A flux-limiting wetting–drying method for finite-element shallow-water models,with application to the Scheldt Estuary

We present a flux-limiting wetting–drying approach for finite-element discretizations of the shallow-water equations using discontinuous linear elements for the elevation. The key ingredient of the method is the use of limiters for generalized nodal fluxes. This method is implemented into the Second-generation Louvain-la-Neuve Ice-ocean Model (SLIM), and is verified against standard test cases. The method is further applied to the wetting and drying of sand banks in the Scheldt Estuary, which is located in northern Belgium and the southern Netherlands. The results obtained for both the benchmarks and the realistic problem illustrate the accuracy of the method in describing the hydrodynamics in the vicinity of dry areas. In particular, the method strictly conserves mass, and there is no transport through dry areas.     

Application of an intelligent model developed from experimental data to building design for fire safety

Computational fluid dynamics (CFD) techniques are widely adopted to simulate the behavior of fire. However, CFD suffers from the shortcoming of requiring extensive computer storage and a lengthy computational time. In practical applications, although comprehensive field information on velocities, temperatures, pressure, and the fractions of different constitutes can be obtained from CFD simulations, the user may only be interested in few important parameters that index the performance of a compartment design in the event of a fire. The height of the thermal interface (HTI) is one such key index, and refers to the average height above floor level inside a fire compartment at which the temperature gradient is highest. In practice, a fire compartment is considered untenable when the HTI drops below the respiratory level of the occupants, and in optimizing the design of a fire system, another set of design parameters (e.g., the width of the door opening) must be examined if the HTI of a fire compartment design is evaluated by CFD as being too low. This trial and error exercise then continues until a close to optimum set of design parameters is achieved. This approach is theoretically feasible, but requires lengthy computational time. This paper proposes the application of an Artificial Neural Network (ANN) approach as a fast alternative to CFD models to simulate the behavior of a compartment fire. A novel ANN model named GRNNFA has been specially developed for fire studies. It is a hybrid ANN model that combines the General Regression Neural Network (GRNN) and Fuzzy ART (FA). The GRNNFA model features a network structure that grows incrementally, stable learning, and the absence of the noise embedded in experimental fire data. It has been employed to establish a system response surface based on the training samples collected from a full-scale experiment on compartment fire. However, as the available training samples may not be sufficient to describe the behavior of all systems, and especially those involving fire data, this paper proposes that extra knowledge be acquired from human experts. Human expert network training has thus been developed to remedy established system response surface problems. After transforming the remedied system response surface to the problem domain, a Genetic Algorithm (GA) is applied to evaluate the close to optimum set of design parameters.     

Direct evidence of the feedback between climate and weathering

Long-term climate moderation is commonly attributed to chemical weathering; the higher the temperature and precipitation the faster the weathering rate. Weathering releases divalent cations to the ocean via riverine transport where they promote the drawdown of CO₂ from the atmosphere by the precipitation and subsequent burial of carbonate minerals. To test this widely-held hypothesis, we performed a field study determining the weathering rates of 8 nearly pristine north-eastern Iceland river catchments with varying glacial cover over 44 years. The mean annual temperature and annual precipitation of these catchments varied by 3.2 to 4.5 °C and 80 to 530%, respectively during the study period. Statistically significant linear positive correlations were found between mean annual temperature and chemical weathering in all 8 catchments and between mean annual temperature and both mechanical weathering and runoff in 7 of the 8 catchments. For each degree of temperature increase, the runoff, mechanical weathering flux, and chemical weathering fluxes in these catchments are found to increase from 6 to 16%, 8 to 30%, and 4 to 14% respectively, depending on the catchment. In contrast, annual precipitation is less related to the measured fluxes; statistically significant correlations between annual precipitation and runoff, mechanical weathering, and chemical weathering were found for 3 of the least glaciated catchments. Mechanical and chemical weathering increased with time in all catchments over the 44 year period. These correlations were statistically significant for only 2 of the 8 catchments due to scatter in corresponding annual runoff and average annual temperature versus time plots. Taken together, these results 1) demonstrate a significant feedback between climate and Earth surface weathering, and 2) suggest that weathering rates are currently increasing with time due to global warming.     

Extraterrestrial amino acids and L‐enantiomeric excesses in the CM2 carbonaceous chondrites Aguas Zarcas and Murchison

The abundances, distributions, enantiomeric ratios, and carbon isotopic compositions of amino acids in two fragments of the Aguas Zarcas CM2 type carbonaceous chondrite fall and a fragment of the CM2 Murchison meteorite were determined via liquid chromatography time‐of‐flight mass spectrometry and gas chromatography isotope ratio mass spectrometry. A suite of two‐ to six‐carbon aliphatic primary amino acids was identified in the Aguas Zarcas and Murchison meteorites with abundances ranging from ~0.1 to 158 nmol/g. The high relative abundances of α‐amino acids found in these meteorites are consistent with a Strecker‐cyanohydrin synthesis on these meteorite parent bodies. Amino acid enantiomeric and carbon isotopic measurements in both fragments of the Aguas Zarcas meteorites indicate that both samples experienced some terrestrial protein amino acid contamination after their fall to Earth. In contrast, similar measurements of alanine in Murchison revealed that this common protein amino acid was both racemic (D ≈ L) and heavily enriched in ¹³C, indicating no measurable terrestrial alanine contamination of this meteorite. Carbon isotope measurements of two rare non‐proteinogenic amino acids in the Aguas Zarcas and Murchison meteorites, α‐aminoisobutyric acid and D‐ and L‐isovaline, also fall well outside the typical terrestrial range, confirming they are extraterrestrial in origin. The detections of non‐terrestrial L‐isovaline excesses of ~10–15% in both the Aguas Zarcas and Murchison meteorites, and non‐terrestrial L‐glutamic acid excesses in Murchison of ~16–40% are consistent with preferential enrichment of circularly polarized light generated L‐amino acid excesses of conglomerate enantiopure crystals during parent body aqueous alteration and provide evidence of an early solar system formation bias toward L‐amino acids prior to the origin of life.     

Effect of stiffness variability on the response of isolated structures

Results are presented of an investigation, the objective of which was to determine the relationship between the stiffness variability of the bearings of an isolation system and the response variability of the structure. The system is modeled as a rigid, rectangular structure that is free to translate and rotate. The isolation system consists of N isolation bearings arranged in a rectangular pattern, each with a stiffness k_i that is an independent, normally distributed, random variable. Response spectrum analysis is used to obtain the analytical solution for the structure response. Approximate closed‐form expressions are obtained for the variance of the centreline displacement, rotation, corner displacement and base shear, that are in terms of the variability of the isolator stiffness, aspect ratio of the structure, and the number and layout of isolation bearings. Results show that the standard deviation of the centreline displacement and base shear decrease with increasing number of isolation bearings, and are independent of the aspect ratio and layout of isolators, and in all cases are less than 1/4 the standard deviation of the isolator stiffness. The standard deviation of the corner displacement is a function of all of the system parameters, and is bounded below by the standard deviation of the centreline displacement and above by the standard deviation of a bar aligned perpendicular to the direction of ground motion with m isolation bearings distributed along the length. The approximate expressions are shown to be in good agreement with the results of Monte Carlo simulations. The results should be of use to designers of isolated structures and manufacturers of isolation systems, in assessing the significance of stiffness variability on the response of the isolated structure. Copyright © 2000 John Wiley & Sons, Ltd.     

Sonication of bacteria, phytoplankton and zooplankton: Application to treatment of ballast water

We investigated the effect of high power ultrasound, at a frequency of 19 kHz, on the survival of bacteria, phytoplankton and zooplankton, in order to obtain estimates of effective exposure times and energy densities that could be applied to design of ultrasonic treatment systems for ballast water. Efficacy of ultrasonic treatment varied with the size of the test organism. Zooplankton required only 3-9s of exposure time and 6-19 J/mL of ultrasonic energy to realize a 90% reduction in survival. In contrast, decimal reduction times for bacteria and phytoplankton ranged from 1 to 22 min, and decimal reduction energy densities from 31 to 1240 J/mL. Our results suggest that stand-alone ultrasonic treatment systems for ballast water, operating at 19-20 kHz, may be effective for planktonic organisms >100 microm in size, but smaller planktonic organisms such as phytoplankton and bacteria will require treatment by an additional or alternative system.     

Evolution and petroleum geology of Amlia and Amukta intra-arc summit basins, Aleutian Ridge

Amlia and Amukta Basins are the largest of many intra-arc basins formed in late Cenozoic time along the crest of the Aleutian Arc. Both basins are grabens filled with 2–5 km of arc-derived sediment. A complex system of normal faults deformed the basinal strata. Although initial deposits of late Micocene age may be non-marine in origin, by early Pliocene time, most of the basinfill consisted of pelagic and hemipelagic debris and terrigenous turbidite deposits derived from wavebase and subaerial erosion of the arc's crestal areas. Late Cenozoic volcanism along the arc commenced during or shortly after initial subsidence and greatly contributed to active deposition in Amlia and Amukta Basins.Two groups of normal faults occur: major boundary faults common to both basins and ‘intra-basin’ faults that arise primarily from arc-parallel extension of the arc. The most significant boundary fault, Amlia-Amukta fault, is a south-dipping growth fault striking parallel to the trend of the arc. Displacement across this fault forms a large half-graben that is separated into the two depocentres of Amlia and Amukta Basins by the formation of a late Cenozoic volcanic centre, Seguam Island. Faults of the second group reflect regional deformation of the arc and offset the basement floor as well as the overlying basinal section. Intra-basin faults in Amlia Basin are predominantly aligned normal to the trend of the arc, thereby indicating arc-parallel extension. Those in Amukta basin are aligned in multiple orientations and probably indicate a more complex mechanism of faulting. Displacement across intra-basin faults is attributed to tectonic subsidence of the massif, aided by depositional loading within the basins. In addition, most intra-basin faults are listric and are associated with high growth rates.Although, the hydrocarbon potential of Amlia and Amukta Basins is difficult to assess based on existing data, regional considerations imply that an adequate thermal history conducive to hydrocarbon generation has prevailed during the past 6-5 my. The possibility for source rocks existing in the lower sections of the basins is suggested by exposures of middle and upper Miocene carbonaceous mudstone on nearby Atka Island and the implication that euxinic conditions may have prevailed during the initial formation of the basins. Large structures have evolved to trap migrating hydrocarbons, but questions remain concerning the preservation of primary porosity in a sedimentary section rich in reactive volcaniclastic debris.     

Simulating flood events at the Twin Ports of Duluth-Superior using a linked hydrologic-hydrodynamic framework

Ocean Dynamics - Generally, ports in the North American Great Lakes are not supported with navigational guidance (water level, water temperature, currents, ice) by NOAA’s Great Lakes...     

Field evidence for the influence of weathering on rock erodibility and channel form in bedrock rivers

Erosion processes in bedrock‐floored rivers shape channel cross‐sectional geometry and the broader landscape. However, the influence of weathering on channel slope and geometry is not well understood. Weathering can produce variation in rock erodibility within channel cross‐sections. Recent numerical modeling results suggest that weathering may preferentially weaken rock on channel banks relative to the thalweg, strongly influencing channel form. Here, we present the first quantitative field study of differential weathering across channel cross‐sections. We hypothesize that average cross‐section erosion rate controls the magnitude of this contrast in weathering between the banks and the thalweg. Erosion rate, in turn, is moderated by the extent to which weathering processes increase bedrock erodibility. We test these hypotheses on tributaries to the Potomac River, Virginia, with inferred erosion rates from ~0.1 m/kyr to >0.8 m/kyr, with higher rates in knickpoints spawned by the migratory Great Falls knickzone. We selected nine channel cross‐sections on three tributaries spanning the full range of erosion rates, and at multiple flow heights we measured (1) rock compressive strength using a Schmidt hammer, (2) rock surface roughness using a contour gage combined with automated photograph analysis, and (3) crack density (crack length/area) at three cross‐sections on one channel. All cross‐sections showed significant (p < 0.01 for strength, p < 0.05 for roughness) increases in weathering by at least one metric with height above the thalweg. These results, assuming that the weathered state of rock is a proxy for erodibility, indicate that rock erodibility varies inversely with bedrock inundation frequency. Differences in weathering between the thalweg and the channel margins tend to decrease as inferred erosion rates increase, leading to variations in channel form related to the interplay of weathering and erosion rate. This observation is consistent with numerical modeling that predicts a strong influence of weathering‐related erodibility on channel morphology. Copyright © 2017 John Wiley & Sons, Ltd.     

Dynamics and fluxes of organic carbon and nitrogen in two Guiana Shield river basins impacted by deforestation and mining activities

Deforestation and mining activities have proven to be very damaging to rivers because these activities disturb the environmental characteristics of rivers. Thus, the concentrations of dissolved organic carbon (DOC), particulate organic carbon (POC), particulate nitrogen (PN), and Chlorophyll‐a (Chl‐a) were measured monthly during 2 hydrological years in the Maroni and Oyapock Rivers to assess the dynamics and fluxes of organic carbon and nitrogen in these 2 Guiana Shield basins, which have been strongly (Maroni) and weakly (Oyapock) impacted by deforestation and mining activities. The 2‐year time series show that DOC, POC, PN, and Chl‐a concentrations vary seasonally with discharge in both rivers, indicating a hydrologically dominated control. Temporal patterns of DOC, POC, and PN indicate that these variables show maximum concentrations in rising waters due to the yield of organic matter and nitrogen accumulated in soils, which are incorporated into the rivers during rainfall. However, the Chl‐a concentrations were at a maximum during low‐water stages. The C/N and C/Chl‐a ratios also showed a seasonal trend, with lower values during the low water periods due to an increase in algal biomass. During high water, the POC in both rivers is the result of terrestrial organic matter, whereas during low‐water autochthonous organic matter can reach up to 34% of the POC. The mean annual fluxes of TOC and PN were higher (4.56 × 10⁵ tonC year^?1 and 1.77 × 10⁴ tonN year^?1, respectively) in the Maroni River than those (1.84 × 10⁵ tonC year^?1 and 0.54 × 10⁴ tonN year^?1, respectively) in the Oyapock River. However, the specific fluxes of DOC, POC, and PN from both basins were nearly the same. Although gold mining activities are performed in both basins, there is no conclusive evidence regarding the impact of these activities on the dynamics of organic matter and particulate nitrogen in the Maroni and Oyapock Rivers.