Mixed terrigenous—Carbonate sedimentation in the Hispaniola—Caicos turbidite basin

Sedimentation in the 9500 km², 4100 m deep Hispaniòla—Caicos Basin is dominated by turbidity currents. Carbonate turbidites originate from the Bahama Islands, Great Inagua and Caicos at the north end of the basin. Mixed carbonate—non-carbonate flows come from Hispaniola and perhaps Cuba. Most flows originate on insular slopes rather than in shallow water. The relatively low CaCO₃ content of hemipelagic sequences throughout the entire basin reveals that the influence of non-carbonate Hispaniola—Cuba sources is widespread.The basin was sampled with closely spaced piston cores. Sand-layer isopach and frequency maps reveal four or five major basin entry points for turbidity currents. Flow size is proportional to the size of source areas. Average volumes of flows originating from Hispaniola—Cuba, the largest source, are 10⁹ m³. This compares to an average flow volume of 10⁶ m³ for flows derived from the smallest source area, the Southeastern Caicos Bank. Measures of turbidity-current activity, such as thickness and frequency, change in a regular fashion away from each entry point. Average lutite thickness (combining hemipelagic and turbiditic lutite) are greatest near the basin entry points. On the abyssal plain occupying the south half of the basin, Bouma turbidite sedimentary structure sequences tend to be complete. However, on the Caicos Fan, the sedimentary structure sequences in turbidites are characterized by missing or repeated units. Six radiocarbon dates of two widespread presumed pelagic units in the basin yielded younger dates in stratigraphically older positions. The reversed dates are assumed to reflect storm erosion of older sediment on adjacent insular shelves.Consideration of a north—south reflection seismic profile over the basin indicates that the present sediment regimen has pertained through much of the Neogene. The coherence, convergence and termination of reflections in the seismic section are consistent with and tend to confirm conclusions based on the core study regarding the greater extent and volume of sediment deposits derived from the Hispaniola source area.     

Evaluation and comparison of spatial interpolators

This study evaluates 15 different estimators to determine their relative merits in estimating block concentrations at contaminant waste sites. The evaluation was based on 54 subsets of data drawn from an exhaustive set of 19,800 data. For each subset, 198 block estimates were made with each estimator. The measurements of estimation quality were a linear loss function and a more standard statistic, the mean square error. The linear loss function showed that seven of the estimators produced scores close enough to be within the same statistical population. Results based on the mean square error were similar. The surprising results of this study were that inverse distance and inverse distance squared both produced better scores than kriging.     

Glutathione-mediated chlorothalonil detoxification in channel catfish gills

Maintenance of the glutathione (GSH) pathway is critical in guarding against the toxic effects of a variety of pollutants. However, despite their importance as an initial line of defense against waterborne toxicants, little is known regarding the role of fish gills in GSH-mediated xenobiotic metabolism. In these studies, the role of channel catfish gills in the detoxification of 2,4,5,6-tetrachloroisophthalonitrile (chlorothalonil), an electrophilic fungicide, was examined. Chlorothalonil was metabolized in vitro by gill cytosolic and microsomal glutathione S-transferases (GSTs). Chlorothalonil metabolism by cytosolic fructions was reduced markedly when GSH was omitted from reaction mixtures. Microsomal metabolism of chlorothalonil did not occur in the absence of GSH and in the presence of an NADPH-regenerating system lacking GSH. Channel catfish exposed in vivo to chlorothalonil had increased gill GSH and cysteine concentrations after 72 h exposure, and increased gill gamma-glutamylcysteine synthetase (GCS) activity at 144 h of exposure. Our results show that the gills play an important role in the metabolism and detoxification of chlorothalonil in the channel catfish. Catfish can maintain elevated gill GSH concentrations in the presence of chlorothalonil by increasing gill cysteine concentrations.     

GSTA is a major glutathione S-transferase gene responsible for 4-hydroxynonenal conjugation in largemouth bass liver

We have previously shown that largemouth bass (Micropterus salmoides) has a remarkable ability to conjugate 4-hydroxy-2-nonenal (4HNE), a mutagenic and cytotoxic alpha,beta-unsaturated aldehyde produced during the peroxidation of lipids. In addition, we have isolated a glutathione S-transferase cDNA (bass GSTA) that encodes a recombinant protein which is highly active in 4HNE conjugation and structurally similar to plaice (Pleuronectes platessa) GSTA. In the present study, HPLC-GST subunit analysis revealed the presence of at least two major GST isoforms in bass liver, with one peak constituting 80% of the total bass liver GST protein. Liquid chromatography mass spectrometry (LC-MS) and electrospray ionization analysis of the major bass GST subunit yielded a molecular weight of 26,396 kDa. Endo-proteinase Lys-C digestion and Edman degradation protein sequencing of this GST peak demonstrated that this protein was encoded by bass GSTA. Analysis of genomic DNA fragments isolated by nested PCR indicated the presence of a GST gene cluster in bass liver that contained GSTA, and was similar to a GST gene cluster characterized by Leaver et al., in plaice. Collectively, our data indicates the presence of a major GST in bass liver involved in the protection against oxidative stress. This GST is part of a gene cluster that may be conserved in certain freshwater and marine fish.     

Biological disturbance and camouflage of sedimentary features on the Northeast United States slope and rise

Evidence from over 200 sediment cores, numerous submersible dives, and bottom photographs prove that bioturbation and bioerosion are ongoing processes affecting northeastern U.S. continental slope and rise sedimentation. Evidence of biological activity was found in greater than 95% of the cores examined. Submersible dive observations reveal that the results of biological activity often dominate sea-floor microtopography. Bioturbation can disturb sediments several centimeters deep in a matter of seconds and is in some areas the primary sediment transport mechanism. Many cores with sandy intervals were profoundly disturbed by bioturbation. Biologically camouflaged sand-rich intervals can easily be missed by visual observation.     

Science-based and stakeholder-driven marine protected area network planning: A successful case study from north central California

The planning process for California's Marine Life Protection Act in north central California represents a case study in the design of a regional component of a statewide network of marine protected areas (MPAs) for improved ecosystem protection. We describe enabling factors, such as a legislative mandate, political will, and adequate capacity and funding that fostered a successful planning process. We identify strategic principles that guided the design of a transparent public planning process that delivered regional MPA network proposals, which both met science guidelines and achieved a high level of support among stakeholders. We also describe key decision support elements (spatial data, planning tools, and scientific evaluation) that were essential for designing, evaluating, and refining alternative MPA network proposals and for informing decision-makers.     

Three-dimensional bounding surface architecture and lateral facies heterogeneity of a wet aeolian system: Entrada Sandstone,Utah

Aeolian deposits form noteworthy reservoirs (for example, Norphlet Formation and Rotliegend Group) in hydrocarbon extraction and carbon capture and storage contexts, but stratigraphic architecture imparts significant heterogeneity. Bounding surfaces result from autogenic and allogenic controls and can represent important changes in dune-field dynamics. To further evaluate the impacts of facies heterogeneity and flow-inhibiting bounding surfaces on reservoir performance and reconstruct ancient erg evolution, the stratigraphic architecture of aeolian systems must continue to be studied at multiple scales. This study pairs traditional methods (for example, measured stratigraphic sections) with advanced technologies (for example, drone-derived outcrop models) to precisely resolve the metre to kilometre-scale three-dimensional stratigraphic architecture of wet aeolian Middle Jurassic Entrada Sandstone outcrops located at Rone Bailey Mesa near Moab, Utah, USA. Five facies are identified, primarily based on sedimentary fabrics, and are grouped into three associations named dune, sabkha and sand sheet. Statistical analyses of gamma-ray spectrometer and automated mineralogy data indicate a distinct mineralogical difference between dune (quartz-rich) and sabkha (more feldspathic) packages, suggesting that gamma-ray logs may be used to better predict facies distribution in the subsurface. Seven modelled super bounding surfaces are planar to undulatory, with no perceived spatial trends. Five modelled interdune migration surfaces are undulatory but exhibit an average 0.09° angle of climb roughly parallel to the palaeocurrent direction. Two modelled superposition surfaces are linear to sinuous in plan-view. Laterally discontinuous sabkha packages observed are interpreted to be remnants of closed, damp, interdune flats located between ca 8.5 to 17.0 m tall, sinuous, transverse bedforms or patches of such bedforms. Based on stratigraphic architecture interpretations, the Entrada Sandstone preserves signals of allogenic forcing and localized autogenic bedform cannibalization of the substrate. The findings of this study, some of which are not commonly recognized in wet aeolian facies models, enhance the understanding of erg evolution and can parameterize static models of aeolian reservoirs.     

Power spectrum for the small-scale Universe

The first objects to arise in a cold dark matter (CDM) universe present a daunting challenge for models of structure formation. In the ultra small-scale limit, CDM structures form nearly simultaneously across a wide range of scales. Hierarchical clustering no longer provides a guiding principle for theoretical analyses and the computation time required to carry out credible simulations becomes prohibitively high. To gain insight into this problem, we perform high-resolution  ( N = 720³–1584³)  simulations of an Einstein–de Sitter cosmology where the initial power spectrum is   P ( k ) ∝ k ⁿ ,  with  −2.5 ≤ n ≤− 1  . Self-similar scaling is established for   n =−1  and −2 more convincingly than in previous, lower resolution simulations and for the first time, self-similar scaling is established for an   n =−2.25  simulation. However, finite box-size effects induce departures from self-similar scaling in our   n =−2.5  simulation. We compare our results with the predictions for the power spectrum from (one-loop) perturbation theory and demonstrate that the renormalization group approach suggested by McDonald improves perturbation theory's ability to predict the power spectrum in the quasi-linear regime. In the non-linear regime, our power spectra differ significantly from the widely used fitting formulae of Peacock & Dodds and Smith et al. and a new fitting formula is presented. Implications of our results for the stable clustering hypothesis versus halo model debate are discussed. Our power spectra are inconsistent with predictions of the stable clustering hypothesis in the high- k limit and lend credence to the halo model. Nevertheless, the fitting formula advocated in this paper is purely empirical and not derived from a specific formulation of the halo model.