The impact of logging on the surrounding flow in a managed forest

The influence of a freshly logged area in a managed pine forest on the flow field is investigated by comparing sodar wind profile data over the forest canopy with the synoptic wind field extracted from North American Regional Reanalysis, National Centers for Environmental Prediction. As a consequence of the pressure gradient arising from the sharp temperature difference between the clearcut and the surrounding uncut forests, the local wind direction over the forest measured with the sodar departs dramatically from the prevailing synoptic wind direction when the latter is transverse to the clearcut-sodar direction. Sodar measurements also indicate systematic strong updrafts during daytime followed by nighttime downdrafts with wind coming from the logged area. This suggests the presence of horizontal advection carrying daytime warm air (or nighttime cool air) from the clearcut to the forested area. This paper also examines the influence of wind velocity, clearcut fetch, and solar radiation on locally generated circulations and advection. The presence of local circulations arising from contrasting neighboring surface characteristics well outside the footprint is of particular relevance for atmospheric flux sites where robust surface?Catmosphere exchange values are sought. This study highlights the high level of circumspection required at the time of identifying locations for flux sites. It also suggests vigilant monitoring of the surrounding landscape during eddy?Cflux measurements particularly in actively managed landscapes.     

Lippmann Diagrams: Theory and Application to Carbonate Systems

Since 1980 when F. Lippmann's seminal paper appeared, ourunderstanding of solubility equilibria involving ionic solidsolutions has been advanced by theoretical considerations as wellas careful experimental studies designed to determine excess Gibbsfunctions. A unified theory of solid-solution aqueous-solutionequilibria as well as the thermodynamic background of thephenomenon of ``stoichiometric saturation' are reviewed.It is shown that Lippmann diagrams effectively summarize thethermodynamic basis of solid-solute aqueous-solution equilibria ofsparingly soluble metal carbonate systems. Clearly, the predictivepower of these diagrams may be limited due to kineticrestrictions. Only when dissolution and precipitation areessentially reversible, favourable conditions to synthesizehomogeneous solid phases can be derived from studies of equilibria.     

Exploring the impact of diagenesis on (isotope) geochemical and microstructural alteration features in biogenic aragonite

For the Quaternary and Neogene, aragonitic biogenic and abiogenic carbonates are frequently exploited as archives of their environment. Conversely, pre‐Neogene aragonite is often diagenetically altered and calcite archives are studied instead. Nevertheless, the exact sequence of diagenetic processes and products is difficult to disclose from naturally altered material. Here, experiments were performed to understand biogenic aragonite alteration processes and products. Shell subsamples of the bivalve Arctica islandica were exposed to hydrothermal alteration. Thermal boundary conditions were set at 100°C, 175°C and 200°C. These comparably high temperatures were chosen to shorten experimental durations. Subsamples were exposed to different ¹⁸O‐depleted fluids for durations between two and twenty weeks. Alteration was documented using X‐ray diffraction, cathodoluminescence, fluorescence and scanning electron microscopy, as well as conventional and clumped isotope analyses. Experiments performed at 100°C show redistribution and darkening of organic matter, but lack evidence for diagenetic alteration, except in Δ₄₇ which show the effects of annealing processes. At 175°C, valves undergo significant aragonite to calcite transformation and neomorphism. The δ¹⁸O signature supports transformation via dissolution and reprecipitation, but isotopic exchange is limited by fluid migration through the subsamples. Individual growth increments in these subsamples exhibit bright orange luminescence. At 200°C, valves are fully transformed to calcite and exhibit purple‐blue luminescence with orange bands. The δ¹⁸O and Δ₄₇ signatures reveal exchange with the aqueous fluid, whereas δ¹³C remains unaltered in all experiments, indicating a carbonate‐buffered system. Clumped isotope temperatures in high‐temperature experiments show compositions in broad agreement with the measured temperature. Experimentally induced alteration patterns are comparable with individual features present in Pleistocene shells. This study represents a significant step towards sequential analysis of diagenetic features in biogenic aragonites and sheds light on reaction times and threshold limits. The limitations of a study restricted to a single test organism are acknowledged and call for refined follow‐up experiments.     

A source of high-velocity white dwarfs

We investigate whether the recently observed population of high-velocity white dwarfs can be derived from a population of binaries residing initially within the thin disc of the Galaxy. In particular, we consider binaries where the primary is sufficiently massive to explode as a Type II supernova. A large fraction of such binaries are broken up when the primary then explodes as a supernova, owing to the combined effects of the mass loss from the primary and the kick received by the neutron star on its formation. For binaries where the primary evolves to fill its Roche lobe, mass transfer from the primary leads to the onset of a common envelope phase during which the secondary and the core of the primary spiral together as the envelope is ejected. Such binaries are the progenitors of X-ray binaries if they are not broken up when the primary explodes. For those systems that are broken up, a large number of the secondaries receive kick velocities ∼100–200 km s⁻¹ and subsequently evolve into white dwarfs. We compute trajectories within the Galactic potential for this population of stars and relate the birth rate of these stars over the entire Galaxy to those seen locally with high velocities relative to the local standard of rest (LSR) . We show that for a reasonable set of assumptions concerning the Galactic supernova rate and the binary population, our model produces a local number density of high-velocity white dwarfs compatible with that inferred from observations. We therefore propose that a population of white dwarfs originating in the thin disc may make a significant contribution to the observed population of high-velocity white dwarfs.     

Complex deep seismic anisotropy below the Scandinavian Mountains

Several seismological projects focused on the deep structure of the Scandinavian Mountains, in Norway and neighbouring Sweden. We use these recordings to study seismic anisotropy by analysing the birefringence of SKS and SKKS phases. These phases, which should be polarised radially, are split into an additional transverse component if they propagate through an anisotropic medium. Our results are directions Φ of the apparent fast shear wave polarisation and delay times δt between the split phases. For station KONO in Southern Norway, we find frequency-dependent Φ and δt values, indicating a depth-dependent anisotropy. Additionally, Φ and δt values vary with epicentre backazimuths in Norway, indicating a complex anisotropic structure in the crust and upper mantle. Stacking of the SKS/SKKS waveforms improves the signal-to-noise ratio along one station line and allows us to better determine the splitting parameters. A unique and complete model of the complex anisotropy cannot be obtained due to the limited observed backazimuth range. Near-surface tectonic structures correlate with the splitting pattern and thus the crust is one anisotropic layer in the region. Partly preferred orientations in the rock fabric at the surface can be correlated with Φ. Below one or more anisotropic layers must exist to explain the backazimuth- and frequency-dependent observations, as well as the long δt values (>2 s) which cannot be explained with crustal anisotropy alone. The spatial distribution of the splitting results indicates that different tectonics units, e.g. the Sveconorwegian, the Central and Northern Svecofennian and the Caledonian nappes, are each characterised by specific anisotropic signatures.     

Tektonische Studien in Schiefer- und Phyllitgebieten Thüringens

Zusammenfassung Schiefer- und Phyllitgebiete sind auch tektonisch voneinander verschieden. An Beispielen werden Charakteristika der beiden Einheiten erläutert. Im Schiefergebirge Ostthüringens sind die Beziehungen zwischen Faltung und Schieferung von besonderem Interesse. Im Schiefer- und Phyllitgebiet des Schwarzburger Sattels lassen sich mehreres-Flächensysteme und Achsen unterscheiden; zum Liegenden hin ist hier entsprechend den Vorstellungen einer Stockwerktektonik eine Änderung des tektonischen Stils zu beobachten.

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Tectonically, regions of shale and areas of phyllite are different. In the shale and phyllite area of the Schwarzburg Anticline several systems of s-surfaces and axes are represented. Toward the base a change in structural style can be observed in accordance with the concept of Stockwerk tectonics.

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Résumé Les domaines de schistes et de phyllites sont différents les uns des autres également du point de vue tectonique. Des exemples illustrent les caractéristiques des 2 unités. Dans le Massif schisteux de la Thuringe orientale, les relations entre le plissement et la schistosité sont particulièrement intéressantes. Dans le domaine des schistes et des phyllites de l'anticlinal de Schwarzburg, on peut distinguer plusieurs axes et plans de clivage; vers le bas on observe un changement du style tectonique conformément à une tectonique de Stockwerk.

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Comment on ‘García‐Santos G,Bruijnzeel LA. 2011. Rainfall,fog and throughfall dynamics in a subtropical ridge top cloud forest,National Park of Garajonay (La Gomera,Canary Islands,Spain). Hydrological Processes 25: 411–417’

A previous study aiming to characterize the water dynamics of a cloud forest in the Garajonay National Park (La Gomera) from measurements taken in a plot located in the upper part of a selected watershed within the park is here commented. Reported magnitudes of hydrological variables and conclusions based on them are in disagreement with those of numerous studies carried out previously at the same site. Large data dispersion and inapplicability of some of the hypothesis assumed are shown to invalidate most of the results. Copyright © 2011 John Wiley & Sons, Ltd.     

Inclined lidar observations of boundary layer aerosol particles above the Kongsfjord,Svalbard

An inclined lidar with vertical resolution of 0.4 m was used for detailed boundary layer studies and to link observations at Zeppelin Mountain (474 m) and Ny-Ålesund, Svalbard. We report on the observation of aerosol layers directly above the Kongsfjord. On 29 April 2007, a layer of enhanced backscatter was observed in the lowest 25 m above the open water surface. The low depolarization ratio indicated spherical particles. In the afternoon, this layer disappeared. The ultrafine particle concentration at Zeppelin and Corbel station (close to the Kongsfjord) was low. On 1 May 2007, a drying process in the boundary layer was observed. In the morning, the atmosphere up to Zeppelin Mountain showed enhanced values of the backscatter coefficient. Around noon, the top of the highly reflecting boundary layer decreased from 350 to 250 m. The top of the boundary layer observed by lidar was confirmed by radiosonde data.     

Macropores as preferential flow paths in meander bends

Macropores are subsurface connected void spaces caused by processes such as fracture of soils, micro‐erosion, and fauna burrows. They are common near streams (e.g. hyporheic and riparian zones) and may act as preferential flow paths between surface and groundwaters, affecting hydrologic and biogeochemical processes. We tested the hydrologic function of macropores by constructing an artificial macropore within the saturated zone of a meander bend (open macropore, ‘OM’) and later filling its upstream end (partially filled macropore, ‘PFM’). For each treatment, we injected saline tracer at an upgradient monitoring well within the meander and monitored downgradient hydraulics and tracer transport. Pressure transducers in monitoring wells indicated hydraulic gradients within the meander were 32% higher perpendicular to and 6% higher parallel to the macropore for the OM than for the PFM. Additionally, hydraulic conductivities measured via falling head tests were 29 to 550 times higher along the macropore than in nearby sediment. We used electrical conductivity probes in wells and electrical resistivity imaging to track solute transport. Transport velocities through the meander were on average 9 and 21% higher (per temporal moment analysis and observed tracer peak, respectively) for the OM than for the PFM. Furthermore, temporal moments of tracer breakthrough analysis indicated downgradient longitudinal dispersion and breakthrough tracer curve tailing were on average 234% and 182% higher for the OM, respectively. This suggests the OM enabled solute transport at overall shorter timescales than the matrix but also increased tailing. Our results demonstrate the importance of macropores to meander bend hydrology and solute transport. Copyright © 2012 John Wiley & Sons, Ltd.     

Natural background and pollution levels of some heavy metals in soils from the area of Dayton,Ohio

In a reconnaissance study, trace amounts of Cd, Cu, Pb, and Zn were determined in “A-zone” soil from 22 locations in the Dayton, Ohio, area. Soil samples were collected at high-volume air monitoring sites in urban, suburban, and rural areas. Measurable amounts of the elements were found in all of the samples. Positive correlations occur between each metal and particulate matter, with correlation coefficients of aboutr=0.70, at the 99% confidence level. Natural background values for the elements were measured in soil from rural areas. Theoretical background values, which are very close to those measured, were calculated from the individual regression equations. Natural background levels do not exceed 1.00 ppm Cd, 15 ppm Cu, 25 ppm Pb, and 55 ppm Zn. The heavy metal contents of most soils in the area exceed background by factors of up to 3.0 for Cd, up to 4.5 for Cu, up to 11 for Pb, and up to 4.5 for Zn. Significant positive correlations among the metals suggest a common source (or sources) for at least some, if not most, of the heavy metals. For the most part, the highest metal values are found in soils near coal-burning plants. Fly ash from a local plant contains substantial amounts of the elements. The high lead values are largely due to vehicular exhaust. However, there is evidence that the metals can also come from the normal deterioration of vehicles. It appears that airborne pollution is an important source of heavy metals in Dayton area soils.