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171.
Estimation of bioavailability of polycyclic aromatic hydrocarbons in river sediments 总被引:2,自引:2,他引:0
S. Froehner L. F. Dombroski K. S. Machado C. Scapulatempo Fernandes M. Bessa 《International Journal of Environmental Science and Technology》2012,9(3):409-416
This study aimed to evaluate the total concentration of polycyclic aromatic hydrocarbons in sediments of Iguassu River in Southern Brazil. Alongside the concentration, the amount of such compounds bioavailable was also evaluated. This is accomplished by comparing its total amount present in sediments and the amount extracted by n-butanol. The results showed that the total concentration of polycyclic aromatic hydrocarbons presented in sediment ranged from 4.49 to 58.75???g/g. The total amount of polycyclic aromatic hydrocarbons extracted by n-butanol ranged from 1.22 to 17.07???g/g. The use of n-butanol represents the mimetic conditions that hydrocarbons, derived from oil, could be taken up by organisms. Most of the hydrocarbons extracted by n-butanol were those with lower octanol?Cwater partition constant, usually those with three and four rings. Compounds with more than four rings were extracted in lower or insignificant amounts. Even the hydrocarbons with lower molecular weight available may be degraded or eliminated by organisms, when accumulated. Estimating bioavailability of hydrocarbons represents what specific hydrocarbons could be available to be taken up by organisms. 相似文献
172.
The Biomass Expansion Factor (BEF) and the Root-to-Shoot Ratio (R) are variables used to quantify carbon stock in forests.
They are often considered as constant or species/area specific values in most studies. This study aimed at showing tree size
and age dependence upon BEF and R and proposed equations to improve forest biomass and carbon stock. Data from 70 sample Pinus spp. grown in southern Brazil trees in different diameter classes and ages were used to demonstrate the correlation between
BEF and R, and forest inventory data, such as DBH, tree height and age. Total dry biomass, carbon stock and CO2 equivalent were simulated using the IPCC default values of BEF and R, corresponding average calculated from data used in
this study, as well as the values estimated by regression equations. The mean values of BEF and R calculated in this study
were 1.47 and 0.17, respectively. The relationship between BEF and R and the tree measurement variables were inversely related
with negative exponential behavior. Simulations indicated that use of fixed values of BEF and R, either IPCC default or current
average data, may lead to unreliable estimates of carbon stock inventories and CDM projects. It was concluded that accounting
for the variations in BEF and R and using regression equations to relate them to DBH, tree height and age, is fundamental
in obtaining reliable estimates of forest tree biomass, carbon sink and CO2 equivalent. 相似文献
173.
Cardoso I Pais MP Henriques S da Fonseca LC Cabral HN 《Marine pollution bulletin》2011,62(5):992-1001
The importance of establishing the ecological quality of estuarine systems has been widely acknowledged and led to the development of several fish community-based multimetric indices. Nevertheless, a question rose about the accuracy of these tools when natural disturbance is acting upon the organization of the systems’ communities. Four multimetric indices were used to examine their ability to differentiate the ecological status of five small estuarine systems (southern Portugal), and also to test if they reflected the level of anthropogenic pressures. Fish assemblages from Mira, Odeceixe and Aljezur (in the Southwest coast), Gilão and Bensafrim (in the South coast) estuaries were sampled seasonally for one year, and anthropogenic sources of pressure were identified and quantified. We found that although the applied indices provided information on ecological condition differentiation among systems, they are unable to explain different classes of ecological status in systems with equivalent pressure levels. 相似文献
174.
Santos RG Martins AS Farias Jda N Horta PA Pinheiro HT Torezani E Baptistotte C Seminoff JA Balazs GH Work TM 《Marine pollution bulletin》2011,62(6):1297-1302
To show the influence of coastal habitat degradation on the availability of food for green turtles (Chelonia mydas), we assessed the dietary preferences and macroalgae community at a feeding area in a highly urbanized region. The area showed low species richness and was classified as degraded. We examined stomach contents of 15 dead stranded turtles (CCL = 44.0 cm (SD 6.7 cm)). The diet was composed primarily of green algae Ulva spp. (83.6%). In contrast, the macroalgae community was dominated by the green alga Caulerpa mexicana. We found a selection for red algae, seagrass and Ulva spp., and avoidance for C. mexicana and brown alga Dictyopteris delicatula. The low diversity of available food items, possibly a result of environmental degradation, likely contributed to the low dietary diversity. The nutritional implications of this restricted diet are unclear. 相似文献
175.
Costa PM Caeiro S Lobo J Martins M Ferreira AM Caetano M Vale C DelValls TÁ Costa MH 《Marine pollution bulletin》2011,62(1):55-65
Juvenile Senegalese soles were exposed through 28-day laboratory and field (in situ) bioassays to sediments from three sites of the Sado estuary (W Portugal): a reference and two contaminated by metallic and organic contaminants. Fish were surveyed for ten hepatic histopathological alterations divided by four distinct reaction patterns and integrated through the estimation of individual histopathological condition indices. Fish exposed to contaminated sediments sustained more damage, with especial respect to regressive changes like necrosis. However, differences were observed between laboratory- and field-exposed animals, with the latest, for instance, exhibiting more pronounced fatty degeneration and hepatocellular eosinophilic alteration. Also, some lesions in fish exposed to the reference sediment indicate that in both assays unaccounted variables produced experimental background noise, such as hyaline degeneration in laboratory-exposed fish. Still, the field assays yielded results that were found to better reflect the overall levels of contaminants and physico-chemical characteristics of the tested sediments. 相似文献
176.
Alfredo Alberto Muxel Sonia Maria Nobre Gimenez Flaveli Aparecida de Souza Almeida Rení Ventura da Silva Alfaya Antonio Alberto da Silva Alfaya 《洁净——土壤、空气、水》2011,39(3):289-295
The natural cotton fiber was used to synthesize an anion exchange, containing ZrO2 film on its surface, NCFZC (natural cotton fiber/ZrO2 composite). This anion exchanger was produced by the reaction of the zirconium oxychloride and hydroxyl groups on surface of the natural cotton fiber. The material was used for Cr(VI) ions adsorption studies. Adsorption equilibrium time and optimum pH for Cr(VI) adsorption were found to be 6 h and 4.0, respectively. The Langmuir and Temkin isotherms were used to models adsorption equilibrium data. The adsorption capacity of NCFZC was found to be 1.33 mmol/g. Kinetic studies showed that the rate of adsorption of Cr(VI) on NCFZC obeyed a pseudo‐second‐order kinetic model. 相似文献
177.
A. Prestes N.R. Rigozo D.J.R. Nordemann C.M. Wrasse M.P. Souza Echer E. Echer M.B. da Rosa P.H. Rampelotto 《Journal of Atmospheric and Solar》2011,73(11-12):1587-1593
This study of Sun–Earth relationships is based on tree growth rings analysis of araucarias (Araucaria angustifolia) collected at Severiano de Almeida (RS) Brazil. A chronology of 359 years was obtained, and the classical method of spectral analysis by iterative regression and wavelet method was applied to find periodicities and trends contained in the tree growth. The analysis of the dendrochronological series indicates representative periods of solar activity of 11 (Schwabe cycle), 22 (Hale cycle), and 80 (Gleissberg cycle) years. The result shows the possible influence of the solar activity on tree growth in the last 350 years. Periods of 2–7 years were also found and could represent a response of the trees to local climatic conditions. Good agreement between the time series of tree growth rings and the 11 year solar cycle was found during the maximum solar activity periods. 相似文献
178.
E. Costa E. Echer M.V. Alves B.T. Tsurutani F.J.R. Simões F.R. Cardoso G.S. Lakhina 《Journal of Atmospheric and Solar》2011,73(11-12):1405-1409
We present a new method of calculating cross-field diffusion of charged particles due to their interactions with interplanetary magnetic decreases (MDs) in high heliospheric latitudes. We use a geometric model that evaluates perpendicular diffusion to the ambient magnetic field as a function of particle's gyroradius, MD radius, ratio between fields outside and inside the MD, and a random impact parameter. We use Ulysses magnetic field data of 1994 to identify the MDs and get the empirical size and magnetic field decrease distribution functions. We let protons with energies ranging from 100 keV to 2 MeV interact with MDs. The MD characteristics are taken from the observational distribution functions using the Monte Carlo method. Calculations show that the increase in diffusion tends to saturate when particles' gyroradius becomes as large as MD radii, and that particles' gyroradius increases faster than diffusion distance as the energy of the particles is increased. 相似文献
179.
A temporary accelerometer network has been installed in Tarcento (Friuli, NE Italy), a small town heavily hit by the 1976–1977
Friuli earthquake sequence, as a part of an ongoing research project aimed at ground motion simulation and generation of shakemaps
in the near-field of an earthquake. The network operated from October 2008 to April 2010 and consisted of three K2 accelerographs
with internal Episensor, distributed over a linear array of about 1.5 km length. Tarcento town had been chosen, at the end
of the 1970s, as the ideal site for a pilot microzonation study, the first of this kind in Italy, in which a substantial number
of field (and laboratory) tests were carried out in order to assess the mechanical properties of local alluvium deposits and
their complex (3D) geometrical configuration. The data from the temporary network, illustrated herein, allow for proper verification
and review of some of the quantitative predictions formulated in the 1980 study. As argued in the discussion section, we also
believe that the data are apt to provide valuable information of more general interest on the complex seismic response of
alluvium-filled valleys, and we show therein how the observations can be interpreted in the light of presently available parametric
simulation studies and simplified criteria for handling basin amplification effects. 相似文献
180.
Andrew M. Moore Hernan G. ArangoGregoire Broquet Chris EdwardsMilena Veneziani Brian PowellDave Foley James D. DoyleDan Costa Patrick Robinson 《Progress in Oceanography》2011,91(1):50-73
The Regional Ocean Modeling System (ROMS) 4-dimensional variational (4D-Var) data assimilation systems have been systematically applied to the mesoscale circulation environment of the California Current to demonstrate the performance and practical utility of the various components of ROMS 4D-Var. In particular, we present a comparison of three approaches to 4D-Var, namely: the primal formulation of the incremental strong constraint approach; the dual formulation “physical-space statistical analysis system”; and the dual formulation indirect representer approach. In agreement with theoretical considerations all three approaches converge to the same ocean circulation estimate when using the same observations and prior information. However, the rate of convergence of the dual formulation was found to be inferior to that of the primal formulation. Other aspects of the 4D-Var performance that relate to the use of multiple outer-loops, preconditioning, and the weak constraint are also explored. A systematic evaluation of the impact of the various components of the 4D-Var control vector (i.e. the initial conditions, surface forcing and open boundary conditions) is also presented. It is shown that correcting for uncertainties in the model initial conditions exerts the largest influence on the ability of the model to fit the available observations. Various important diagnostics of 4D-Var are also examined, including estimates of the posterior error, the information content of the observation array, and innovation-based consistency checks on the prior error assumptions. Using these diagnostic tools, we find that more than 90% of the observations assimilated into the model provide redundant information. This is a symptom of the large percentage of satellite data that are used and to some extent the nature of the data processing employed. This is the second in a series of three papers describing the ROMS 4D-Var systems. 相似文献