Geochemistry of the Rare Earth Elements in Natural Terrestrial Waters：A Review of What Is Currently Knows

The range of observed chemical compositions of natural terrestrial waters varies greatly especially when compared to the essentially constant global composition of the oceans.The concentrations of the REEs in natural terrestrial waters also exhibit more variation than what was reported in seawater,In terrestrial waters ,pH values span the range from acid up to alkaline,In addition,terrestrial waters can range from very dilute waters through to highly concentrated brines.The REE concentrations and their behavior in natural terrestrial waters reflect these compositional ranges,Chemical weathering of rocks represents the source of the REEs to natural terrestrial waters and ,consequently,the REE signature of rocks can impart their REE signature to associated waters,In addition,Because of the typical low solubilities of the REEs both surface and solution complexation can be important in fractionating REEs in aqueous solution.Both of these processes are important in all natural terrestrial waters,however,their relative importance varies as a function of the overall solution composition,In alkaline waters,for example,Solution complexation of the REEs with carbonate ions appears to control their aqueous distributions whereas in acid waters,the REE signature of the labile fraction of the REEs is readily leached from the rocks.In circumneutral pH waters,both processes appear to be important and their relative significance has not yet been determined.     

Late Cretaceous rift-related upwelling and melting of the Trindade starting mantle plume head beneath western Brazil

High mantle potential temperatures and local extension, associated with the Late-Cretaceous impact of the Trindade mantle plume, produced substantial widespread and voluminous magmatism around the northern half of the Paraná sedimentary basin. Our previous studies have shown that, above the central and eastern portions of the postulated impact zone where lithosphere extension is minimal, heat conducted by the plume caused large-scale melting of the more fusible parts of the subcontinental lithospheric mantle beneath the margin of the São Francisco craton and the surrounding Brasilía mobile belt. Here we combine geochemical data and field evidence from the Poxoreu Igneous Province, western Brazil to show how more intense lithospheric extension above the western margin of the postulated impact zone permitted greater upwelling and melting of the Trindade plume than further east. Laser ⁴⁰Ar/³⁹Ar age determinations indicate that rift-related basaltic magmas of the Poxoreu Igneous Province were emplaced at ? 84 Ma. Our detailed geochemical study of the mafic magmas shows that the parental melts underwent polybaric crystal fractionation within the crust prior to final emplacement. Furthermore, some magmas (quartz-normative) appear to have assimilated upper crust whereas others (nepheline- and hypersthene-normative) appear to have been unaffected by open-system crustal magma chamber processes. Incompatible trace element ratios (e.g. chondrite-normalised La/Nb?=?1) and isotopic ratios (⁸⁷Sr/⁸⁶Sr?=?0.704 and ¹⁴³Nd/¹⁴⁴Nd?=?0.51274) of the Hy-normative basalts resemble those of oceanic islands (OIB). We therefore propose that these “OIB-like” magmas were predominantly derived from convecting-mantle-source melts (i.e. Trindade mantle plume). Inverse modelling of rare-earth element (REE) abundances suggests that the initial melts were predominantly generated within the depth range of ?80–100 km, in mantle with a potential temperature of ?1500 °C.     

Environmental and legal aspects of karst areas

 Environmental impacts on karst settings are common as they are more sensitive than those of other rock terrains. Regulatory procedures that are effective in other rock terrains are not necessarily applicable to karst settings. Development and exploitation by man that affect the karst hydrology regime can trigger catastrophic events and result in numerous legal actions where the effects of changes go beyond property boundaries. A great variety of regulations and examples of litigation exist for karst areas. Received: 25 October 1994 · Accepted: 17 October 1995     

Geochemistry and petrogenesis of Sikait leucogranite, Egypt: an example of S-type granite in a metapelitic sequence

 The Sikait leucogranite (SLG) is a body of porphyritic garnet granite intruded a metapelitic sequence and interlayered orthogneisses. Multiple deformation and low- to medium-grade metamorphism of the sequence was closely associated with pluton emplacement. Textural features of the SLG indicate that subsolidus plastic deformation was induced during the extensive thrusting. The granite is strongly peraluminous, alkali-rich and HFS (high field-strength) elements-depleted with low contents of REE, all facts that substantiate the geochemical characteristics of S-type granites. The geologic and geochemical features are consistent with a dehydration melting model of the hosted metapelites to generate the peraluminous SLG. However, geochemical modelling of trace elements and REEs suggest that the anatectic partial melt was subsequently affected by fractional crystallization of feldspars. This could explain much of the chemical attributes of SLG. Received: 20 September 1994 / Accepted: 2 August 1996     

Ophiolite remnants at the eastern margin of the Bohemian Massif and their bearing on the tectonic evolution

Summary Amphibolites are widespread in the eastern part of the Bohemian Massif, east of the South Bohemian Pluton. Based on their geological situation, their metamorphic evolution and their geochemistry, they were separated into three genetically different units: the Rehberg ophiolite, the Buschandlwand amphibolite and the Raabs group. The metamorphic Rehberg ophiolite consists of a ultramafic to mafic plutonic sequence overlain by a gabbro/dike complex and a volcanic section with basaltic, andesitic and rhyolitic volcanics associated with pelitic to psammitic sediments. The entire ophiolite underwent amphibolite facies metamorphism. Rock/MORB normalisation plots and other element ratio plots, such as Ti vs. V or Ta/Yb vs. Th/Yb argue for a supra-subduction zone environment as site of the origin of the Rehberg ophiolite. The Letovice ophiolite in Moravia is structured in a similar way. Geochemically it shows a more MORB like composition but also a distinct tholeiitic island arc group. Although there is no age data for the protolith of both ophiolites, it is believed that they have formed in an oceanic basin separating the Brunovistulian-Moravian block to the east and the Moldanubian block to the west. Possible traces of the continuation of the ophiolites towards the north can be found in the Stare Mesto ophiolites and the ophiolites surrounding the Sowie Gory block in the Sudetes.

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Ophiolitrelikte am ostrand der Böhmischen Masse und ihre bedeutung für die tektonische entwicklung

Zusammenfassung Amphibolite sind in der Böhmischen Masse, östlich des Südböhmischen Plutons weit verbreitet. Ausgehend von ihrer geologischen Position, ihrer metamorphen Entwick lung und ihrer Geochemie lassen sie sich in drei genetisch unterschiedliche Einheiten teilen: den Rehberg Ophiolith, den Buschandlwand Amphibolit und die Raabser Gruppe. Der metamorphe Rehberg Ophiolith besteht aus einer ultramatischen bis mafischen plutonischen Abfolge, die von einem Gabbro/Gangkomplex überlagert wird und einer vulkanischen Folge mit Basalten, Andesiten and Rhyoliten, die mit tonigen und sandigen Sedimenten verknüpft sind. Der gesamte Ophiolithkörper wurde unter amphibolitfaziellen Bedingungen metamorph überprägt. Rock/MORB Diagramme und andere Elementdarstellungen, wie z.B. das Ti vs. V, oder das Ta/Yb vs. Th/Yb Diagramm sprechen für eine Entstehung des Rehberg Ophioliths in einer Suprasubduction Zone. Der Letovice Ophiolith in Mähren weist eine ähnliche Struktur auf. Geochemisch zeigt er stärkere Ähnlichkeiten mit MORB, enthält aber auch Elemente von tholeiitischen Inselbogenbasalten. Auch wenn es für beide Ophiolithe noch keine Protolith-Altersdaten gibt, scheint es dennoch wahrscheinlich, daß sie in einem Ozeanbecken, das den Brunovistulisch-Moravischen Kontinentalblock im Osten vom Moldanubischen Kontinent im Westen trennt, gebildet wurden. Die mögliche Fortsetzung beider Ophiolithe könnten im Norden der Stare Mesto Ophiolith und die Ophiolithe rund um den Sowie Gory Block in den Sudeten darstellen.

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With 7 Figures     

Geochemical exploration for platinum-group elements in the Bushveld Complex, South Africa

Analyses of stream sediment and soil samples from the Bushveld Complex, South Africa have revealed enhanced precious metal concentrations, which can be related both to mining activities and the presence of hidden concentrations of platinum-group elements (PGEs) and gold. The economically important PGE deposits hosted by the Upper Critical Zone of the Rustenburg Layered Suite are revealed by a high PGE and Au content in the overlying soils. A second zone of elevated precious metal concentrations straddles the boundary between the Main and Upper Zones and has to date been traced for more than 100 km. This zone follows the igneous layering of the Rustenburg Layered Suite and is offset by the Brits Graben. It is therefore thought to be the reflection of a magmatic PGE-Au mineralisation. Received: 31 May 1996 / Accepted: 7 January 1997     

Isotope composition of Medieval lead glasses reflecting early silver production in Central Europe

The lead isotope composition of 32 lead glasses excavated from strata of the twelfth to early fifteenth century in six countries of NW Europe made the predominance of the Harz Mountains in this period of the Medieval European lead and silver production highly probable. Post-Variscan vein type galena, Devonian syngenetic hydrothermal ore (Rammelsberg) and blended ore from both deposits in the Harz were used. Our evaluation of 200 mining sites in Germany, Britain and Ireland also demonstrated that minor lead sources for lead glass were located in Bavaria/Bohemia and England. Lead ores from the Rhenohercynian orogenic belt in Germany are derived from rock sources close to the upper continental crust composition in ²³⁸U/²⁰⁴Pb of about 10 and Th/U of about 4. The ores in Central England originated from rocks with ²³⁸U/²⁰⁴Pb of about 11. Received: 24 September 1996 / Accepted: 17 January 1997     

Prediction of volumes and risk in hydrocarbon exploration: a quantification of geology

 The prediction of the hydrocarbon potential of a specific trap or of a number of specific traps (venture), referred to herein as prospect appraisal, concerns a probabilistic exercise based on the quantification of geology in terms of structural closure, reservoir quality, hydrocarbon charge, and the retention potential of the seal. Its objectives include: (a) prediction of the hydrocarbon volumes that could be present in the trap from an analysis of its geologic attributes; (b) the amount of uncertainty introduced in the volumetric prediction by the uncertainties in the subsurface geology; (c) the risk that one or more of the essential attributes of the prospect are underdeveloped and recoverable reserves are absent. The uncertainty of the geologic input requires a probabilistic approach, for which the Monte Carlo procedure is well suited. Prospect appraisal forms the basis for decision-making in oil exploration and development and, therefore, should be reliable, consistent, and auditable. This requires the use of a consistent methodology, the development of reliable models to quantify the geologic processes involved, and the collection of comprehensive and relational databases for the many geologic variables. As a result of data availability, uncertainty and risk tend to increase strongly from mature, producing basins to areas of frontier exploration. This may complicate management of exploration portfolios. Received: 1 July 1996/Accepted: 25 November 1996