点上. 矢量分析表明, 三联点东、西两侧左旋滑动速率的减少量转换成了阿尔金断裂带中东段南盘北西向活动逆断层上的地壳缩短和上盘推覆体抬升, 形成了党河南山、大雪山、祁连山等条块山地. 因此, 青藏高原北部物质向东挤出的速率和幅度是有限的, 符合“叠瓦状逆冲转换——有限挤出模型”.