Autoxidation of N(III), S(IV), and other Species in Frozen Solution – A Possible Pathway for Enhanced Chemical Transformation in Freezing Systems

The chemistry of glycolaldehyde (hydroxyacetaldehyde) relevant to the troposphere has been investigated using UV absorption spectrometry and FTIR absorption spectrometry in an environmental chamber. Quantitative UV absorption spectra have been obtained for the first time. The UV spectrum peaks at 277 nm with a maximum cross section of (5.5± 0.7)×10^–20 cm² molecule^–1. Studies of the ultraviolet photolysis of glycolaldehyde ( = 285 ± 25 nm) indicated that the overall quantum yield is > 0.5 in one bar of air, with the major products being CH₂OH and HCO radicals. Rate coefficients for the reactions of Cl atoms and OH radicals with glycolaldehyde have been determined to be (7.6± 1.5)×10^–11 and (1.1± 0.3)×10^–11 cm³ molecule^–1 s^–1, respectively, in good agreement with the only previous study. The lifetime of glycolaldehyde in the atmosphere is about 1.0 day for reaction with OH, and > 2.5 days for photolysis, although both wet and dry deposition should also be considered in future modeling studies.     

Bioterrorism: A ‘New’ Global Environmental Health Threat

Biological weapons represent a unique "environmental" hazard. The pathogens involved are natural in the sense that they are risks that naturally occur in our environment. However they are unnatural in the way in which they are inflicted upon society. This revised version was published online in September 2006 with corrections to the Cover Date.     

Detection Time for Plausible Changes in Annual Precipitation, Evapotranspiration, and Streamflow in Three Mississippi River Sub-Basins

We use diagnostic studies of off-line variable infiltration capacity (VIC) model simulations of terrestrial water budgets and 21st-century climate change simulations using the parallel climate model (PCM) to estimate the time required to detect predicted changes in annual precipitation (P), evapotranspiration (E), and discharge (Q) in three sub-basins of the Mississippi River Basin. Time series lengths on the order of 50–350 years are required to detect plausible P, E, and Q trends in the Missouri, Ohio, and Upper Mississippi River basins. Approximately 80–160, 50, and 140–350 years, respectively, are needed to detect the predicted P, E, and Q trends with a high degree of statistical confidence. These detection time estimates are based on conservative statistical criteria (α = 0.05 and β = 0.10) associated with low probability of both detecting a trend when it is not occurring (Type I error) and not detecting a trend when it is occurring (Type II error). The long detection times suggest that global-warming-induced changes in annual basin-wide hydro-climatic variables that may already be occurring in the three basins probably cannot yet be detected at this level of confidence. Furthermore, changes for some variables that may occur within the 21st century might not be detectable for many decades or until the following century – this may or may not be the case for individual recording station data. The long detection times for streamflow result from comparatively low signal-to-noise ratios in the annual time series. Finally, initial estimates suggest that faster detection of acceleration in the hydrological cycle may be possible using seasonal time series of appropriate hydro-climatic variables, rather than annual time series.     

Inverted-polarity electrical structures in thunderstorms in the Severe Thunderstorm Electrification and Precipitation Study (STEPS)

Balloon-borne electric field soundings and lightning mapping data have been analyzed for three of the storms that occurred in the Severe Thunderstorm Electrification and Precipitation Study field program in 2000 to determine if the storms had inverted-polarity electrical structures. The polarities of all or some of the vertically stacked charge regions in such storms are opposite to the polarities observed at comparable heights in normal storms. Analyses compared the charge structures inferred from electric field soundings in the storms with charges inferred from three-dimensional lightning mapping data. Charge structures were inferred from electric field profiles by combining the one-dimensional approximation of Gauss's law with additional information from three-dimensional patterns in the electric field vectors. The three different ways of inferring the charge structure in the storms were found to complement each other and to be consistent overall. Charge deposition by lightning possibly occurred and increased the charge complexity of one of the storms.Many of the cloud flashes in each case were inverted-polarity flashes. Two storms produced ground flash activity comprised predominantly of positive ground flashes. One storm, which was an isolated thunderstorm, produced inverted-polarity cloud flashes, but no flashes to ground. The positive and negative thunderstorm charge regions were found at altitudes where, respectively, negative and positive charge would be found in normal-polarity storms. Thus, we conclude that these storms had anomalous and inverted-polarity electrical structures. Collectively, these three cases (along with the limited cases in the refereed literature) provide additional evidence that thunderstorms can have inverted-polarity electrical structures.     

Global change and the intensification of agriculture in the tropics

Bridging understanding of local environmental change with regional and global patterns of land-use and land-cover change (LUCC) remains a key goal and challenge for our understanding of global environmental change. This meta-analysis attempts to bridge local and regional scales of LUCC by demonstrating the ways in which previously published case studies can be compared and used for a broader regional synthesis in the tropics. In addition to providing results from a meta-analysis, this paper suggests ways to make future case studies more widely comparable.     

From pastoralism to tourism: The historical impact of changing land use practices in Namaqualand

We use the concept of ecological revolutions to explain the environmental history of Namaqualand, from the advent of pastoralism 2000 years BP, to colonial settlement in the 18th century and finally to the recent trend of de-agrarianization from the middle of the 20th century. Early traveller's records and census data are used to assess changes in the human population of the region and how this affected wildlife and agricultural practices. Pre-colonial indigenous hunter-gatherer (Bushmen) and pastoralist (Khoekhoen) populations in Namaqualand consisted of probably no more than a few thousand individuals. Over the next three centuries, the general population rose steadily to more than 65,000 people but has fallen in recent years. Wildlife appears not to have been abundant in Namaqualand's pre-colonial landscapes and large springbok ‘treks’ were probably a rare event. The number of domestic livestock in Namaqualand peaked in 1957 largely as a result of an increase in the number of sheep which have fallen steadily since this time. Crop production was absent from Namaqualand's pre-colonial landscapes but increased to cover nearly 30,000 ha in the early 1970s. The area under cultivation has declined by nearly two thirds since this time largely as a result of the large-scale abandonment of wheat farming in marginal environments. We touch on differences between the communal areas and private farms, particularly in terms of their human populations and agricultural impact on the land. Repeat landscape photographs support our main findings which suggest that both rocky, upland habitats and rivers have not been transformed substantially by land use practices in Namaqualand. Instead, sandy pediments have borne the brunt of human impacts in the region. Finally, we highlight the beginning of a new ecological revolution in Namaqualand due to changes in the global and national political economy.     

Modelling the sustainability and productivity of pastoral systems in the communal areas of Namaqualand

We investigated the effects of rainfall and the number of animals on changes in vegetation and on the output of milk and meat from the communal areas of Namaqualand. Previously published short- and long-term models link processes that range from the levels of tissue (in, for example, the mammary gland), to the milk yields of individual animals, to the growth and survival of their young and to long-term changes in plant species populations at the ecosystem level. These models have been used to study how different factors and management strategies affect livestock productivity and vegetation composition on a 20,000 ha rangeland in Namaqualand. First, the inter-relations between rainfall, stocking rate and productivity were studied using the short-term model. This model shows that in addition to total rainfall and stocking rate, the timing of rainfall within a year also influences doe live weight and survival to the end of the year. When the long-term model is run, using recorded rainfall, predictions of small stock numbers agree closely with livestock data recorded over the same 30-year period. One thousand replicates of 100-year runs of the long-term model were then used to study the probable impact of different upper limits to stock numbers on animal performance. Off take (sales and slaughterings) are maximal when stock numbers are limited to 2000 adults. Animal numbers increase marginally as the limit is increased above this level, but the variability between years in numbers increases. Secondly, the long-term model was used to study the long-term effects of the stocking rate strategies on rangeland condition. The model predicts that although these effects are variable, when moderately degraded range is stocked with an upper limit at the recommended level it is unable to recover to less degraded states over 100 years. Thirdly, the model was used to examine the effects of reduction in stock numbers and slaughtering of kids in a drought year on goat numbers during the subsequent 5 years. Finally, the model predicts that a 10% reduction in mean annual rainfall will lead to a 35% reduction in animal numbers over 200 years.     

Trace element zoning in pyroxenes from ODP Hole 735B gabbros: diffusive exchange or synkinematic crystal fractionation?

Major and trace element profiles of clinopyroxene grains in oceanic gabbros from ODP Hole 735B have been investigated by a combined in situ analytical study with ion probe, and electron microprobe. In contrast to the homogeneous major element compositions, trace elements (REE, Y, Cr, Sr, and Zr) show continuous core to rim zoning profiles. The observed trace element systematics in clinopyroxene cannot be explained by a simple diffusive exchange between melts and gabbros along grain boundaries. A simultaneous modification of the melt composition is required to generate the zoning, although Rayleigh fractional crystallization modelling could mimic the general shape of the profiles. Simultaneous metasomatism between the cumulate crystal and the porous melt during crystal accumulation is the most likely process to explain the zoning. Deformation during solidification of the crystal mush could have caused squeezing out of the incompatible element enriched residual melts (interstitial liquid). Migration of the melt along grain boundaries might carry these melt out of the system. This process named as synkinematic differentiation or differentiation by deformation (Natland and Dick in J Volcanol Geotherm Res 110(3–4):191–233, 2001) may act as an important magma evolution mechanism in the oceanic crust, at least at slow-spreading ridges.