Water vapor in the atmosphere over the northern Tien Shan

Refined data of systematic measurements of total water vapor in the atmosphere from May 1980 to April 2005 are presented. The data were obtained at the Issyk Kul atmospheric-monitoring station by the method of solar molecular-absorption spectroscopy. Over 25 years, the annual mean water-vapor content in the atmosphere increased by 4.5% at a mean rate of increase of 0.18% per year. However, the water-vapor content decreased in the last five years. The results of statistical processing of experimental data (general statistical characteristics, correlation coefficients, composite oscillations) are described. A refined model is proposed for forecasts of temporal variations in the monthly mean and annual mean water-vapor contents for the coming years. The model includes a linear trend and the sum of oscillations with periods close to the periods of a number of well-known geophysical phenomena. Regression equations are proposed to relate the water-vapor content in the atmospheric column to the surface temperature and absolute humidity.     

Lead contamination of small cetaceans in European waters--the use of stable isotopes for identifying the sources of lead exposure

Lead concentrations and isotopic composition have been measured in bone and teeth of small cetaceans belonging to three species (Delphinus delphis, Phocoena phocoena and Stenella coeruleoalba), to evaluate the toxicological risk and to determine sources of lead in the European waters. Lead concentrations, far lower than threshold value inducing toxic effects in human, were higher in teeth than in bones, but highly correlated between the two tissues (r=0.92, p<0.001). Large variations of 206Pb/207Pb values in bone tissue showed that cetaceans must be submitted to various atmospheric influences. No geographical differences appeared which is consistent with studies on their distribution indicating seasonal movements between Brittany waters and the Bay of Biscay. The negative correlation between 206Pb/207Pb ratios and age of the individuals reflected the decrease in the production of alkyl lead in Europe, i.e., the increasing use of unleaded gasoline.     

Determination of phospholipid fatty acid structures and stable carbon isotope compositions of deep-sea sediments of the Northwest Pacific, ODP site 1179

Sediment samples ranging from 0.05 to 278 m below sea floor (mbsf) at a Northwest Pacific deep-water (5564 mbsl) site (ODP Leg 191, Site 1179) were analyzed for phospholipid fatty acids (PLFAs). Total PLFA concentrations decreased by a factor of three over the first meter of sediment and then decreased at a slower rate to approximately 30 mbsf. The sharp decrease over the first meter corresponds to the depth of nitrate and Mn(IV) reduction as indicated by pore water chemistry. PLFA-based cell numbers at site 1179 had a similar depth profile as that for Acridine orange direct cell counts previously made on ODP site 1149 sediments which have a similar water depth and lithology. The mole percentage of straight chain saturated PLFAs increases with depth, with a large shift between the 0.95 and 3.95 mbsf samples. PLFA stable carbon isotope ratios were determined for sediments from 0.05 to 4.53 mbsf and showed a general trend toward more depleted δ¹³C values with depth. Both of these observations may indicate a shift in the bacterial community with depth across the different redox zones inferred from pore water chemistry data. The PLFA 10me16:0, which has been attributed to the bacterial genera Desulfobacter in many marine sediments, showed the greatest isotopic depletion, decreasing from − 20 to − 35‰ over the first meter of sediment. Pore water chemistry suggested that sulfate reduction was absent or minimal over this same sediment interval. However, 10me16:0 has been shown to be produced by recently discovered anaerobic ammonium oxidizing (anammox) bacteria which are known chemoautotrophs. The increasing depletion in δ¹³C of 10me16:0 with the unusually lower concentration of ammonium and linear decrease of nitrate concentration is consistent with a scenario of anammox bacteria mediating the oxidation of ammonium via nitrite, an intermediate of nitrate reduction.     

Measurement of alkaline and earthy ions in fish otolith and sea water using a high performance ion chromatography

Fish growth and the relation between growth and environmental conditions offer a good opportunity for measuring alkaline and earthy ions in fish otoliths.The analytical method must involve high sensitivity when attempting to discriminate between fish growth and environmental conditions.The aim of this paper is to propose a chromatographic method, with low detection limits, as a new approach in determining some important micronutrients present in sea water and fish otoliths.The work samples are: coastal, off-shore and sediment waters and fish otoliths (Engraulis encrasicholus, Mullus barbatus, Umbrina cirrhosa, Sciaena umbra, Pagellus erythrinus) in the Adriatic Sea and the Canal of Sicily.The analytical method includes an IONPAC CS12A chromatographic column and a 18 mM methanesulfonic acid eluent.The detection limit readings obtained with this method, for one E. encrasicholus fish otolith, weighing 2.6 mg are equal or inferior to 0.1 μg/L for lithium (Li), 59 μg/L for sodium (Na), 46 μg/L for ammonium (NH₄), 23 μg/L for potassium (K), 13 μg/L for magnesium (Mg), 88 μg/L for manganese (Mn), 2.567 μg/L for calcium (Ca) and 13 μg/L for strontium (Sr).The HPIC method minimizes overlaps such as Na on Li, and NH₄ in seawater and Ca on Mg and Sr in fish otolith. These elements are an essential constituent present in otoliths when describing the relation between growth and environmental conditions.Good separation among analytes is achieved within 16 min.     

Equilibrium constants of triethanolamine in major seawater salts

Acid–base equilibrium constants of triethanolamine (TEA) have been determined by potentiometric titrations with a glass electrode, at 25 °C. Ionic strength was kept constant with only one electrolyte (using one of these salts: NaCl, KCl, MgCl₂ or CaCl₂), with binary mixtures of MgCl₂ and CaCl₂, and finally, in a solution with a composition approximately similar to that of natural seawater without sulfate. Equilibrium constants have been expressed in function of ionic strength by means of Pitzer equations and interaction parameters proposed in this theory have been obtained. It has been found that acid–base behaviour of TEA depends greatly on the salt used: basicity of TEA is decreased by CaCl₂, while it is increased by the other electrolytes used in this work.     

Appraisal of storm beach buffer width for cyclonic waves

The loss of beach sand from berm and dune due to high waves and surge is a universal phenomenon associated with sporadic storm activities. To protect the development in a coastal hazard zone, hard structures or coastal setback have been established in many countries around the world. In this paper, the requirement of a storm beach buffer, being a lesser extent landward comparing with the coastal setback to ensure the safety of infrastructures, is numerically assessed using the SBEACH model for three categories of wave conditions in terms of storm return period, median sand grain size, berm width, and design water level. Two of the key outputs from the numerical calculations, berm retreat and bar formation offshore, are then analysed, as well as beach profile change. After having performed a series of numerical studies on selected large wave tank (LWT) test results with monochromatic waves using SBEACH, we may conclude that: (1) Berm erosion increases and submerged bar develops further offshore as the storm return period increases for beach with a specific sand grain size, or as the sand grain reduces on a beach under the action of identical wave condition; (2) Higher storm waves yield a large bar to form quicker and subsequently cause wave breaking on the bar crest, which can reduce the wave energy and limit the extent of the eroding berm; (3) A larger buffer width is required for a beach comprising small sand grain, in order to effectively absorb storm wave energy; and (4) Empirical relationships can be tentatively proposed to estimate the storm beach buffer width, from the input of wave conditions and sediment grain size. These results would benefit a beach nourishment project for shore protection or design of a recreational beach.     

The eastern slope of the southern Adriatic basin: a case study of submarine landslide characterization and tsunamigenic potential assessment

Marine Geophysical Research - The southern Adriatic basin is the current foredeep of the Albanide fold-and-thrust belt that runs along the eastern boundary of the Adriatic basin and partly owes its...     

Impact of Ocean Mean Dynamic Topography on Satellite Data Assimilation

The response of an eddy-permitting ocean model to changes imposed by the use of different mean dynamic topographies (MDT) is analyzed in a multivariate assimilation context, allowing the evaluation of this impact, not only on the surface circulation, but also on the interior ocean representation. The assimilation scheme is a reduced-order sequential Kalman filter (SEEK). In a first set of experiments, high resolution sea surface temperature, along-track sea surface height and sea surface salinity from climatology are assimilated into a 1/3° resolution North and Tropical Atlantic version of the HYCOM model. In a second experiment, in situ profile data are assimilated in addition to the surface measurements.

The first set of experiments illustrates that important differences in the representation of the horizontal model circulation pattern are related to differences in the MDT used. The objective of assimilation is to improve the representation of the 3D ocean state. However, the imperfect representation of the mean dynamic topography appears to be an important limiting factor with regard to the degree of realism obtained in the simulated flow.

Vertical temperature and salinity profiles are key observations to drive a general circulation ocean model toward a more realistic state. The second set of experiments shows that assimilating them in addition to sea surface measurements is a far from trivial exercise. A specific difficulty is due to inconsistencies between the dynamic topography diagnosed from in situ observations and that diagnosed from sea surface height. These two fields obtained from different data sources do not contain exactly the same information. In order to overcome this difficulty, a strategy is proposed and validated.     

Cement Deep Soil Mixing (CDSM) for Solidification of Soft Estuarine Sediments

A preliminary study was conducted to determine the potential for cement deep soil mixing (CDSM) technology as a method for in-situ solidification of contaminated river and estuarine sediments. The study was conducted in Newark Bay, near the mouth of the Passaic River, New Jersey. The primary objective of the study was to evaluate the viability of CDSM for the in-situ S/S with a focus on: 1) determining the correct mix of the cement slurry, which provides rapid stabilization of the sediment matrix, 2) potential resuspension of solids during CSDM operations, 3) the effects of high organic content on the solidification process, and 4) the feasibility of using conventional dredging/extraction methods once the sediments have been stabilized and allowed to cure. The results of the study show CDSM slurry mixtures, as low as 7% in cement content, result in significant solidification and strength gain of in-situ sediments under ambient conditions. In sediments with very high organic contents (> 20%), the slurry mix would need to be adjusted to account for retardation effects of organics on cement hydration. Sediment resuspension during application was shown to be minimal at a distance of as little as 75 feet from the mixing head. Strength gains were considerable, effectively consolidating the sediment particles in a secure matrix, but not so high as to preclude extraction of solidified sediments with conventional dredging equipment. Dredged solidified sediment exhibited characteristics of a stiff glacial clay, and as such was easier to handle and transport than untreated dredged sediments. This technique has high potential to be used as an interim remedial measure prior to either extraction and decontamination/disposal or proper capping.     

Probabilistic analysis for wave‐induced submarine landslides

Abstract

When waves propagate over the ocean floor, they induce a change of hydrodynamic pressure, positive under the crest and negative under the trough. These pressure changes may cause shear failure in soft sediments and lead to submarine landslides. This paper presents a general analytical procedure for evaluating the probability of wave‐induced failure in offshore clay sediments. Both the wave and the un‐drained shear strength of clay sediments are considered random. Numerical results of some analyses are also presented.