A percent-of-flow approach for managing reductions of freshwater inflows from unimpounded rivers to Southwest Florida estuaries

The Southwest Florida Water Management District has implemented a management approach for unimpounded rivers that limits withdrawals to a percentage of streamflow at the time of withdrawal. The natural flow regime of the contributing river is considered to be the baseline for assessing the effects of withdrawals. Development of the percent-of-flow approach has emphasized the interaction of freshwater inflow with the overlap of stationary and dynamic habitat components in tidal river zones of larger estuarine systems. Since the responses of key estuarine characteristics (e.g., isohaline locations, residence times) to freshwater inflow are frequently nonlinear, the approach is designed to prevent impacts to estuarine resources during sensitive low-inflow periods and to allow water supplies to become gradually more uvailable as inflow increases. A high sensitivity to variation at low inflow extends to many invertebrates and fishes that move upstream and downstream in synchrony with inflow. Total numbers of estuarine-resident and estuarine-dependent organisms have been found to decrease during low-inflow periods, including mysids, grass shrimp, and juveniles of the bay anchovy and sand seatrout. The interaction of freshwater inflow with seasonal processes, such as phytoplankton production and the recruitment of fishes to the tidal-river nursery, indicates that withdrawal percentages during the springtime should be most restrictive. Ongoing efforts are oriented toward refining percentage withdrawal limits among seasons and flow ranges to account for shifts in the responsiveness of estuarine processes to reductions in freshwater inflow.     

Causes of interestuarine variability in bay anchovy (<Emphasis Type="Italic">Anchoa mitchilli</Emphasis>) salinity at capture

Salinities occupied by different life stages of bay anchovy (Anchoa mitchilli) were compared over annual cycles at 128 stations in 12 Florida estuaries. The comparison included eight stations in an oligotrophic, groundwater-based estuary in which all life stages were rare or absent. At other stations, adults, eggs, and early larvae occurred in intermediate to high salinities (10-30 psu) with no apparent central salinity tendency. The larva-juvenile transition was marked by an upstream shift to lower salinities (0-15 psu), also with no central salinity tendency. Mean salinities of the juvenile catch were strongly dependent on the salinities of the sampling effort. This dependence was strongest in estuaries that had weak horizontal salinity gradients. Weak salinity gradients were either natural or resulted from estuarine dams. After using nonlinear regression to account for the interaction between effort salinity and catch salinity, catch salinities were found to be similar from year to year within estuaries, but widely different among estuaries, with interestuarine differences ranging as high as 10–13 psu. Lower salinities were occupied by juveniles in estuaries that had long freshwater turnover times. Inherent geomorphic and inflow-related effects on the distribution of prey resources, coupled with an ontogenetic diet shift, are proposed as the explanation for both the habitat shift and the strong interestuarine variability in salinity at capture.     

The ∼2 ka subplinian eruption of Montaña Blanca,Tenerife

The latest cycle of volcanism on Tenerife has involved the construction of two stratovolcanoes, Teide and Pico Viejo (PV), and numerous flank vent systems on the floor of the Las Cañadas Caldera, which has been partially infilled by magmatic products of the basanite-phonolite series. The only known substantial post-caldera explosive eruption occurred 2 ka bp from satellite vents at Montaña Blanca (MB), to the east of Teide and at PV. The MB eruption began with extrusion of 0.022 km³ of phonolite lava (unit I) from a WNW-ESE fissure system. The eruption then entered an explosive subplinian phase. Over a 7–11 hour period, 0.25 km³ (DRE) of phonolitic pumice (unit II) was deposited from a 15 km high subplinian column, dispersed to the NE by 10 m/s winds. Pyroclastic activity also occurred from vents near PV to the west of Teide. Fire-fountaining towards the end of the explosive phase formed a proximal welded spatter facies. The eruption closed with extrusion of small volume domes and lavas (0.025 km³) at both vent systems. Geochemical, petrological data and Fe-Ti oxide geothermometry indicate the eruption of a chemically and thermally stratified magma system. The most mafic and hottest (875°C) unit I magma can yield the more evolved and cooler (755–825°C) phonolites of units II and III by between 7 and 11% fractional crystallization of an assemblage dominated by alkali feldspar. Analyses of glass inclusions from phenocrysts by ion microprobe show that the pumice was derived from the water-saturated roof zone of a chamber containing 3.0–4.5 wt.% H₂O and abundant halogens (F0.35wt.%). Hotter, more mafic tephritic magma intermingled with the evolved phonolites in banded pumice, indicating the injection of mafic magma into the system during or just before eruption. Reconstruction ot the event indicates a small chamber chemically stratified by in situ (side-wall) crystallization at a depth of 3–4 km below PV. Although phonolite is the dominant product of the youngest activity of the Teide-PV system, there has been no eruption of phonolitic magma for at least 500 years from teide itself and for 2000 years from the PV system. Therefore there could be a large volume of highly evolved, volatile-rich magma accumulating in these magma systems. An eruption of fluorine-rich magma comparable with MB would have major damaging effects on the island.     

Occurrences of hydrous and carbonate phases in ultrahigh-pressure rocks from east-central China: Implications for the role of volatiles deep in cold subduction zones

Abstract Minor epidote-zoisite, phengite, glaucophane, nyböite, talc, magnesite, and dolomite occur as matrix phases or as mineral inclusions in some ultrahigh-pressure (UHP) rocks from the Dabie-Sulu terrane. Some of these phases contain inclusions of coesite or coesite pseudomorphs and appear to have been in equilibrium with coesite at the time of formation. Their occurrences in the UHP rocks together with experimentally determined and calculated phase relations indicate that they are stable at mantle depths in relatively low-temperature environments. Because of the apparently dry nature of subducted continental protoliths of the Yangtze craton, small amounts of volatile components at depths exceeding 50 km along a cold subduction zone may have been stored mainly by these hydrous and carbonate phases. These minerals, in addition to some dense hydrous magnesian silicates, act as important carriers for H₂O and CO₂ recycled at mantle depths. Available petrological and geochemical data support limited or no fluid flow in this region. At very high pressures and low temperatures, the subducted sialic crust evidently served as a desiccating agent. Partial melting of the subducting slab, therefore, may not have occurred, and near absence of volatile expulsion from the subducting slab to the overlying mantle wedge + continental crust may have inhibited large-scale partial melting, accounting for the lack of a typical contemporaneous calc-alkaline magmatic arc.     

Earthquake focal mechanisms of the induced seismicity in 2006 and 2007 below Basel (Switzerland)

To stimulate the reservoir for a “hot dry rock" geothermal project, that was initiated by a private/public consortium in the city of Basel, approximately 11500 m³ of water were injected between December 2nd and 8th, 2006, at high pressures into a 5 km deep well. More than 10500 seismic events were recorded during the injection phase, and minor sporadic seismic activity was still occurring more than two years later. The present article documents the focal mechanisms of the 28 strongest events, with M_L between 1.7 and 3.4, that have been obtained by the Swiss Seismological Service (SED) during and after the stimulation. The analysis is based on data that was recorded by a six-station borehole network, operated by the project developers, as well as by several permanent and temporary surface networks. The hypocenters of the events are located inside the stimulated rock volume at depths between 4 and 5 km within the crystalline basement. Of the 28 faultplane solutions two are normal faulting mechanisms and one is a strike-slip mechanism with a strong normal component. All others are typical strike-slip mechanisms with mostly NS and EW striking nodal planes. As a consequence, the T-axes are all nearly horizontal and oriented in a NE or SW direction (mean azimuth 46 ± 11 degrees) and the P-axes of the strike-slip events point in a NW or SE direction (mean azimuth 138 ± 13 degrees). Overall, the observed focal mechanisms agree with what would be expected from both the stress observations within the well and the stress field derived from the previously known natural seismicity.     

Fundamental changes in the activity of the natrocarbonatite volcano Oldoinyo Lengai, Tanzania

On September 4, 2007, after 25 years of effusive natrocarbonatite eruptions, the eruptive activity of Oldoinyo Lengai (OL), N Tanzania, changed abruptly to episodic explosive eruptions. This transition was preceded by a voluminous lava eruption in March 2006, a year of quiescence, resumption of natrocarbonatite eruptions in June 2007, and a volcano-tectonic earthquake swarm in July 2007. Despite the lack of ground-based monitoring, the evolution in OL eruption dynamics is documented based on the available field observations, ASTER and MODIS satellite images, and almost-daily photos provided by local pilots. Satellite data enabled identification of a phase of voluminous lava effusion in the 2 weeks prior to the onset of explosive eruptions. After the onset, the activity varied from 100 m high ash jets to 2–15 km high violent, steady or unsteady, eruption columns dispersing ash to 100 km distance. The explosive eruptions built up a ∼400 m wide, ∼75 m high intra-crater pyroclastic cone. Time series data for eruption column height show distinct peaks at the end of September 2007 and February 2008, the latter being associated with the first pyroclastic flows to be documented at OL. Chemical analyses of the erupted products, presented in a companion paper (Keller et al. 2010), show that the 2007–2008 explosive eruptions are associated with an undersaturated carbonated silicate melt. This new phase of explosive eruptions provides constraints on the factors causing the transition from natrocarbonatite effusive eruptions to explosive eruptions of carbonated nephelinite magma, observed repetitively in the last 100 years at OL.     

Turbulence in a Katabatic Flow

Turbulence measurements performed in a stable boundary layer over the sloping ice surface of the Vatnajökull in Iceland are described. The boundary layer, in which katabatic forces are stronger than the large-scale forces, has a structure that closely resembles that of a stable boundary layer overlying a flat land surface, although there are some important differences. In order to compare the two situations the set-up of the instruments on an ice cap in Iceland was reproduced on a flat grass surface at Cabauw, the Netherlands. Wind speed and temperature gradients were calculated and combined with flux measurements made with a sonic anemometer in order to obtain the local stability functions _m and _h as a function of the local stability parameter z/L. Unlike the situation at Cabauw, where _m was linear as a function of z/L, in the katabatically forced boundary layer, the dependence of _m on stability was found to be non-linear and related to the height of the wind maximum. Thermal stratification and the depth of the stable boundary layer however seem to be rather similar under these two different forcing conditions.Furthermore, measurements on the ice were used to construct the energy balance. These showed good agreement between observed melt and components contributing to the energy balance: net radiation (supplying 55% of the energy), sensible heat flux (30%) and latent heat flux (15%).Local sources and sinks in the turbulent kinetic energy budget are summed and indicate a reasonable balance in near-neutral conditions but not in more stable situations. The standard deviation of the velocity fluctuations _u, _v, and _w, can be scaled satisfactorily with the local friction velocity u_* and the standard deviation of the temperature fluctuation with the local temperature scale _*.     

Isotopic Composition of Non-Methane Hydrocarbons in Emissions from Biomass Burning

The stable carbon isotope ratios of nonmethane hydrocarbons (NMHC) and methyl chloride emitted from biomass burning were determined by analyzing seven whole air samples collected during different phases of the burning process as part of a laboratory study of wood burning. The average of the stable carbon isotope ratios of emitted alkanes, alkenes and aromatic compounds is identical to that of the burnt fuel; more than 50% of the values are within a range of ±1.5 of thecomposition of the burnt fuel wood. Thus for the majority of NMHC emitted from biomass burning stable carbon isotope ratio of the burnt fuel a good first order approximation for the isotopic composition of the emissions. Of the more than twenty compounds we studied, only methyl chloride and ethyne differed in stable carbon isotope ratios by more than a few per mil from the composition of the fuel. Ethyne is enriched in ¹³C by approximately 20–30, and most of the variability can beexplained by a dependence on flame temperature. The ¹³C values decreaseby 0.019 /K (±0.0053/K) with increasing temperature. Methyl chloride is highly depleted in ¹³C, on average by25. However the results cover a wide range of nearly 30. Specifically, in two measurements with wood from Eucalyptus (Eucalyptus delegatensis) as fuel we observed the emission of extremely light methyl chloride (–68.5and–65.5). This coincides with higher than average emission ratiosfor methyl chloride (15.5 × 10^–5 and 18 ×10^–5 mol CH₃Cl/mol CO₂). These high emission ratios are consistent with the highchlorine content of the burnt fuel, although, due to the limited number of measurements, it would be premature to generalize these findings. The limited number of observations also prevents any conclusion on a systematic dependence between chlorine content of the fuel, emission ratios and stable carbon isotope ratio of methyl chloride emissions. However, our results show that a detailed understanding of the emissions of methyl chloride from chloride rich fuels is important for understanding its global budget. It is also evident that the usefulness of stable carbon isotope ratios to constrain the global budget of methyl chloride will be complicated by the very large variability of the stable carbon isotope ratio of biomass burning emissions. Nevertheless, ultimately the large fractionation may provide additional constraints for the contribution of biomass burning emissions to the atmospheric budget of methyl chloride.