Evidence for Mg-rich carbonates on Mars from a 3.9 μm absorption feature

The origin and nature of the early atmosphere of Mars is still debated. The discovery of sulfate deposits on the surface, coupled with the evidence that there are not large abundances of carbonates detectable on Mars in the optically accessible part of the regolith, leaves open different paleoclimatic evolutionary pathways. Even if carbonates are responsible for the feature observed by TES and Mini-TES at 6.76 μm, alternative hypotheses suggest that it could be due to the presence of Hydrated Iron Sulfates (HIS). Carbonates can be discerned from HIS by investigating the spectral region in which a strong overtone carbonate band is present. The Planetary Fourier Spectrometer on board the Mars Express spacecraft has acquired several thousand martian spectra in the range 1.2-45 μm since January 2004, most of which show a weak absorption feature between 3.8 and 4 μm. A similar feature was observed previously from the Earth, but its origin could not be straightforwardly ascribed to surface materials, and specifically to carbonates. Here we show the surficial nature of this band that can be ascribed to carbonate mixed with the martian soil materials. The materials that best reproduce the detected feature are Mg-rich carbonates (huntite [CaMg₃(CO₃)₄] and/or magnesite [MgCO₃]). The presence of carbonates is demonstrated in both bright and dark martian regions. An evaluation of the likeliest abundance gives an upper limit of ∼10 wt%. The widespread distribution of carbonates supports scenarios that suggest carbonate formation occurred not by precipitation in a water-rich environment but by weathering processes.     

Geochemistry of K‐feldspar and Muscovite in Rare‐element Pegmatites and Granites from the Totoral Pegmatite Field,San Luis,Argentina

The geochemistry of K‐feldspar for K, P, Sr, Ba, Rb, Cs, Ga, and of muscovite for the same elements plus Nb and Ta, was used for proving the parental relationships of S‐type granites and LCT (Li, Cs, Ta) rare‐element pegmatites in the southernmost pegmatitic field of the Pampean pegmatite province in Argentina. The variation of K/Rb‐Cs, K/Cs‐Rb, K/Rb‐Rb/Sr, K/Rb‐Ba in K‐feldspar from the granites and pegmatites show that they form an association with the evolutional sequence: granites → barren‐ to transitional pegmatites → beryl type, beryl‐columbite‐phosphate pegmatites → complex type of spodumene subtype pegmatites → albite‐spodumene type → albite type pegmatites. This sequence reflects the regional distribution of the different magmatic units. The Ta‐Cs diagram for muscovite reveals that none of the studied pegmatites exceed the threshold established in previous studies for being considered with important tantalum oxide mineralization. The granites and pegmatites constitute a rare‐element pegmatitic field in which different magmatic units form a continuous fractionation trend, extended from the less evolved granitic facies to the most geochemically specialized pegmatites     

Bearing Capacity of Strip Footings Near Slopes

In the last decades a great attention was given by many authors to the evaluation of the static and seismic bearing capacity of footings near slopes. In this paper a model has been developed based on the limit equilibrium method, considering a circular surface propagates towards the slope until the sloping ground is reached. The bearing capacity is investigated considering either the distance of the footing from the edge of the slope and/or the effect of the footing embedment. A validation of the proposed model was made by a comparison with solutions taken from literature regarding the evaluation of the bearing capacity for a footing adjacent to a slope and for an inclined load. The loading conditions consist in vertical and horizontal stress on the footing and on the soil below the footing. Both the inertial and kinematic effects of the seismic loading have been analyzed, and a simple equation has been derived for the evaluation of the seismic bearing capacity. The static and seismic bearing capacity has been investigated as a function of the soil friction angle, of the seismic coefficient, of the sloping ground. Finally, the influence of the distance of the footing from the edge of the slope was taken into consideration in the evaluation of the bearing capacity, and a threshold distance at which the reduction of the bearing capacity due to the sloping ground vanishes has been defined.     

The boreal spring variability of the Intra-Americas low-level jet and its relation with precipitation and tornadoes in the eastern United States

The Intra-Americas Sea (IAS) low-level jet has been studied mainly for the summer and winter seasons. In contrast, spring conditions have been studied less. Here we analyze the boreal spring variability of the IAS low-level jet (IA-LLJ) and its relation with precipitation and tornadic activity in the region of the lower Mississippi, Tennessee and Ohio River basins (MORB). The main mode of variability of the spring IA-LLJ is obtained from a combined principal component analysis of zonal and meridional winds at 925-hPa. The first empirical orthogonal function of the IA-LLJ is a strengthening of the climatological flow with stronger easterlies in the Caribbean and stronger southeasterlies in the Gulf of Mexico. This first mode of variability of the IA-LLJ is related mainly to the Pacific North American (PNA) teleconnection pattern as the PNA modulates the pressure in the southeast region of the U.S. Consequently, there is an increase in precipitation over the MORB region as the moisture fluxes associated with the IA-LLJ increase. Tornadic activity in nine states spanning the MORB region is also significantly related to the IA-LLJ and the PNA index for March, in addition to the Pacific decadal oscillation (PDO) and the Ni?o indexes. Among the environmental factors that influence tornadic activity are southwesterly wind shear, dry transients at the mid-troposphere, moist transients at low levels, and an increase in convective available potential energy (CAPE). The decadal shifts in MORB precipitation and tornado activity appear to be related to the decadal shift of the IA-LLJ.     

ENSO to multi-decadal time scale changes in East Australian Current transports and Fort Denison sea level: Oceanic Rossby waves as the connecting mechanism

The connection between East Australian Current (EAC) transport variability and Australia’s east coast sea level has received little treatment in the literature. This is due in part to the complex interacting physical processes operating in the coastal zone combined with the sparsity of observations available to improve our understanding of these possible connections. This study demonstrates a statistically significant (at the >90% level) relationship between interannual to decadal time scale variations in observed estimates of the EAC transport changes and east coast sea level measured at the high-quality, long record Fort Denison tide-gauge in Sydney Harbour, Australia (33°51′18″S, 151°13′32″E). We further demonstrate, using a linear reduced-gravity ocean model, that ENSO to decadal time-scale variations and the ocean-adjusted multi-decadal trend (approx. 1 cm/decade) in observed sea level at Fort Denison are strongly connected to modulations of EAC transports by incoming westward propagating oceanic Rossby waves. We show that EAC transport and Fort Denison sea level vary in a manner expected from both Tasman Sea generated Rossby waves, which account for the interannual and multi-annual variability, and remotely forced (from east of New Zealand) Rossby wave connections through the mid-latitudes, accounting for the ocean-adjusted multi-decadal trend observed at the New South Wales coast - with the regional-Tasman Sea forcing explaining the greatest overall proportion of EAC transport and sea-level variances.     

Paleomagnetism and rock magnetism of the Neoproterozoic Itajaí Basin of the Rio de la Plata craton (Brazil): Cambrian to Cretaceous widespread remagnetizations of South America

A detailed rock magnetic and paleomagnetic study was performed on samples from the Neoproterozoic Itajaí Basin in the state of Santa Catarina, Brazil, in order to better constrain the paleogeographic evolution of the Rio de la Plata craton between 600 and 550 Ma. However, rock magnetic properties typical of remagnetized rocks and negative response in the fold test indicated that these rocks carried a secondary chemical remanent magnetization. After detailed AF and thermal cleaning, almost all samples showed a normal polarity characteristic remanent magnetization component close to the present geomagnetic field. The main magnetic carriers are magnetite and hematite, probably of authigenic origin. The mean paleomagnetic pole of the Itajaí Basin is located at Plat = − 84°, Plong = 97.5° (A95 = 2°) and overlaps the lower Cretaceous segment of the apparent polar wander path of South America, suggesting a cause and effect with the opening of the South Atlantic Ocean. A compilation of remagnetized paleomagnetic poles from South America is presented that highlights the superposition of several large-scale remagnetization events between the Cambrian and the Cretaceous. It is suggested that some paleomagnetic poles used to calibrate the APWP of Gondwana at Precambrian times need to be revised; the indication of remagnetized areas in southern South America may offer some help in the selection of sites for future paleomagnetic investigations in Precambrian rocks.     

Geotechnical zonation and soil–structure interaction at Puerto Vallarta,México

Natural Hazards - We performed a seismic vulnerability assessment that involves geotechnical and building structure analysis for Puerto Vallarta, Mexico, a city located along the pacific coast....     

Phylogeography of the bluespotted cornetfish,Fistularia commersonii: a predictor of bioinvasion success?

Biological invasions result in huge ecological and economic impacts; therefore, a great amount of effort is dedicated to predicting the potential success of newly established or candidate bioinvaders. Thus far, over 90 species of fish have entered the Mediterranean Sea via the Suez canal, the so‐called Lessepsian bioinvaders. The bluespotted cornetfish, Fistularia commersonii, is remarkable in its ability to disperse within the Mediterranean and has been dubbed ‘the Lessepsian sprinter’. In just a few years, starting in 2000, it expanded over the entire area, from the Suez Canal to Gibraltar. Theoretical predictions correlate the dispersal capabilities of an invader in its native range (using the population genetic metrics, F_st, as a proxy) with its dispersal capability in its invading area (continuous extent of spread, CES). Here, we estimated the population genetic characteristics of Indo‐Pacific native populations of F. commersonii in order to determine if this Lessepsian ‘sprinter’ fits the predictive model of dispersal. Indeed, we found that even in the case of such a very rapid range expansion, the predicted relationship between F_st and CES is fulfilled in F. commersonii.     

Analysis of some degenerate quadruple collisions

We consider the trapezoidal problem of four bodies. This is a special problem where only three degrees of freedom are involved. The blow up method of McGehee can be used to deal with the quadruple collision. Two degenerate cases are studied in this paper: the rectangular and the collinear problems. They have only two degrees of freedom and the analysis of total collapse can be done in a way similar to the one used for the collinear and isosceles problems of three bodies. We fully analyze the flow on the total collision manifold, reducing the problem of finding heteroclinic connections to the study of a single ordinary differential equation. For the collinear case, from which arises a one parameter family of equations, the analysis for extreme values of the parameter is done and numerical computations fill up the gap for the intermediate values. Dynamical consequences for possible motions near total collision as well as for regularization are obtained.Paper presented at the 1981 Oberwolfach Conference on Mathematical Methods in Celestial Mechanics.Dedicated to Prof. Szebehely on the occasion of his sixtieth birthday.