Contamination of Caribbean coastal waters by the antifouling herbicide Irgarol 1051

Irgarol 1051 is a s-triazine herbicide used in popular slime-resistant antifouling paints. It has been shown to be acutely toxic to corals, mangroves and sea grasses, inhibiting photosynthesis at low concentrations (>50 ng l(-1)). We present the first data describing the occurrence of Irgarol 1051 in coastal waters of the Northeastern Caribbean (Puerto Rico (PR) and the US Virgin Islands (USVI)). Low level contamination of coastal waters by Irgarol 1051 is reported, the herbicide being present in 85% of the 31 sites sampled. It was not detected in water from two oceanic reference sites. In general, Irgarol 1051was present at concentrations below 100 ng l(-1), although far higher concentrations were reported at three locations within Benner Bay, USVI (223-1,300 ng l(-1)). The known toxicity of Irgarol 1051 to corals and sea grasses and our findings of significant contamination of the Northeastern Caribbean marine environment by this herbicide underscore the importance of understanding, more fully, local and regional exposure of reef and sea grass habitats to Irgarol 1051 and, where necessary, implementing actions to ensure adequate protection of these important ecosystems.     

Infrared micro-spectroscopy of the martian meteorite Zagami: Extraction of individual mineral phase spectra

Zagami, a well characterized SNC meteorite, represents a reference sample to verify the feasibility of the non-destructive infrared micro-spectroscopy technique to extract spectral signatures from individual mineral phases in a meteorite sample. For the first time individual infrared spectra of the major mineral phases, in the 6000-600 cm⁻¹ (1.67-16.7 μm) spectral interval, whose identification is confirmed by energy dispersive X-ray analysis and backscattered imaging, are measured. The signatures of the main mineral phases we identified in the Zagami chip are: (1) maskelynite characterized by broad and smooth SiO vibrational bands in the 1000 cm⁻¹ spectral region; (2) crystalline pyroxenes showing well defined fine structures; and (3) an oxide mineral phase with an almost featureless and flat spectrum. In the part of the spectrum centered around 2 μm, by analyzing the different positions of the Fe²⁺ bands, we were able to discern the high-Ca from the low-Ca pyroxene phases. This result demonstrates that by means of the infrared micro-spectroscopy technique it is possible to retrieve directly the composition of pyroxenes in the En-Fs-Wo system, without relying on the use of deconvolution techniques. In addition IR signatures due to water and aliphatic hydrocarbons were observed to be more abundant in the pyroxenes than in maskelynite. This could be an indication that the organic and water signatures are due to indigenous compounds in Zagami rather than laboratory contamination, however, further investigations are necessary before this conclusion can be confirmed.     

The Planetary Nebula Spectrograph elliptical galaxy survey: the dark matter in NGC 4494

We present new Planetary Nebula Spectrograph observations of the ordinary elliptical galaxy NGC 4494, resulting in positions and velocities of 255 planetary nebulae out to seven effective radii (25 kpc). We also present new wide-field surface photometry from MMT/Megacam, and long-slit stellar kinematics from VLT/FORS2. The spatial and kinematical distributions of the planetary nebulae agree with the field stars in the region of overlap. The mean rotation is relatively low, with a possible kinematic axis twist outside  1 R _e  . The velocity dispersion profile declines with radius, though not very steeply, down to  ∼70 km s⁻¹  at the last data point.
We have constructed spherical dynamical models of the system, including Jeans analyses with multi-component Λ cold dark matter (CDM) motivated galaxies as well as logarithmic potentials. These models include special attention to orbital anisotropy, which we constrain using fourth-order velocity moments. Given several different sets of modelling methods and assumptions, we find consistent results for the mass profile within the radial range constrained by the data. Some dark matter (DM) is required by the data; our best-fitting solution has a radially anisotropic stellar halo, a plausible stellar mass-to-light ratio and a DM halo with an unexpectedly low central density. We find that this result does not substantially change with a flattened axisymmetric model.
Taken together with other results for galaxy halo masses, we find suggestions for a puzzling pattern wherein most intermediate-luminosity galaxies have very low concentration haloes, while some high-mass ellipticals have very high concentrations. We discuss some possible implications of these results for DM and galaxy formation.     

Kinematic analysis of a transtensional fault system: The Atuel depocenter of the Neuquén basin,southern Central Andes,Argentina

The Atuel depocenter of the Neuquén basin originated as an Upper Triassic to Lower Jurassic rift system, later inverted during the Andean contractional deformation. In order to study the extensional architecture and the kinematic evolution of this depocenter, we collected a large amount of field and sub-surface data, consisting of slip data from outcrop-scale normal faults, thickness and facies distribution within the synrift deposits, and structural data from angular and progressive unconformities. The Atuel depocenter has a NNW trend, showing a bimodal distribution of NNW and WNW major faults (first and second order faults). On the other hand, from kinematic indicators measured on outcrop-scale faults (third and fourth order faults), we found a mean NE internal extension direction, which is oblique to the general trend of the sub-basin. Taking these particular characteristics into account, we interpreted the Atuel depocenter as an oblique rift system. We evaluated two mechanisms in order to explain the development of this transtensional system: 1) reactivation of upper-crustal NNW-oriented Paleozoic shear zones, and 2) oblique stretching of a previous NNW-oriented lithospheric weakness zone.     

Spatial variability of soil nutrients in disturbed riverine mangrove forests at different stages of regeneration in the San Juan River estuary,Venezuela

Geostatistical analysis of selected soil properties were performed in two mangrove sites (B7 and B9) dominated by the mangrove speciesRhizophora mangle along the San Juan River, Venezuela, to evaluate the effect of forest disturbance on nutrient spatial distributions. Plots within area B7 were clear-cut in 1972–1973 and in area B9 in 1982–1983. Four plots within each area were systematically selected and represented natural (2) and regenerated (2) forests. Individual plots were 1.5 ha in B7 and 1.25 ha in B9 and sampled at a resolution of 25 m. Soil samples were obtained at the intersection of an aligned grid with 90 points in B7 and 78 points in B9. Measured soil properties included salinity, total nitrogen, total carbon, total phosphorus, osmolality, and pore water cation concentrations (potassium, calcium, magnesium, and sodium). Sites were sampled in May 1996 and 1997, although spatial analysis was performed only for the data obtained in May 1997. Geostatistical analysis showed that most of the variables tested were spatially auto-correlated within each area and that there were no differences between regenerated and natural plots. Structural variance as a proportion of sample variance ranged from 55–99% for most of the properties. The significant spatial dependence observed for most of the variables in natural and regenerated plots, despite management schedules, indicates that clear-cutting did not have an effect on modifying the distribution of nutrient concentrations. These results suggest that after 15 and 25 yr following forest disturbance nutrient distributions were reestablished either there was not a net effect on patterns of element loss or tidal input was stronger than plant modifications of soils.     

Spatial pattern of photospheric granules in a sunspot neighborhood

Based on high-resolution (0.3 arcsec) observations, we studied the behavior of solar granulation in the neighborhood of a sunspot. The bright granules’ spatial distribution and the granules’ surface density as a function of distance from the center of the sunspot umbra were determined.Bright granules distribute delimiting cells of dimensions in the mesogranular scale. The mean diameter of these cells does not show significant variation with the variation of the magnetic field of the sunspot. The granules’ surface density does not show significant variation with distance to the sunspot umbra. Both results point to a very weak, if any, influence of the sunspot magnetic field at distances greater than 20 arcsec.     

Tectonic Control of the Triassic Santa Maria Supersequence of the Paraná Basin, Southernmost Brazil, and its Correlation to the Waterberg Basin, Namibia

The Middle and Late Triassic Santa Maria Basin, exposed in southernmost Brazil, and Waterberg Basin, in Namibia, are herein interpreted as part of en échelon small basins in southern West Gondwana. The main structures are the Waterberg-Omaruru Fault which can be connected to a NW-strike anastomosed fault zone in Brazil. Based on field structural and stratigraphic analysis two populations of NW-strike fractures, named A-type and B-type, are recognized. A-type fractures (Az = 280°-290°) occur in the Sanga do Cabral Supersequence, underlying units of Santa Maria Basin, as extension of the Waterberg-Omaruru Fault during the Early Triassic. B-type fractures (Az = 295°-345°) are observed in all studied stratigraphic units, from the Triassic Sanga do Cabral Supersequence to the Early Cretaceous Botucatu/Serra Geral formations. Based on the structural analysis we propose that NNE-SSW extension reactivated structures of the Damara Belt, Namibia, with a propagation towards Rio Grande do Sul State forming an anastomosing normal fault system and related-rift basin by Early-Middle Triassic time. The A-type fractures were preferentially active by this phase and the B-type ones are interpreted as secondary link segments within the anastomosing system. During the Gondwana break-up and South Atlantic opening (rift to proto-oceanic phase, Aptian) the B-type fractures were reactivated as normal faults by N50°E-S50°W extension.     

Tropospheric transformation products of a series of hydrofluorocarbons and hydrochlorofluorocarbons

The products of the Cl-atom initiated reactions of a series of hydrofluorocarbons (HFCs) and hydrochlorofluorocarbons (HCFCs) in air have been investigated at 298 K and one atmosphere (740 Torr total pressure) of air. The products observed and quantified and their yields (%) were as follows: from CHF₂Cl (HCFC-22), C(O)F₂ (100%); from CHFCl₂ (HCFC-21), C(O)FCl (100%); from CH₂FCl (HCFC-31), HC(O)F (100%); from CH₃F (HFC-41), HC(O)F (100%); from CH₃CFCl₂ (HCFC-141b), C(O)FCl (100%); from CH₃CF₂Cl (HCFC-142b), C(O)F₂ (100%); from CH₃CHF₂ (HFC-152a), C(O)F₂ (92%); from CHCl₂CF₃ (HCFC-123), CF₃C(O)Cl (98%); from CHFClCF₃ (HCFC-124), CF₃C(O)F (101%); and from CHF₂CF₃ (HFC-125), C(O)F₂ (100%). The reaction mechanisms are discussed.     

Paleomagnetism, geochemistry and Ar/Ar dating of the North-eastern Paraná Magmatic Province: tectonic implications

Seventy sites of sills, flows and dikes from Northeastern Paraná Magmatic Province (PMP), were submitted to paleomagnetic, chemical and radiometric analyses. The rocks are high in TiO₂ content, and similar in composition to the rocks from the northern region of PMP. The sills intrude mainly Paleozoic sediments, and can be subdivided into two domains; the northern being characterized by sills showing reversed polarities, and the southern essentially by sills of normal polarities. ⁴⁰Ar/³⁹Ar dating of three distinct sills gave plateau ages (129.9 ± 0.1, 130.3 ± 0.1 and 131.9 ± 0.4 Ma) that are similar to surface-outcropping flows of the Northern Paraná Basin, and the Ponta Grossa dikes. The new paleomagnetic data combined with existing data from the northern PMP allowed the calculation of a paleomagnetic pole at 71.4° E and 83.0° S (N = 92; α₉₅=2.4°; k = 39). This pole is in good agreement with poles for central and southern PMP, which are slightly older than the northern PMP, as well as for the contemporaneous Central Alkaline Province (Paraguay) on the western side of PMP. In contrast, the coeval pole for the Ponta Grossa dikes (eastern border of PMP), however, is slightly displaced from that group of poles, suggesting that dikes in that area may have undergone some tectonic tilting.     

Fluvial system dynamics derived from distributed sediment budgets: perspectives from an uncertainty‐bounded application

The utility of sediment budget analysis is explored in revealing spatio‐temporal changes in the sediment dynamics and morphological responses of a fluvial system subject to significant human impacts during the recent Anthropocene. Sediment budgets require a data‐intensive approach to represent spatially‐differentiated impacts adequately and are subject to numerous estimation uncertainties. Here, field and topographic surveys, historical data, numerical modelling and a representative‐area extrapolation method are integrated to construct a distributed, process‐based sediment budget that addresses historical legacy factors for the highly regulated Lagunitas Creek (213 km²), California, USA, for the period 1983–2008. Independent corroboration methods and error propagation analysis produce an uncertainty assessment unique to a catchment of this size. Current sediment yields of ~20 000 t a^‐1 ± 6000 t a^‐1 equate to unit rates of ~300 t km^‐2 a^‐1 ± 90 t km^‐2 a^‐1 over the effective sediment contributing area of 64 km². This is comparable with yields associated with early Euro‐American settlement in the catchment, despite loss of sediment supply upstream of the two large dams. It occurs because ~57% of the sediment is now derived from incision‐related channel erosion. Further, the highly efficient routing of channel‐derived sediments in these incised channels suggests an efflux of 84% of contemporary sediment production, contrasting with the efflux of ≈10–30% reported for unregulated agricultural catchments. The results highlight that sediment budgets for regulated rivers must accommodate channel morphological responses to avoid significantly misrepresenting catchment yields, and that volumetric precision in sediment budgets may best be improved by repeat, spatially dense, channel cross‐section surveys. Human activities have impacted every aspect of the sediment dynamics of Lagunitas Creek (production, storage, transfer, rates of movement through storage), confirming that, while distributed sediment budgets are data demanding and subject to numerous error sources, the approach can provide valuable insights into Anthropocene fluvial geomorphology. Copyright © 2017 John Wiley & Sons, Ltd.