Die Ausbildung der Geologen muß ergänzt werden

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Trophic modeling of the Northern Humboldt Current Ecosystem, Part I: Comparing trophic linkages under La Niña and El Niño conditions

The El Niño of 1997–98 was one of the strongest warming events of the past century; among many other effects, it impacted phytoplankton along the Peruvian coast by changing species composition and reducing biomass. While responses of the main fish resources to this natural perturbation are relatively well known, understanding the ecosystem response as a whole requires an ecotrophic multispecies approach. In this work, we construct trophic models of the Northern Humboldt Current Ecosystem (NHCE) and compare the La Niña (LN) years in 1995–96 with the El Niño (EN) years in 1997–98. The model area extends from 4°S–16°S and to 60 nm from the coast. The model consists of 32 functional groups of organisms and differs from previous trophic models of the Peruvian system through: (i) division of plankton into size classes to account for EN-associated changes and feeding preferences of small pelagic fish, (ii) increased division of demersal groups and separation of life history stages of hake, (iii) inclusion of mesopelagic fish, and (iv) incorporation of the jumbo squid (Dosidicus gigas), which became abundant following EN. Results show that EN reduced the size and organization of energy flows of the NHCE, but the overall functioning (proportion of energy flows used for respiration, consumption by predators, detritus and export) of the ecosystem was maintained. The reduction of diatom biomass during EN forced omnivorous planktivorous fish to switch to a more zooplankton-dominated diet, raising their trophic level. Consequently, in the EN model the trophic level increased for several predatory groups (mackerel, other large pelagics, sea birds, pinnipeds) and for fishery catch. A high modeled biomass of macrozooplankton was needed to balance the consumption by planktivores, especially during EN condition when observed diatoms biomass diminished dramatically. Despite overall lower planktivorous fish catches, the higher primary production required-to-catch ratio implied a stronger ecological impact of the fishery and stresses the need for precautionary management of fisheries during and after EN. During EN energetic indicators such as the lower primary production/total biomass ratio suggest a more energetically efficient ecosystem, while reduced network indicators such as the cycling index and relative ascendency indicate of a less organized state of the ecosystem. Compared to previous trophic models of the NHCE we observed: (i) a shrinking of ecosystem size in term of energy flows, (ii) slight changes in overall functioning (proportion of energy flows used for respiration, consumption by predators and detritus), and (iii) the use of alternate pathways leading to a higher ecological impact of the fishery for planktivorous fish.     

A combined method to model grain crushing with DEM

This paper presents a combined method to model grain crushing effects with discrete element method.This method combines the two most commonly used concepts to model grain crushing in DEM,i.e.the replacement method and the agglomerate method,so that it is both accurate and efficient.The method can be easily implemented.The performance is shown by several DEM simulations of biaxial tests.Particles with different crush-abilities are modeled.DEM simulation results with and without grain crushing are compared and discussed.The change of grain size distribution due to grain crushing is also investigated.     

Stereo analysis of high-resolution SAR images for building height estimation in cases of orthogonal aspect directions

SAR stereo image analysis for 3D information extraction is mostly carried out based on imagery taken under same-side or opposite-side viewing conditions. For urban scenes in practice stereo is up to now usually restricted to the first configuration, because increasing image dissimilarity connected with rising illumination direction differences leads to a lack of suitable features for matching, especially in the case of low or medium resolution data. However, due to two developments SAR stereo from arbitrary viewing conditions becomes an interesting option for urban information extraction. The first one is the availability of airborne sensor systems, which are capable of more flexible data acquisition in comparison to satellite sensors. This flexibility enables multi-aspect analysis of objects in built-up areas for various kinds of purpose, such as building recognition, road network extraction, or traffic monitoring. The second development is the significant improvement of the geometric resolution providing a high level of detail especially of roof features, which can be observed from a wide span of viewpoints. In this paper, high-resolution SAR images of an urban scene are analyzed in order to infer buildings and their height from the different layover effects in views taken from orthogonal aspect angles. High level object matching is proposed that relies on symbolic data, representing suitable features of urban objects. Here, a knowledge-based approach is applied, which is realized by a production system that codes a set of suitable principles of perceptual grouping in its production rules. The images are analyzed separately for the presence of certain object groups and their characteristics frequently appearing on buildings, such as salient rows of point targets, rectangular structures or symmetries. The stereo analysis is then accomplished by means of productions that combine and match these 2D image objects and infer their height by 3D clustering. The approach is tested using real SAR data of an urban scene.     

Quantifying uncertainties in projections of extremes��a perturbed land surface parameter experiment

Uncertainties in the climate response to a doubling of atmospheric CO₂ concentrations are quantified in a perturbed land surface parameter experiment. The ensemble of 108 members is constructed by systematically perturbing five poorly constrained land surface parameters of global climate model individually and in all possible combinations. The land surface parameters induce small uncertainties at global scale, substantial uncertainties at regional and seasonal scale and very large uncertainties in the tails of the distribution, the climate extremes. Climate sensitivity varies across the ensemble mainly due to the perturbation of the snow albedo parameterization, which controls the snow albedo feedback strength. The uncertainty range in the global response is small relative to perturbed physics experiments focusing on atmospheric parameters. However, land surface parameters are revealed to control the response not only of the mean but also of the variability of temperature. Major uncertainties are identified in the response of climate extremes to a doubling of CO₂. During winter the response both of temperature mean and daily variability relates to fractional snow cover. Cold extremes over high latitudes warm disproportionately in ensemble members with strong snow albedo feedback and large snow cover reduction. Reduced snow cover leads to more winter warming and stronger variability decrease. As a result uncertainties in mean and variability response line up, with some members showing weak and others very strong warming of the cold tail of the distribution, depending on the snow albedo parametrization. The uncertainty across the ensemble regionally exceeds the CMIP3 multi-model range. Regarding summer hot extremes, the uncertainties are larger than for mean summer warming but smaller than in multi-model experiments. The summer precipitation response to a doubling of CO₂ is not robust over many regions. Land surface parameter perturbations and natural variability alter the sign of the response even over subtropical regions.     

Analytic theory of Titan’s Schumann resonance: Constraints on ionospheric conductivity and buried water ocean

This study presents an approximate model for the atypical Schumann resonance in Titan’s atmosphere that accounts for the observations of electromagnetic waves and the measurements of atmospheric conductivity performed with the Huygens Atmospheric Structure and Permittivity, Wave and Altimetry (HASI–PWA) instrumentation during the descent of the Huygens Probe through Titan’s atmosphere in January 2005. After many years of thorough analyses of the collected data, several arguments enable us to claim that the Extremely Low Frequency (ELF) wave observed at around 36 Hz displays all the characteristics of the second harmonic of a Schumann resonance. On Earth, this phenomenon is well known to be triggered by lightning activity. Given the lack of evidence of any thunderstorm activity on Titan, we proposed in early works a model based on an alternative powering mechanism involving the electric current sheets induced in Titan’s ionosphere by the Saturn’s magnetospheric plasma flow. The present study is a further step in improving the initial model and corroborating our preliminary assessments. We first develop an analytic theory of the guided modes that appear to be the most suitable for sustaining Schumann resonances in Titan’s atmosphere. We then introduce the characteristics of the Huygens electric field measurements in the equations, in order to constrain the physical parameters of the resonating cavity. The latter is assumed to be made of different structures distributed between an upper boundary, presumably made of a succession of thin ionized layers of stratospheric aerosols spread up to 150 km and a lower quasi-perfect conductive surface hidden beneath the non-conductive ground. The inner reflecting boundary is proposed to be a buried water–ammonia ocean lying at a likely depth of 55–80 km below a dielectric icy crust. Such estimate is found to comply with models suggesting that the internal heat could be transferred upwards by thermal conduction of the crust, while convective processes cannot be ruled out.     

Aqueous–solid solution thermodynamic model of U(VI) uptake in C–S–H phases

Reliable thermodynamic models assessing the interaction of radionuclides with cementitious materials are important in connection with long-term predictions of the safe disposal of radioactive waste in cement-based repositories. In this study, a geochemical model of U(VI) interaction with calcium silicate hydrates (C–S–H phases), the main component of hardened cement paste (HCP), has been developed. Uranium(VI) sorption isotherms on C–S–H phases of different Ca:Si ratios (C:S) and structural data from spectroscopic studies provided the indispensable set of experimental data required for the model development. This information suggested that U(VI) is neither adsorbed nor incorporated in the Ca–O octahedral layers of the C–S–H structure, but rather is located in the interlayer, similar to Ca²⁺ and other cations. With a view to the high recrystallisation rates and the cryptocrystalline ‘gel-like’ structure of the C–S–H phases, these observations indicated a U(VI) uptake driven by the formation of a solid solution.     

Limnologische Beiträge zur Glazialgeologie

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Preparation and characterization of antibacterial silver/vermiculites and silver/montmorillonites

The reason for the preparation and characterization of the novel antibacterial silver/vermiculites (Ag/V) together with the silver/montmorillonites (Ag/M) was that the information on the vermiculite structure change and stability of Ag/V in water as well as its effect on bacteria are sporadic. The vermiculite (V), (Si_3.02Al_0.98)^IV (Mg_2.27Al_0.12Ti_0.07)^VI O₁₀(OH)₂ Ca_0.09Na_0.21K_0.50 from West China and montmorillonite (M), (Si_3.96Al_0.04)^IV (Al_1.20Mg_0.42Ti_0.02)^VI O₁₀ (OH)₂Ca_0.15Na_0.14K_0.08 from Ivan?ice (Czech Republic), fraction <0.4 μm were the starting clay materials for sample preparation. The samples V1 and M1 were prepared via reaction of the V and M with the 0.01 mol L⁻¹ AgNO₃ aqueous solution. The samples V2 and M2 were treated with the aqueous solution of AgNO₃ for two times. The cation exchange and reduced metallic silver on M1 and V1 evoked the specific surface area (SSA) diminution, the mean particle-size diameter extension and appearance of micropores with radius (<0.4 nm). Repeated silver cation exchange in M2 and V2 reduced particle size, increased slightly SSA and micropores with radius of 0.4-0.5 nm. Samples Ag/V and Ag/M showed higher content of pores with radius 0.5-1.0 nm than original V and M. The Ag concentration was found higher in Ag/V than in Ag/M and higher in repeatedly treated samples: 0.9 wt.% Ag in V1, 1.4 wt.% Ag in V2, 0.6 wt.% Ag in M1 and 1.0 wt.% Ag in M2. Vermiculite structure consisting of the hydrated interstratified phases and the mica-like phase changed to the cation-one-zero layer hydrate interstratification structure in V1 and to the random of two-one layer hydrate interstratifications in V2. Infrared and Mössbauer spectroscopy revealed no changes in the structure of the clay minerals that could be related directly to the sorption and crystallization of silver. Transmission electron microscopy showed that the silver nanoparticles size distribution was much narrower for the samples Ag/M than for Ag/V. The mean size of the Ag particles was between 40 and 50 nm. Although the Ag nanoparticles did not adhere sufficiently at the clay minerals surface and migrated moderately into water, all samples under study were approved to be effective inhibitors of the bacterial growth persisting for the whole testing period of 6 days. Silver/vermiculite was antimicrobial more efficient against Klebsiella pneumoniae and Pseudomonas aeruginosa than silver/montmorillonite.