Devitrite (Na2Ca3Si6O16)—structural, spectroscopic and computational investigations on a crystalline impurity phase in industrial soda-lime glasses

Single crystals of devitrite (Na₂Ca₃Si₆O₁₆) were synthesized as pale-yellow transparent needle shaped crystals using a Na₂MoO₄-flux. Experiments aiming to prepare the K-equivalent of devitrite from the corresponding K₂MoO₄-flux were unsuccessful. The crystal structure of devitrite was determined from single-crystal X-ray diffraction data (Mo-K_α radiation, 2θ_max.?=?25.34°, R_int?=?2.66%) and refined in space group P $ \bar{1} $ (no. 2) to R(|F|)?=?3.08% using 2,513 observed reflections with I?>?2σ(I). Unit-cell parameters are: a?=?7.2291(8), b?=?10.1728(12), c?=?10.6727(12) Å, α?=?95.669(9), β?=?109.792(10), γ?=?99.156(9)°, V?=?719.19(14) ų, Z?=?2. The structure belongs to the group of multiple chain silicates consisting of dreier quadruple chains, i.e. the crystallochemical formula can be written as $ {\hbox{N}}{{\hbox{a}}_2}{\hbox{C}}{{\hbox{a}}_3}\left\{ {{\mathbf{uB}}{,4}_\infty^1} \right\}\left[ {^3{\hbox{S}}{{\hbox{i}}_6}} \right.\left. {{{\hbox{O}}_{16}}} \right\} $ . Linkage between the bands running along [100] is provided by double chains of edge sharing CaO₆-octahedra as well as additional more irregularly coordinated Na- and Ca-cations located in the tunnel-like cavities of the mixed tetrahedral-octahedral framework. Structural investigations were completed by Raman and infrared spectroscopical studies. The allocation of the bands to certain vibrational species was aided by density functional theory (DFT) calculations.     

Wave-induced steady streaming,mass transport and net sediment transport in rough turbulent ocean bottom boundary layers

The interaction between two important mechanisms which causes streaming has been investigated by numerical simulations of the seabed boundary layer beneath both sinusoidal waves and Stokes second order waves, as well as horizontally uniform bottom boundary layers with asymmetric forcing. These two mechanisms are streaming caused by turbulence asymmetry in successive wave half-cycles (beneath asymmetric forcing), and streaming caused by the presence of a vertical wave velocity within the seabed boundary layer as earlier explained by Longuet-Higgins. The effect of wave asymmetry, wave length to water depth ratio, and bottom roughness have been investigated for realistic physical situations. The streaming induced sediment dynamics near the ocean bottom has been investigated; both the resulting suspended load and bedload are presented. Finally, the mass transport (wave-averaged Lagrangian velocity) has been studied for a range of wave conditions. The streaming velocities beneath sinusoidal waves (Longuet-Higgins streaming) is always in the direction of wave propagation, while the streaming velocities in horizontally uniform boundary layers with asymmetric forcing are always negative. Thus the effect of asymmetry in second order Stokes waves is either to reduce the streaming velocity in the direction of wave propagation, or, for long waves relative to the water depth, to induce a streaming velocity against the direction of wave propagation. It appears that the Longuet-Higgins streaming decreases as the wave length increases for a given water depth, and the effect of wave asymmetry can dominate, leading to a steady streaming against the wave propagation. Furthermore, the asymmetry of second order Stokes waves reduces the mass transport (wave-averaged Lagrangian velocity) as compared with sinusoidal waves. The boundary layer streaming leads to a wave-averaged transport of suspended sediments and bedload in the direction of wave propagation.     

Economic gains of liberalising access to fishing quotas within the European Union

This paper analyses the extent to which specialisation gains can be achieved by liberalising access to fishing quotas within the European Union (EU). Fishing quotas are today exchanged between EU member states at a rate of 4% of total turnover in EU fisheries. Germany, Belgium, Denmark and the Netherlands are the most active. Only one fourth of these exchanges are permanent. With the management systems in EU fisheries differing among countries, comparative advantages in fisheries exist in member states with the best management practices. Hence, although positive but small specialisation gains exist in EU fisheries today, these gains might potentially be increased by liberalising access to fishing quotas and allowing transferability of quotas between individuals from different countries on a permanent basis. Increasing the gains might, however, affect relative stability.     

The Mesozoic of Western Scandinavia and East Greenland

Thick Mesozoic sediments are found offshore Norway and Denmark, and Mesozoic rocks are present and well exposed in Denmark, along the coast of East Greenland and on the arctic islands of Svalbard.
During the Mesozoic, Scandinavia and Greenland were subject to major extension in the Late Permian-Early Triassic and Late Jurassic-Early Cretaceous, prior to Cenozoic opening of the North Atlantic. Deep basins developed along the rift zones of the North Sea and between East Greenland and Norwa）; and were .filled with sediments derived from mainland Scandinavia and Greenland. The marginal areas bordering the rift zones suffered less subsidence, as did the epicontinental Barents Sea.     

Validation of very high cloud droplet number concentrations in air masses transported thousands of kilometres over the ocean

The microstructure of orographic clouds related to the aerosol present was studied during the second Aerosol Characterisation Experiment (ACE‐2). Very high cloud droplet number concentrations (almost 3000 cm⁻³) were observed. These high concentrations occurred when clouds formed on a hill slope at Tenerife in polluted air masses originating in Europe that had transported the order of 1000 km over the Atlantic Ocean. The validity of the measured droplet number concentrations was investigated by comparing with measurements of the aerosol upstream of the cloud and cloud interstitial aerosol. Guided by distributions of the ratios between the measurements, three criteria of typically 30% in maximum deviation were applied to the measurements to test their validity. Agreement was found for 88% of the cases. The validated data set spans droplet number concentrations of 150–3000 cm⁻³. The updraught velocity during the cloud formation was estimated to 2.2 m s⁻¹ by model calculations, which is typical of cumuliform clouds. The results of the present study are discussed in relation to cloud droplet number concentrations previously reported in the literature. The importance of promoting the mechanistic understanding of the aerosol/cloud interaction and the use of validation procedures of cloud microphysical parameters is stressed in relation to the assessment of the indirect climatic effect of aerosols.     

Simulations of a Line W-based observing system for the Atlantic meridional overturning circulation

In a series of observing system simulations, we test whether the Atlantic meridional overturning circulation (AMOC) can be observed based on the existing Line W deep western boundary array. We simulate a Line W array, which is extended to the surface and to the east to cover the basin to the Bermuda Rise. In the analyzed ocean circulation model ORCA025, such an extended Line W array captures the main characteristics of the western boundary current. Potential trans-basin observing systems for the AMOC are tested by combining the extended Line W array with a mid-ocean transport estimate obtained from thermal wind “measurements” and Ekman transport to the total AMOC (similarly to Hirschi et al., Geophys Res Lett 30(7):1413, 2003). First, we close Line W zonally supplementing the western boundary array with several “moorings” in the basin (Line W-32°N). Second, we supplement the western boundary array with a combination of observations at Bermuda and the eastern part of the RAPID array at 26°N (Line W-B-RAPID). Both, a small number of density profiles across the basin and also only sampling the eastern and western boundary, capture the variability of the AMOC at Line W-32°N and Line W-B-RAPID. In the analyzed model, the AMOC variability at both Line W-32°N and Line W-B-RAPID is dominated by the western boundary current variability. Away from the western boundary, the mid-ocean transport (east of Bermuda) shows no significant relation between the two Line W-based sections and 26°N. Hence, a Line W-based AMOC estimate could yield an estimate of the meridional transport that is independent of the 26°N RAPID estimate. The model-based observing system simulations presented here provide support for the use of Line W as a cornerstone for a trans-basin AMOC observing system.     

Nonaxisymmetric instabilities in self-gravitating disks. II. Linear and quasi-linear analyses

We studied global nonaxisymmetric hydrodynamic instabilities in an extensive collection of hot, self-gravitating polytropic disk systems, systems that covered a wide expanse of the parameter space relevant to protostellar and protoplanetary systems. We examined equilibrium disk models varying three parameters: the ratio of the inner to outer equatorial radii, the ratio of star mass to disk mass, and the rotation law exponent q. We took the polytropic index n=1.5 and examined the exponents q=1.5 and 2, and the transitional one q=1.75. For each of these sets of parameters, we examined models with inner to outer radius ratios from 0.1 to 0.75, and star mass to disk mass ratios from 0 to 10³. We numerically calculated the growth rates and oscillation frequencies of low-order nonaxisymmetric disk modes, modes with azimuthal dependence ∝e ^im? . Low-m modes are found to dominate with the character and strength of instability strongly dependent on disk self-gravity. Representatives of each mode type are examined in detail, and torques and mass transport rates are calculated.     

Interactive visualization of 3D mantle convection

The current availability of thousands of processors at many high performance computing centers has made it feasible to carry out, in near real time, interactive visualization of 3D mantle convection temperature fields, using grid configurations having 10–100 million unknowns. We will describe the technical details involved in carrying out this endeavor, using the facilities available at the Laboratory of Computational Science and Engineering (LCSE) at the University of Minnesota. These technical details involve the modification of a parallel mantle convection program, ACuTEMan; the usage of client–server socket based programs to transfer upwards of a terabyte of time series scientific model data using a local network; a rendering system containing multiple nodes; a high resolution PowerWall display, and the interactive visualization software, DSCVR. We have found that working in an interactive visualizastion mode allows for fast and efficient analysis of mantle convection results. Electronic supplementary material  The online version of this article (doi:) contains supplementary material, which is available to authorized users.     

Permeability and stress in crystalline rocks

Groundwater from crystalline rocks is a significant resource in many areas of the world. It is also an important medium for contaminant transport from, for example, deep nuclear waste repositories. Stress distributions in fractured rocks are important in controlling groundwater flow in several ways: (i) palaeostress fields are responsible for the evolution of fracture systems which transmit groundwater; (ii) current in situ stress fields will influence the shape and aperture of fractures; (iii) humans can influence the natural stress field in a rock mass to enhance fracture flows. The significance of stresses for groundwater flow can be investigated by field techniques (hydraulic fracturing), laboratory techniques (stress cells) or by numerical modelling.