Surface-water quality for the Salí River watershed in NW Argentina

Spatial and temporal variations of Na, Mg, Si, K, Ca, SO₄^2-, Cl^-, HCO₃^-, Ag, Al, As, Au, B, Ba, Be, Bi, Br, Ce, Cd, Co, Cr, Cs, Cu, Dy, Er, Eu, F, Fe, Ga, Ge, Gd, Hf, Hg, Ho, I, La, Li, Mn, Mo, Nb, Nd, Ni, P, Pb, Pr, Rb, Sb, Sm, Sn, Sr, Ta, Tb, Te, Th, Ti, Tl, U, V, W, Y, Yb, Zn, and Zr were monitored through 37 sampling stations to determine the main aspects influencing the surface-water quality in the Salí River watershed (Tucumán Province, NW Argentina). The influence of the regional geological setting on water chemistry allows to distinguish three sub-basins. The interaction with sedimentary rocks was found to be dominant in the northern and central-eastern sub-basin as well as in the southern sub-basin, whereas the metamorphic-granitic basement of the Pampean Ranges was noted in the central sub-basin. In addition, anthropogenic activities affect the spatial variation of K, P, Mn, Rb, and Pb as well as dissolved oxygen concentrations and Eh. Temporal water-quality variation is related to the spatial distribution of precipitation and to the seasonal character of the main local industries (sugar cane, alcohol, citrus), increasing P and K concentrations and decreasing dissolved oxygen concentration and Eh in winter. Cl^-, Na, SO₄^2-, Al, As, B, Fe, Mn, Se and U concentrations exceed the regulated drinking-water thresholds at several sampling stations.     

Petrogenesis of the mafic igneous rocks of the Betic Cordilleras: A field, petrological and geochemical study

Mafic igneous rocks are widespread in the Nevado-Filábride Complex, the lowermost metamorphic unit of the internal zones of the Betic Cordilleras. They form intrusive, small, discontinuous bodies, predominantly dikes with subordinate small lava flows. The entire complex underwent alpine compressional metamorphism during the Paleogene continental collision, resulting in eclogites and blueschists in the mafic bodies and high-pressure assemblages in the intruded metasediments. Locally, weakly metamorphosed or completely unmetamorphosed igneous rocks with the same textural features occur as patches surrounded by eclogitized igneous rocks. The bulk rock chemistry of unmetamorphosed and completely metamorphosed mafic igneous rocks is consistent with an alkaline to transitional tholeiitic magmatism with typical within-plate geochemical characteristics. All but a few samples are nepheline normative and display REE and trace element characteristics typical of continental, rift-related magmatism. This conclusion is strongly supported by the mineral chemistry of the major constituents, in particular the calcic Ti-rich character of clinopyroxene, the lack of orthopyroxene, and the occurrence of kaersutitic amphibole. Incompatible trace element abundances and Sr and Nd isotopes support the provenance of these magmas from a variably metasomatized previously depleted sub-continental lithospheric mantle source. Received: 5 July 1999 / Accepted: 28 February 2000     

A comparative study of geothermal and meteorological records of climate change in Kamchatka

To reconstruct the recent climate history in Kamchatka, a series of repeated precise temperature logs were performed in a number of boreholes located in a broad east-west strip (between 52 and 54°N) in the central part of Kamchatka west of Petropavlovsk-Kamchatski. Within three years more than 30 temperature logs were performed in 10 holes (one up to six logs per hole) to the depth of up to 400 metres. Measured temperature gradients varied in a broad interval 0 to 60 mK/m and in some holes a sizeable variation in the subsurface temperatures due to advective heat transport by underground water was observed. Measured data were compared with older temperature profiles obtained in the early eighties by Sugrobov and Yanovsky (1993). Even when older data are of poorer precision (accuracy of about 0.1 K), they presented valuable information of the subsurface temperature conditions existing 20–25 years ago. Borehole observations and the inverted ground surface temperature histories (GSTHs) used for the paleoclimate reconstruction were complemented with a detailed survey of meteorological data. Namely, the long-term surface air temperature (SAT) and precipitation records from Petropavlovsk station (in operation since 1890) were used together with similar data from a number of local subsidiary meteo-stations operating in Central Kamchatka since 1950. Regardless of extreme complexity of the local meteorological/climate conditions, diversity of borehole sites and calibration of measuring devices used during the whole campaign, the results of the climate reconstruction supported a general warming of about 1 K characteristic for the 20th century, which followed an inexpressive cooler period typical for the most of the 19th century. In the last three to four decades the warming rate has been locally increasing up to 0.02 K/year. It was also shown that the snow cover played a dominant role in the penetration of the climate “signal” to depth and could considerably smooth down the subsurface response to the changes occurred on the surface.     

Can origin of the 2400-year cycle of solar activity be caused by solar inertial motion?

A solar activity cycle of about 2400 years has until now been of uncertain origin. Recent results indicate it is caused by solar inertial motion. First we describe the 178.7-year basic cycle of solar motion. The longer cycle, over an 8000 year interval, is found to average 2402.2 years. This corresponds to the Jupiter/Heliocentre/Barycentre alignments (9.8855 × 243). Within each cycle an exceptional segment of 370 years has been found characterized by a looping pattern by a trefoil or quasitrefoil geometry. Solar activity, evidenced by ¹⁴C tree-ring proxies, shows the same pattern. Solar motion is computable in advance, so this provides a basis for future predictive assessments. The next 370-year segment will occur between AD 2240 and 2610.     

Complex site effects and building codes: Making the leap

The engineering community is aware of the importance of site effects, but it lags behind seismological studies when it comes to incorporating site effect considerations in design spectra for seismic norms. This lag is reflected in the conspicuous fact that current building codes make allowance for 1D site effects but ignore complex site effects. The purpose of this paper is to explore a way for including complex site effects in a building code environment. We take as example Eurocode 8, which is a modern code that exemplifies the current approach to site effect consideration. We examine the restrictions that we have imposed to make the problem of a feasible size and discuss the approach we have taken. We propose a strategy to incorporate a class of complex site effects in a design elastic spectrum.     

New radiolarian biostratigraphic age constraints on Middle Triassic basalts and radiolarites from the Inner Hellenides (Northern Pindos and Othris Mountains, Northern Greece) and their implications for the geodynamic evolution of the early Mesozoic Neotethys

The Avdella Mélange in the northern Pindos Mountains and its equivalent formation, the Loggitsion Unit in the Othris Mountains expose early Mesozoic (Mid-Late Triassic) oceanic fragments beneath the Western Greek Ophiolite Belt of the Inner Hellenides, Northern Greece. The mélange consists of locally interfingering blocks and slices of ribbon radiolarite, radiolarian chert and pillow basalt and is usually overthrust by Jurassic ophiolites. New Middle and Upper Triassic radiolarian biostratigraphic data are presented from radiolarites and basalt-radiolarite sequences within mélange blocks. Pillow basalts associated with the radiolarites provide clues to the opening of the Neotethyan ocean basin. The radiolarians indicate a Middle Triassic age (latest Anisian, probably early Illyrian), which is documented for the first time in the northern Pindos Mountains. The new radiolarian biostratigraphic data suggest that rift-type basalt volcanism already began in pre-Ladinian time (late Scythian?—Anisian). These basalts were then overlain by Upper Anisian to Carnian (?Norian) radiolarites.     

Re‐establishment of soil water repellency after destruction by intense burning in a Mediterranean heathland (SW Spain)

Soil water repellency has been conventionally considered as a fire‐induced effect, but an increasing number of studies have suggested that natural background repellency occurs in many soil types, and many of them have suggested that water repellency can be re‐established over time after being destroyed. An experimental fire was conducted to study changes of the soil surface during the first 18 months following intense burning. The main objectives of this paper are as follows: (1) to investigate in situ water repellency changes at three soil depths (0, 2 and 4 cm) immediately after burning; (2) to evaluate the medium‐term evolution of water repellency under field conditions; and (3) to outline the main hydrological consequences of these changes. Also, different water repellency tests (water drop penetration time, ethanol percentage test (EPT) and contact angle (CA) between water drops and the soil surface) were carried out for comparison purposes. Field experiments showed that soil water repellency was partly destroyed after intense burning. Changes were relatively strong at the soil surface, but diminished progressively with depth. Levels of water repellency were practically re‐established 18 months after burning. This suggests that water repellency in the studied area is not necessarily a consequence of fire, but can instead be a natural attribute. Finally, although limited in time, destruction of soil water repellency has important consequences for runoff flow generation and soil loss rates, and, indirectly, for water quality. Copyright © 2009 John Wiley & Sons, Ltd.     

Morphosedimentary features and recent depositional architectural model of the Cantabrian continental margin

Multibeam bathymetry, high (sleeve airguns) and very high resolution (parametric system-TOPAS-) seismic records were used to define the morphosedimentary features and investigate the depositional architecture of the Cantabrian continental margin. The outer shelf (down to 180–245 m water depth) displays an intensively eroded seafloor surface that truncates consolidated ancient folded and fractured deposits. Recent deposits are only locally present as lowstand shelf-margin deposits and a transparent drape with bedforms. The continental slope is affected by sedimentary processes that have combined to create the morphosedimentary features seen today. The upper (down to 2000 m water depth) and lower (down to 3700–4600 m water depth) slopes are mostly subject to different types of slope failures, such as slides, mass-transport deposits (a mix of slumping and mass-flows), and turbidity currents. The upper slope is also subject to the action of bottom currents (the Mediterranean Water — MW) that interact with the Le Danois Bank favouring the reworking of the sediment and the sculpting of a contourite system. The continental rise is a bypass region of debris flows and turbidity currents where a complex channel-lobe transition zone (CLTZ) of the Cap Ferret Fan develops.The recent architecture depositional model is complex and results from the remaining structural template and the great variability of interconnected sedimentary systems and processes. This margin can be considered as starved due to the great sediment evacuation over a relatively steep entire depositional profile. Sediment is eroded mostly from the Cantabrian and also the Pyrenees mountains (source) and transported by small stream/river mountains to the sea. It bypasses the continental shelf and when sediment arrives at the slope it is transported through a major submarine drainage system (large submarine valleys and mass-movement processes) down to the continental rise and adjacent Biscay Abyssal Plain (sink). Factors controlling this architecture are tectonism and sediment source/dispersal, which are closely interrelated, whereas sea-level changes and oceanography have played a minor role (on a long-term scale).     

Impact of submarine hydrothermal vents on the metal composition of krill and its excretion products

We have measured the metal composition and estimated the excretion rate of trace elements (Ag, Cd, Co, Cu, Ni, Pb, V and Zn) by Antarctic krill (Euphausia superba) in three locations (two located within a submarine hydrothermal vent field and one away from it) along the Antarctic Peninsula region of the Southern Ocean. Results indicated that krill excreted large amounts of Ag, Cu, Pb and Zn, (range: 1.9–41.2 pmol Ag g DW^? 1 h^? 1, 15.3–26.8 nmol Cu g DW^? 1 h^? 1, 308.7–1118.3 pmol Pb g DW^? 1 h^? 1 and 24.4–76.5 nmol Zn g DW^? 1 h^? 1), compared with the non-significant or undetectable release rates of Cd, Co, Ni and V. The metal composition of the excreted material from krill collected in the area of hydrothermal activity was similar to the metal composition reported for suspended particles emitted from those vents. Our results suggest that krill recycling of Ag, Cu, Pb and Zn could potentially influence trace metal concentrations in the water column of the Bransfield region of the Southern Ocean, and that the original source of metals to these waters may be hydrothermal vents.