Advanced frame element for seismic analysis of masonry structures: model formulation and validation

This paper presents a masonry panel model for the nonlinear static and dynamic analysis of masonry buildings suitable for the seismic assessment of new and existing structures. The model is based on an equivalent frame idealization of the structure and stems from previous research on force‐based frame elements. The element formulation considers axial, bending, and shear deformations within the framework of the Timoshenko beam theory. A phenomenological cyclic section law that accounts for the shear panel response is coupled, through equilibrium between shear and bending forces along the element, with a fiber‐section model that accounts for the axial and bending responses. The proposed panel model traces with a low computational burden and numerical stability the main aspects of the structural behavior of masonry panels and is suitable for analyses of multi‐floor buildings with a relatively regular distribution of openings and with walls and floors organized to grant a box‐like behavior under seismic loads. The model capabilities are validated though analyses of simple unreinforced masonry panels and comparisons with published experimental results. The model accuracy is strongly dependent on the fiber and shear constitutive laws used. However, the formulation is general, and laws different from those employed in this study are easily introduced without affecting the model formulation. Copyright © 2015 John Wiley & Sons, Ltd.     

Melts of garnet lherzolite: experiments, models and comparison to melts of pyroxenite and carbonated lherzolite

Phase equilibrium experiments on a compositionally modified olivine leucitite from the Tibetan plateau have been carried out from 2.2 to 2.8 GPa and 1,380–1,480 °C. The experiments-produced liquids multiply saturated with spinel and garnet lherzolite phase assemblages (olivine, orthopyroxene, clinopyroxene and spinel ± garnet) under nominally anhydrous conditions. These SiO₂-undersaturated liquids and published experimental data are utilized to develop a predictive model for garnet lherzolite melting of compositionally variable mantle under anhydrous conditions over the pressure range of 1.9–6 GPa. The model estimates the major element compositions of garnet-saturated melts for a range of mantle lherzolite compositions and predicts the conditions of the spinel to garnet lherzolite phase transition for natural peridotite compositions at above-solidus temperatures and pressures. We compare our predicted garnet lherzolite melts to those of pyroxenite and carbonated lherzolite and develop criteria for distinguishing among melts of these different source types. We also use the model in conjunction with a published predictive model for plagioclase and spinel lherzolite to characterize the differences in major element composition for melts in the plagioclase, spinel and garnet facies and develop tests to distinguish between melts of these three lherzolite facies based on major elements. The model is applied to understand the source materials and conditions of melting for high-K lavas erupted in the Tibetan plateau, basanite–nephelinite lavas erupted early in the evolution of Kilauea volcano, Hawaii, as well as younger tholeiitic to alkali lavas from Kilauea.     

Deformation at the eastern margin of the Northern Canadian Cordillera: Potentially related to opening of the North Atlantic

The Northern Canadian Cordillera (NCC) comprises the Mackenzie Mountains, which are characterized by earthquakes occurring ~1,000 km east of the western North American margin. However, no recognized convergence has occurred in this inboard region since the Mesozoic to early Cenozoic formation of the Cordillera. This lack of an obvious driver for the modern NCC deformation has generated considerable debate and various geodynamic models. We show here thermal histories derived from (U‐Th‐Sm)/He data that are interpreted to indicate reactivated deformation and formation of the eastern deformation front beginning ~30 Ma. At that time the western margin of North America was mainly a transform boundary, which typically transmits very limited amount of stress into the continent. Along the northeastern margin of North America, however, the North Atlantic was opening and may have caused horizontal forces that drove deformation far to the west where the rigid craton encountered the weak Cordillera.     

CH4/N2/H2-spark hydrophobic tholins: A systematic approach to the characterisation of tholins. Part II

Two different simulation experiments of prebiotic synthesis were carried out in a CH₄/N₂/H₂ atmosphere with spark discharge activation of aqueous aerosols and liquid water. In both cases, a hydrophilic tholin and a hydrophobic tholin were obtained. The methodology developed by our group for the characterisation of hydrophilic tholins [Ruiz-Bermejo, M., Menor-Salván, C., Mateo-Martí, E., Osuna-Esteban, S., Martín-Gago, J.A., Veintemillas-Verdaguer, S., 2008. Icarus 198, 232-241] was used in order to study the hydrophobic tholins. The gas precursors of the tholins from mixtures containing CH₄, with and without H₂, were studied. We propose that the formation of the hydrophobic tholins involves the formation of unsaturated oligomeric hydrocarbon chains from vinyl and acetylene monomers, as well as allene derivatives formed in the gas phase after the incorporation of polar groups into these hydrocarbon chains. Finally, we compare our results concerning hydrophobic tholins with HCN polymers, since it is generally suggested that the polymeric material formed in spark experiments are possible oligomers of HCN, and that Titan’s tholins could be poly-HCN.     

Soil formation in Phobjikha Valley,Central Bhutan with special regard to the redistribution of loessic sediments

Soil development and landscape evolution were studied in the basin-shaped Phobjikha Valley at 2900–3200 m a.s.l., to the west of the Black Mountain Range, West Central Bhutan. The local environmental setting with strong along-valley winds, frequent freeze–thaw cycles, extensive dry periods and sparse vegetation cover seems to encourage the generation and short-distance transport of silt-sized particles. The effects of this process are evidenced in the smooth valley morphology and in the nature of the examined pedons. Their involvement in continuing redistribution of local sediments is reflected by a homogeneous silty-clayey and stone-free texture, varying profile depths, buried topsoils and weakly developed recent A horizons. In protected locations, in situ weathering of metamorphic parent materials results in alu-andic features with bulk densities <0.9 g cm^?3, (Al_o + ½Fe_o) > 2%, and phosphate retention >95%. Dominance by Al-hydroxy interlayered clay minerals and large amounts of well-crystallised iron oxides indicate an advanced stage of weathering. In areas of preferred eolian deposition, argic and ferralic features emerge, with clay contents of up to 60% and surface areas of >50 m² g^?1. Under forest, umbric horizons can develop. CEC_eff is below 10 cmol_c kg^?1 at all sites. Cluster and factor analyses of soil chemical and physical parameters confirm the redistribution of local sediments as a dominant factor behind the measured variables. No clear indication of glacial activities in the area was found, whereas the massive silty sediments in the lower parts of most profiles, the presence of debris slopes, and the asymmetric cross sections of the side valleys suggest periglacial conditions. Buried topsoils dated at about 2000 conventional ¹⁴C years BP indicate a weakening or absence of sediment influx under wetter conditions towards the end of the Holocene climate optimum. Charcoal on top of paleosols suggests that human activities of deforestation, grazing and arable agriculture may have contributed to the reactivation of local sediment redistribution until today.     

Regolith mass balance inferred from combined mineralogical, geochemical and geophysical studies: Mule Hole gneissic watershed, South India

The aim of this study is to propose a method to assess the long-term chemical weathering mass balance for a regolith developed on a heterogeneous silicate substratum at the small experimental watershed scale by adopting a combined approach of geophysics, geochemistry and mineralogy. We initiated in 2003 a study of the steep climatic gradient and associated geomorphologic features of the edge of the rifted continental passive margin of the Karnataka Plateau, Peninsular India. In the transition sub-humid zone of this climatic gradient we have studied the pristine forested small watershed of Mule Hole (4.3 km²) mainly developed on gneissic substratum. Mineralogical, geochemical and geophysical investigations were carried out (i) in characteristic red soil profiles and (ii) in boreholes up to 60 m deep in order to take into account the effect of the weathering mantle roots. In addition, 12 Electrical Resistivity Tomography profiles (ERT), with an investigation depth of 30 m, were generated at the watershed scale to spatially characterize the information gathered in boreholes and soil profiles. The location of the ERT profiles is based on a previous electromagnetic survey, with an investigation depth of about 6 m. The soil cover thickness was inferred from the electromagnetic survey combined with a geological/pedological survey.Taking into account the parent rock heterogeneity, the degree of weathering of each of the regolith samples has been defined using both the mineralogical composition and the geochemical indices (Loss on Ignition, Weathering Index of Parker, Chemical Index of Alteration). Comparing these indices with electrical resistivity logs, it has been found that a value of 400 Ohm m delineates clearly the parent rocks and the weathered materials. Then the 12 inverted ERT profiles were constrained with this value after verifying the uncertainty due to the inversion procedure. Synthetic models based on the field data were used for this purpose. The estimated average regolith thickness at the watershed scale is 17.2 m, including 15.2 m of saprolite and 2 m of soil cover.Finally, using these estimations of the thicknesses, the long-term mass balance is calculated for the average gneiss-derived saprolite and red soil. In the saprolite, the open-system mass-transport function τ indicates that all the major elements except Ca are depleted. The chlorite and biotite crystals, the chief sources for Mg (95%), Fe (84%), Mn (86%) and K (57%, biotite only), are the first to undergo weathering and the oligoclase crystals are relatively intact within the saprolite with a loss of only 18%. The Ca accumulation can be attributed to the precipitation of CaCO₃ from the percolating solution due to the current and/or the paleoclimatic conditions. Overall, the most important losses occur for Si, Mg and Na with −286 × 10⁶ mol/ha (62% of the total mass loss), −67 × 10⁶ mol/ha (15% of the total mass loss) and −39 × 10⁶ mol/ha (9% of the total mass loss), respectively. Al, Fe and K account for 7%, 4% and 3% of the total mass loss, respectively. In the red soil profiles, the open-system mass-transport functions point out that all major elements except Mn are depleted. Most of the oligoclase crystals have broken down with a loss of 90%. The most important losses occur for Si, Na and Mg with −55 × 10⁶ mol/ha (47% of the total mass loss), −22 × 10⁶ mol/ha (19% of the total mass loss) and −16 × 10⁶ mol/ha (14% of the total mass loss), respectively. Ca, Al, K and Fe account for 8%, 6%, 4% and 2% of the total mass loss, respectively.Overall these findings confirm the immaturity of the saprolite at the watershed scale. The soil profiles are more evolved than saprolite but still contain primary minerals that can further undergo weathering and hence consume atmospheric CO₂.     

Recovery of Normal Cytogenetic Records in Mussels After Cessation of Pollutant Effluents in Puerto Madryn (Patagonia,Argentina)

The capacity of coast recovering after interruption of pollution sources has been explored employing mussels as biomarkers. In an area polluted by sewage sludge in Puerto Madryn (Argentina), abnormally high cytogenetic records (micronuclei) had been detected in the mussel Mytilus edulis, even higher than those obtained in this and other mussel species (Brachydontes rodriguezi, Aulacomya atra atra, Perumytilus purpuratus) sampled from heavily polluted industrial areas, and much higher than those recorded in samples from unpolluted areas of the same region. Normal cytogenetic patterns were recovered in Puerto Madryn less than 1 year after cessation of sewage sludge discharges, without additional treatment of the affected area. This discovery opens the possibility of considering restored coastal areas for aquaculture purposes instead of endangering natural populations in virgin areas.     

GRIDA3—a shared resources manager for environmental data analysis and applications

GRIDA3 (Shared Resources Manager for Environmental Data Analysis and Applications) is a multidisciplinary project designed to deliver an integrated system to forge solutions to some environmental challenges such as the constant increase of polluted sites, the sustainability of natural resources usage and the forecast of extreme meteorological events. The GRIDA3 portal is mainly based on Web 2.0 technologies and EnginFrame framework. The portal, now at an advanced stage of development, provides end-users with intuitive Web-interfaces and tools that simplify job submission to the underneath computing resources. The framework manages the user authentication and authorization, then controls the action and job execution into the grid computing environment, collects the results and transforms them into an useful format on the client side. The GRIDA3 Portal framework will provide a problem-solving platform allowing, through appropriate access policies, the integration and the sharing of skills, resources and tools located at multiple sites across federated domains.     

Development of methods to collect and analyze gasoline range (C5–C12) hydrocarbons from seabed sediments as indicators of subsurface hydrocarbon generation and entrapment

Gasoline range hydrocarbons (C₅–C₁₂) are usually associated with petroleum generation, yet few surface geochemical surveys have attempted to evaluate the gasoline range hydrocarbons in near-surface marine sediments. This is due to the difficulty in capturing and analyzing this volatile range of hydrocarbons with minimum loss and evaporative fractionation. In this study, a Headspace Solid Phase Microextraction (HSPME) method was developed and evaluated for the purpose of capturing the gasoline range of hydrocarbons within unconsolidated sediment using a solventless protocol.