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Galvanic interactions between galena–sphalerite and their reactivity

The galvanic effect between the main associated mineralogical phases in a mineral sphalerite concentrate was evaluated using an alternative methodology. Comparative voltammetric studies were performed between high purity galena mineral (94.65%) and sphalerite concentrate (content of 78.11% sphalerite, ZnS; 13.64% galena, PbS; 0.57% chalcopyrite, CuFeS₂; 0.41% cadmium sulfide, CdS; and 0.11% arsenopyrite, FeAsS) using carbon paste electrodes (CPE) in order to identify galvanic interactions that affect their reactivity. The electrolyte was an aqueous solution of 0.1 M NaNO₃ (pH 6.5). The results showed that, in sphalerite concentrate, the electrochemical reactivity of the galena was diminished and displaced to more positive potentials with respect to the high purity galena mineral response. This behavior can be attributed to the galvanic protection offered by the sphalerite on the galena, thereby avoiding its free oxidation. On the other hand, sphalerite oxidation was diminished by the formation of a passive products film that is dissolved to more positive potentials which provokes oxidation of other minerals like CuFeS₂, (Zn,Cd)S and FeAsS present in a minor proportion in the sphalerite concentrate.     

A MASCOTTE-based characterization of MCSs over Spain, 2000–2002

A 3-year Mesoscale Convective Systems (MCSs) database, which extends from 2000 to 2002, has been built for the Iberian Peninsula and the Balearic Islands using the objective method MASCOTTE (MAximum Spatial COrrelation Technique). It was originally developed to track the evolution of convective systems over the Amazon region; after modifications, it is able to track MCS evolution even with an hour and a half of missed images and provides essential information of both dynamical and morphological characteristics of MCSs. MASCOTTE is tested against a visual and subjective method, and is found to offer advantages such as automation and a simple and efficient operation that make it very useful for building large MCS databases.Thirty-five MCSs were found between June and October, most of them originated along the Mediterranean coast and near the Pyrenees, showing an increasing occurrence from June to September, when the maximum is found. The regions most influenced by MCS occurrences are Balearic Islands, Valencia, Catalonia, Murcia and the Basque Country. The MCSs tend to be small, short-lived and linear, usually moving eastward or northeastward with low velocities.The MCSs-associated precipitation presents high variability, ranging from 80 to 0 mm h⁻¹ as maximum hourly records. Two different convective regions are identified based on MCS behavior in extreme precipitation events: Northern Spain (the Basque Country) with abundant and continuous precipitation regime but little MCS influence, and the Mediterranean coast, where precipitation is sporadic but much more intense.     

Relation between the monthly sums of sunshine and global radiation

Summary The statistical treatment of the dependence of monthly sums of global radiation on the monthly sums of sunshine at the stations of Hradec Králové, Bratislava — Koliba and Hurbanovo is presented. The parameters of linear and quadratic regression are derived for the said stations and for the individual months of the year. Drawing on the statistical analysis of the initial data sets, the accuracy and reliability of the mentioned regression relations are critically evaluated.     

Evolution microtectonique et paléo-champs de contraintes du Bassin de Vienne

Résumé

Une étude des structures cassantes permet de préciser l’évolution tectonique du Bassin de Vienne, généralement considéré comme un bassin de type « pull apart » typique. Le champ de contrainte ottnangien-carpathien (18,5-16, 5 Ma) est caractérisé par une compression NNW-SSE. Pendant le Badénien-Sannanticn (16,5-11 Ma) une zone cisaillante sénestre de direction NE-SW a été formée dans un régime en compression N-S et extension E-W. En liaison avec cette zone décrochante trois types d’extension locale conduisent à une forte subsidence dans les dépression : extension NE-SW parallèle aux accidents sénestres, extension E-W entre les décrochements et extension NW-SE au-dessus des zones décrochantes profondes. Le champ de contrainte vers la fin du Sannaticn est marqué par une compression ENE-WSW, tandis que celui du Pannonicn- récent est similaire á celui du Miocène moyen.

Une rotation de la paléocontrainte maximale horizontale, de NNW-SSE a ENE-SSW est mise en évidence pendant la période Ottnangien-Sannantien (18,5-11 Ma). Cette rotation est parallèle A celle des directions de mise en place des nappes carpathicnnes externes. L’origine des rotation est l’échappement continental des Alpes orientales et des Carpathes septentrionales vers le NE et son blocage graduel d’Ouest en Est au front des nappes carpathiennes. Après ce blocage, l’échappement a continué avec une faible intensité du Pannonien à l’Actuel. Alors que l’échappement a été initié par une compression N-S due á la collision Europe-promontoire Adriatique, le champ de contrainte à l’intérieur des blocs échappés reflète l’effet de leur blocage au front des nappes carpalhiques.     

Hydrological and meteorological extremes derived from taxation records: the estates of Brtnice,Třebíč and Velké Meziříčí, 1706–1849

Abstract

This paper addresses the hydrological and meteorological extremes that may be deduced from the taxation records of the estates of Brtnice, T?ebí? and Velké Mezi?í?í, all in the Moravian-Bohemian Highlands of the Czech Republic, for the years 1706–1849. At that time, damage to agricultural crops constituted grounds for tax remission for individual farmers and landowners. Where it survives, the relevant administrative documentation generally includes a statement from the applicant, a report by the official commission tasked with checking the contents of it, and any decisions made by taxation authorities at regional and “land” level (the Jihlava regional office and the Moravian Land Administration (“Gubernium”) respectively). Data extracted may include the type of event, dating, places of occurrence and damage done. The chronology of hydrological and meteorological extremes (torrential rain, flash flood, flood, hailstorm, lightning, frost) covers the period 1706–1849, but only four events are evident before 1748 and there is a gap in records between 1757 and 1789. Extremes are analysed from a spatio-temporal point of view. A total of 97 extreme events (171 extremes of particular type) were identified for the region studied. Torrential rain, hailstorm and flash flood were the major devastating phenomena, and occurred mainly from May to August. Torrential rain and hailstorm are clearly attributable to thunderstorms with very intense convection. Five outstanding events and their impacts upon individual farmers are described in detail. The results are discussed with respect to uncertainties in the basic data and in the context of the Czech Lands, because only some of the extremes disclosed are known and confirmed by other documentary data.

Editor Z.W. Kundzewicz

Citation Dolák, L., Brázdil, R., and Valá?ek, H., 2013. Hydrological and meteorological extremes derived from taxation records: the estates of Brtnice, T?ebí? and Velké Mezi?í?í, 1706–1849. Hydrological Sciences Journal, 58 (8), 1620–1634.     

Source parameters for the 2013–2015 earthquake sequence in Nógrád county,Hungary

Between 2013 June and 2015 January, 35 earthquakes with local magnitude M _L ranging from 1.1 to 4.2 occurred in Nógrád county, Hungary. This earthquake sequence represents above average seismic activity in the region and is the first one that was recorded by a significant number of three-component digital seismographs in the county. Using a Bayesian multiple-event location algorithm, we have estimated the hypocenters of 30 earthquakes with M _L ≥1.5. The events occurred in two small regions of a few squared kilometers: one to the east of Érsekvadkert and the other at Iliny. The uncertainty of the epicenters is about 1.5–1.7 km in the E-W direction and 1.8–2.1 km in the N-S direction at the 95 % confidence level. The estimated event depths are confined to the upper 3 km of the crust. We have successfully estimated the full moment tensors of 4 M _w ≥3.6 earthquakes using a probabilistic waveform inversion procedure. The non-double-couple components of the retrieved moment tensor solutions are statistically insignificant. The negligible amount of the isotropic component implies the tectonic nature of the investigated events. All of the analyzed earthquakes have strike-slip mechanism with either right-lateral slip on an approximately N-S striking or left-lateral movement on a roughly E-W striking nodal plane. The orientations of the obtained focal mechanisms are in good agreement with the main stress pattern published for the epicentral region. Both the P and T principal axes are horizontal, and the P axis is oriented along a NE-SW direction.     

Peralkaline acid tendencies in Gran Canaria (Canary Islands)

The study of a volcanic series from the island of Gran Canaria (Canary Islands) in which alkaline and peralkaline, saturated and undersaturated rocks coexist, is reported here. Materials with high volatile content (ignimbritic trachytes) were first emitted and the series ended with the eruption of phonolitic lavas. The average peralkalinity index in these rocks is typically about 1.0 and, therefore, peralkaline rocks coexist with non-peralkaline ones. However, a maximum in peralkalinity is found in the ignimbritic rocks of the lower part of the series. In spite of the evident acid peralkaline tendencies of these rocks, it does not seem appropriate to classify them as pantellerites or comendites. Nor are they consistent with the genetic processes proposed for rocks of similar composition and oceanic environment.The crystallization of the feldspars controls the variation trends among the different magmas but the fractionation alone does not sufficiently explain the genesis of successive fluids. Various factors seem to point to the important role which a gas-transfer process causing a geochemical stratification inside the magmatic chamber may have played.The occurrence of peralkaline silicics at Gran Canaria, which is located for away from the active Mid-Atlantic ridge, is not related to transitional basalts. These rocks are a deviation from the main undersaturated alkalic trend which characterizes the volcanism of the Canary Islands, their genesis being related to the realization of favourable local volcanic conditions.     

Generalized plasticity state parameter‐based model for saturated and unsaturated soils. Part 1: Saturated state

The behavior of granular materials is known to depend on its loose or dense nature, which in turns depends both on density and confining pressure. Many models developed in the past require the use of different sets of constitutive parameters for the same material under different confining pressures. The purpose of this paper is to extend a basic generalized plasticity model for sands proposed by Pastor, Zienkiewicz and Chan by modifying the main ingredients of the model flow—rule, loading–unloading discriminating direction and plastic modulus—to include a dependency on the state parameter. The proposed model is tested against the available experimental data on three different sands, using for each of them a single set of material parameters, finding a reasonably good agreement between experiments and predictions. Copyright © 2010 John Wiley & Sons, Ltd.