Trace metals in the North Sea

The distribution of zinc, manganese, nickel, copper and cadmium in water and biological material has been measured in the southern North Sea and Straits of Dover, and off the north-east coast of England. These investigations provide baseline values against which future pollution changes can be measured.     

Archean regional transpression and paleomagnetism in northwestern Ontario, Canada

The Archean metamorphic rocks of the Superior province of the Canadian Shield occur in lithologically defined belts or subprovinces. The tectonically more stable interiors of belts possess consistent primary components of magnetic remanence. In the case of the Quetico belt, these stable directions are tightly grouped about 005°/55° with some minor dispersion and most were acquired during the cooling that followed syntectonic recrystallisation.

This study examines the directions of primary remanence components for rocks along the margins of the Quetico belt, within 4 km of the strongly deformed vertical, ENE-trending boundaries. The boundaries are known to have experienced dextral transpression involving penetrative single-phase deformation which out-lasted metamorphism. Within a few kilometres of the belt boundaries, the primary remanence components are re-distributed along a vertical ENE-trending, great-circle girdle which is nearly parallel to the plane of transpressive shear and regional schistosity. It is suggested that the effects of transpression have mechanically deflected the components of primary remanence toward this plane.     

Stable isotope evidence for the atmospheric origin of CO2 involved in carbonation of MSWI bottom ash

Stable isotopes were used to constrain the origin of CO₂ involved in the ageing process of municipal solid waste incineration (MSWI) bottom ash under open-air conditions. The δ¹³C and δ¹⁸O values of CaCO₃ occurring in MSWI bottom ash samples of variable age and the δ¹³C of the residual organic matter content were measured, and laboratory assessments made of the isotopic fractionation accompanying CaCO₃ neo-formation during accelerated carbonation experiments of bottom ash or pure lime with atmospheric or industrial CO₂. The results indicate that stable isotopic compositions exhibited by fresh and aged bottom ash samples reflect non-equilibrium processes resembling those described in the carbonation of concrete and mortar. They also lead to conclusions on the prevalent involvement of atmospheric CO₂ in the open-air carbonation of MSWI bottom ash.     

An integrated wavelet concept of physical geodesy

For the determination of the earth's gravity field many types of observations are nowadays available, including terrestrial gravimetry, airborne gravimetry, satellite-to-satellite tracking, satellite gradio-metry, etc. The mathematical connection between these observables on the one hand and gravity field and shape of the earth on the other is called the integrated concept of physical geodesy. In this paper harmonic wavelets are introduced by which the gravitational part of the gravity field can be approximated progressively better and better, reflecting an increasing flow of observations. An integrated concept of physical geodesy in terms of harmonic wavelets is presented. Essential tools for approximation are integration formulas relating an integral over an internal sphere to suitable linear combinations of observation functionals, i.e. linear functionals representing the geodetic observables. A scale discrete version of multiresolution is described for approximating the gravitational potential outside and on the earth's surface. Furthermore, an exact fully discrete wavelet approximation is developed for the case of band-limited wavelets. A method for combined global outer harmonic and local harmonic wavelet modelling is proposed corresponding to realistic earth's models. As examples, the role of wavelets is discussed for the classical Stokes problem, the oblique derivative problem, satellite-to-satellite tracking, satellite gravity gradiometry and combined satellite-to-satellite tracking and gradiometry. Received: 28 February 1997 / Accepted: 17 November 1997     

Towards a direct collapse–load method of design for concrete frames subjected to severe ground motions

Most current methods of design for concrete structures under earthquake loads rely on highly idealized ‘equivalent’ static representations of the seismic loads and linear‐elastic methods of structural analysis. With the continuing development of non‐linear methods of dynamic analysis for the overload behaviour and collapse of complete concrete structures, a more direct and more accurate design procedure becomes possible which considers conditions at system collapse. This paper describes an evaluation procedure that uses non‐linear dynamic collapse–load analysis together with global safety coefficients. A back‐calibration procedure for evaluating the global safety coefficients is also described. The aim of this paper is to open up discussion of alternative methods of design with improved accuracy which are necessary to move towards a direct collapse–load method of design. Copyright © 2002 John Wiley & Sons, Ltd.     

Geochronology and geochemistry of Grenvillian igneous suites in the northern Oaxacan Complex, southern Mexico: tectonic implications

Chemical and U–Pb isotopic analyses of metaigneous rocks in the northern Oaxacan Complex in southern Mexico indicate that they form part of two granitic–gabbroic suites intruded at 1157–1130 and 1012 Ma, which were metamorphosed under granulite facies conditions between 1004 and 980 Ma. Although the older suite has both within-plate and arc geochemical signatures, the arc characteristics (enrichment of La and Ce relative to Nb, Ta, and Th) are inferred to result from crustal contamination, a conclusion consistent with their negative _Nd signatures. The younger suite is spatially associated with anorthosites (from which we were unable to acquire a protolith age), suggesting that collectively it forms part of anorthosite–mangerite–charnockite–granite (AMCG) suites. The tholeiitic nature of the mafic rocks along with the within-plate character of the felsic rocks suggests that they were intruded during extension related to either farfield backarc rifting, rifting above a slab window, or anorogenic intercontinental rifting. Potentially correlative AMCG suites are widespread in Mexico, the Grenville Province of eastern Canada and northeastern USA, and the Andean massifs of Colombia, however, Pb isotopic data most closely resemble those in South America. These data are consistent with published hypotheses that suggest Oaxaquia represents an exotic terrane derived from Amazonia.     

Peak response of 2-DOF uncoupled oscillator under two-directional base motion

This paper investigates the peak response of a 2-DOF uncoupled linear oscillator under arbitrarily oriented two-component horizontal earthquake motion. Input data consist of 22 two-component acceleration records from the magnitude 6.6, October 15, 1979 Imperial Valley earthquake. One-directional response spectra for each principal direction of the oscillator, and two-directional response spectra (amplitude of the peak resultant response and its direction with respect to principal directions) are calculated by considering all angles of incidence of the excitation. The results indicate that, for oscillators that are not too flexible (i.e. with natural frequencies greater than 0.8 Hz), the two-directional peak response is controlled by the weaker direction of the oscillator. For flexible oscillators the two-directional peak response is controlled by the direction whose natural frequency is closer to dominant ground motion frequencies. The results also show that when the two-directional peak response is expressed as a weighted sum of one-directional peak responses, the weighting factors are not constants, but functions of oscillator and dominant ground motion frequencies.     

Changes in the hydrography of Central California waters associated with the 1997–98 El Niño

Oceanographic conditions off Central California were monitored by means of a series of 13 hydrographic cruises between February 1997 and January 1999, which measured water properties along an oceanographic section perpendicular to the California Coast. The 1997–98 El Niño event was defined by higher than normal sea levels at Monterey, which began in June 1997, peaked in November 1997, and returned to normal in March 1998. The warming took place in two distinct periods. During June and July 1997, the sea level increased as a result of stronger than normal coastal warming below 200 dbars and within 100 km of the coast, which was associated with poleward flow of saltier waters. During this period, deeper (400–1000 dbar) waters between 150–200 km from shore were also warmed and became more saline. Subsequently, sea level continued to rise through January 1998, mostly as a result of the warming above 200 dbars although, after a brief period of cooling in September 1997, waters below 200 dbar were also warmer than normal during this period. This winter warm anomaly was also coastally trapped, extending 200 km from shore and was accompanied by cooler and fresher water in the offshore California current. In March and April 1998, sea level dropped quickly to normal levels and inshore waters were fresher and warmer than the previous spring and flowed southward.The warming was consistent with equatorial forcing of Central California waters via propagation of Kelvin or coastally-trapped waves. The observed change in heat content associated with the 1997–98 El Niño was the same as that observed during the previous seasonal cycle. The warming and freshening events were similar to events observed during the 1957–58 and 1982–83 El Niños.     

Residential segregation and housing in Berlin: changes since unification

This paper examines the spatial patterns and extent of residential segregation in Berlin at the time of unification, and also considers changes since that date. Residential segregation is differentiated into three components - demographic, socio-economic and ethnic. For all these dimensions, segregation depends on housing provision and the rules of admission to various segments of the housing market. The former differences in housing regulations in East and West Berlin are therefore of importance, as well as changes since unification. The paper shows that before unification demographic segregation was more prominent in East Berlin, whilst socio-economic segregation was more pronounced in West Berlin. Ethnic minority communities in West Berlin had developed from the immigration of guestworkers and their families, with moderate levels of segregation: however in East Berlin there were very few foreign contract workers present throughout the 1980s. In spite of the short time-period since unification, there are clear signs of convergence between the segregation patterns in the two parts of the city. Nevertheless, it is argued that population movements between East and West are still remarkably low, so that differences in the population patterns will continue to exist for some time to come. This revised version was published online in August 2006 with corrections to the Cover Date.